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91.
Polarized optical absorption spectra of natural olivine, Fa10Fo90, were measured before and after annealing/quenching experiments performed at 650, 800, 1,000 and 1,200°C under controlled oxygen fugacity. It was found that the annealing induces weak but definite changes in the olivine spectra. The intensity of the spin-allowed Z > X-polarized band at 9,560 cm?1 and shoulder at ~8,300 cm?1 attributed to Fe2+(M2), continuously decreases with annealing temperature, whereas a weaker band at ~11,600 cm?1 assigned to electronic spin-allowed transitions of Fe2+(M1), increases. This evidently shows that annealing treatments cause a redistribution of Fe2+ from M2 to M1. The fractionation increases with increasing temperature. This observation is in good correspondence with many diffraction structural studies of natural and synthetic olivines, as well as with recent Raman and Mössbauer investigations by Kolesov and Geiger (Mitt Österr Mineral Ges 149:48, 2004) and Morozov et al. (Eur J Mineral 17:495–500, 2005) evidencing a weak tendency of Fe to order into the M1 site with increasing temperature. However, this deduction is incompatible with the results of the in situ neutron power diffraction study of synthetic FeMgSiO4 by Redfern et al. (Phys Chem Minerals 27:630–637, 2000). Polarization properties of the UV absorption edge, attributed to ligand-to-metal charge-transfer transitions in Fe3+, changes from Y > X ? Z in natural samples to a weak Y ≥ X ≥ Z-pleochroism in annealed ones. This may be due to redistribution of a small content of Fe3+ among M1 and M2 structural sites. 相似文献
92.
93.
Raka Dona Ray Mandal Monika Sinha † Manjari Bagchi Sushan Konar Mira Dey ‡ Jishnu Dey 《Monthly notices of the Royal Astronomical Society》2006,365(4):1383-1386
It appears that there is a genuine shortage of radio pulsars with surface magnetic fields significantly smaller than ∼108 G. We propose that the pulsars with very low magnetic fields are actually strange stars locked in a state of minimum free energy and therefore at a limiting value of the magnetic field which cannot be lowered by the system spontaneously. 相似文献
94.
95.
Zooplankton are an important trophic link and a key food source for many larval fish species in estuarine ecosystems. The
present study documents temporal and spatial zooplankton dynamics in Suisun Bay and the Sacramento–San Joaquin Delta—the landward
portion of the San Francisco Estuary (California, USA)—over a 37-year period (1972–2008). The zooplankton community experienced
major changes in species composition, largely associated with direct and indirect effects of introductions of non-native bivalve
and zooplankton species. A major clam invasion and many subsequent changes in zooplankton abundance and composition coincided
with an extended drought and accompanying low-flow/high-salinity conditions during 1987–1994. In the downstream mesohaline
region, the historically abundant calanoid copepods and rotifers have declined significantly, but their biomass has been compensated
to some extent by the introduced cyclopoid Limnothoina tetraspina. The more upstream estuary has also experienced long-term declining biomass trends, particularly of cladocerans and rotifers,
although calanoid copepods have increased since the early 1990s due to the introduced Pseudodiaptomus spp. In addition, mysid biomass has dropped significantly throughout the estuary. Shifts in zooplankton species composition
have also been accompanied by an observed decrease in mean zooplankton size and an inferred decrease in zooplankton food quality.
These changes in the biomass, size, and possibly chemical composition of the zooplankton community imply major alterations
in pelagic food web processes, including a drop in prey quantity and quality for foraging fish and an increase in the importance
of the microbial food web for higher trophic levels. 相似文献
96.
Abstract— Fischer‐Tropsch catalysis, the iron/nickel catalyzed conversion of CO and H2 to hydrocarbons, would have been the only thermally‐driven pathway available in the solar nebula to convert CO into other forms of carbon. A major issue in meteoritics is to determine the origin of meteoritic organics: are they mainly formed from CO in the solar nebula via a process such as Fischer‐Tropsch, or are they derived from interstellar organics? In order to determine the role that Fischer‐Tropsch catalysis may have played in the organic chemical evolution of the solar nebula, we have developed a kinetic model for this process. Our model results agree well with experimental data from several existing laboratory studies. In contrast, empirical rate equations, which have been derived from experimental rate data for a limited temperature (T) and pressure (P) range, are inconsistent with experimental rate data for higher T and lower P. We have applied our model to pressure and temperature profiles for the solar nebula, during the epoch in which meteorite parent bodies condensed and agglomerated. We find that, under nebular conditions, the conversion rate of CO to CH4 does not simply increase with temperature as the empirically‐derived equations suggest. Instead, our model results show that this process would have been most efficient in a fairly narrow region that coincides with the present position of the asteroid belt. Our results support the hypothesis that Fischer‐Tropsch catalysis may have played a role in solar nebula chemistry by converting CO into less volatile materials that can be much more readily processed in the nebula and in parent bodies. 相似文献
97.
