Groundwater pesticides residue in the southwest of Iran-Shushtar plain

Study area with an area of about 415 km² is located from 31°40′ to 32°05′ northern latitudes and 48°45′ to 49°00′ eastern longitudes 85 km to the north-east of Ahwaz city, in the north of Khuzestan province, and south west of Iran. The purpose of this study is: (1) the determination of the pesticides concentration in the groundwater of the Shushtar plain (Mian-Ab) and (2) the assessment of geology, hydrogeology and anthropogenic activities impacts the groundwater quality. Thirty-seven groundwater samples were taken from product wells based on the standard methods. A simple and efficient automated method for extraction and preconcentration was used. In this method, a pyrrole-based polymer was synthesized and applied as an efficient sorbent for micro-solid-phase extraction. After extraction, analytes were desorbed in ethyl acetate and analyzed using gas chromatography–flame. The study area is surrounded by Aghajari Formation dominated by silt and clay sediments and the Bakhtiari Formation dominated by sand and gravel. Existence of these formations affects the aquifer sediments and the hydrogeological properties. In the study area, the sediments grade from gravel and sand in the north and east into silt and clay to the south and west, respectively. The topsoil in the south of the study area contains more clay sediments. In this study, the concentration of two common herbicides, i.e., 2,4-D and clodinafop propargyl and two pesticides, i.e., permethrin and diazinon, in the groundwater of Mian-Ab aquifer was assessed. Chemical analysis results showed that the 2,4-D residue in the groundwater has the highest concentration (15 ppm). About 50% of the samples have concentration values more than the maximum contamination level based on EPA drinking standard. The pesticides concentrations decrease from the north to the south of the study area. Pesticides influx to the groundwater in the south of the area is prevented or diminished due to the specific geological situation and soil type. Distribution pattern of population centers, which increase to the north of the study area, and the role of groundwater as the main source of drinking water are two important issues that must be considered in management of pesticides use in the area.     

Hazards of mechanized tunnel excavation in H<Subscript>2</Subscript>S bearing ground in Aspar tunnel,Iran

Occurrence of hydrogen sulfide gas (H₂S) is one of the most important engineering geological hazards during tunneling. Its hazards and consequent challenges are very difficult and costly to solve. During site investigation, one of the tasks for engineering geologists is prediction and evaluation of the risk of H₂S gas in the underground spaces. In this study, water conveyance tunnel of Aspar, which was excavated in H₂S-bearing environments, is discussed. The tunnel is excavated in the hydrocarbon formations. Applied experiments suggest that geological formations pertaining to hydrocarbon resources are crucial in formation and reservation of H₂S gas. This paper briefly discusses hazards and geological sources of H₂S, as well as remedial measures for decreasing the risks and problems in excavation of the tunnel. To predict the risk of H₂S gas in the underground spaces, it is possible to use some precursors such as: sulfur springs, organic traces, organic argillaceous rocks, exposure of H₂S odor from fresh surface of rock and smell of H₂S during boreholes drilling. Controlling the inflow of groundwater into the excavation, diluting the concentration of H₂S, training the personnel and utilization of some proper safety equipment have been used to mitigate risks and problems in tunnel excavation.     

Basin analysis study of block 10 in the Say'un-Masilah Basin, Yemen, using a 1D backstripping method

Geohistory analysis was carried out on block 10 in the Say??un-Masilah Basin. The present study is based on the analysis of the well logs of six exploration wells. In the Middle Jurassic to the Middle Eocene, Say??un-Masilah Basin exhibited a complex subsidence history over a period of about 155?Ma. Backstripped subsidence curves are constructed by removing the effects of decompaction to the water column and sediment loads. In the Middle Jurassic, slow subsidence was driven under