本文分析了2004年12月26日苏门答腊-安达曼地震的宽频带地震图。目的是通过不同频率成分的子事件的发生时间了解断层的破裂过程。具体分析的是由相应宽频带地震记录得到的P波的时频地震图。分析结果说明,在S波到达前的时窗内发生了最大辐射强度的相应频率低于1 Hz的15次较大子事件,但在同样的时窗内,还发生了最大辐射强度的频... 相似文献
98.
Frequency analysis of the Sumatra-Andaman earthquake of 2004, one of the most significant and best-recorded earthquakes, is
based on spectral seismograms obtained from their broadband seismograms. The Sumatra-Andaman earthquake is found to have a
wide-range frequency content of P-wave radiation during the rupturing process. On the basis of stacking spectral seismograms
we distinguished four time events of the rupturing process of a total length of about 540 s. The frequency, f
max, is the highest for the first event (0.163 Hz in time interval 0–88 s), lowest for the second — which is the strongest (0.075
Hz in time interval 88–204 s). For third and fourth events frequencies are similar (0.089 and 0.082 Hz in time intervals 204–452
and 452–537 s, respectively). The frequency also shows an azimuthal dependence (±0.02 Hz). Azimuths for which the frequency,
f
max, has maximum and minimum values are 203–222° and 23–42°, respectively. These observations are discussed in relation to previously
published papers on this topic. 相似文献
99.
Water and Iron effect on the P-T-x coordinates of the 410-km discontinuity in the Earth upper mantle
Fiorenza Deon Monika Koch-Müller Dieter Rhede Richard Wirth 《Contributions to Mineralogy and Petrology》2011,161(4):653-666
We performed multi-anvil experiments in the system MgO-SiO2 ± H2O at 13.0–13.7 GPa and 1,025–1,300°C and in the system MgO-FeO-SiO2 ± H2O, under reducing conditions, at 11.0–12.7 GPa and 1,200°C, to depict the effect of H2O on the P-T-x coordinates of the 410-km discontinuity, i.e. the olivine–wadsleyite phase boundary. The charges were investigated
with Electron Microprobe (EMP), Raman Spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR), Secondary Ion Mass Spectrometry
(SIMS) and Electron Energy Loss Spectroscopy (EELS). We observe in the MgO-SiO2-H2O system at 1,200°C a 0.6 GPa shift of the phase boundary to lower pressure compared to dry conditions, due to the stronger
water fractionation into wadsleyite (wad) rather than in olivine (ol). In the MgO-FeO-SiO2-H2O system, we reproduced the triple point, i.e. observed coexisting hydrous ol, wad and ringwoodite (ring). SIMS H quantifications
provided partitioning coefficients for water:
D\textwad/ol\textwater D_{\text{wad/ol}}^{\text{water}} ~ 3.7(5) and
D\textring/ol\textwater D_{\text{ring/ol}}^{\text{water}} ~ 1.5(2) and
D\textwad/ring\textwater D_{\text{wad/ring}}^{\text{water}} ~ 2.5(5). For a bulk composition of x
Fe = 0.1, our data indicate only a slight difference in the width of the loop of the two phase field ol–wad under hydrous conditions
compared to dry conditions, i.e. no broadening with respect to composition but a shift to lower pressures. For bulk compositions
of x
Fe > 0.2, i.e. in regions where wad–ring and ol–ring coexist, we observe, however, an unexpected broadening of the loops with
a shift to higher iron contents. In total, the stability field of hydrous wad expands in both directions, to lower and higher
pressures. Fe3+ concentrations as determined by EELS are very low and are expected to play no role in the broadening of the loops. 相似文献
100.
Marcin Polkowski Beata Plesiewicz Jan Wiszniowski Monika Wilde-Piórko Passeq Working Group 《Acta Geophysica》2016,64(6):2092-2113
PASSEQ 2006–2008 (Passive Seismic Experiment in TESZ; Wilde-Piórko et al. 2008) was the biggest passive seismic experiment carried out so far in the area of Central Europe (Poland, Germany, the Czech Republic and Lithuania). 196 seismic stations (including 49 broadband seismometers) worked simultaneously for over two years. During the experiment, multiple types of data recorders and seismometers were used, making the analysis more complex and time consuming. The dataset was unified and repaired to start the detection of local seismic events. Two different approaches for detection were applied for stations located in Poland. The first one used standard STA/LTA triggers (Carl Johnson’s STA/LTA algorithm) and grid search to classify and locate the events. The result was manually verified. The second approach used Real Time Recurrent Network (RTRN) detection (Wiszniowski et al. 2014). Both methods gave similar results, showing four previously unknown seismic events located in the Gulf of Gdańsk area, situated in the southern Baltic Sea. In this paper we discuss both detection methods with their pros and cons (accuracy, efficiency, manual work required, scalability). We also show details of all detected and previously unknown events in the discussed area. 相似文献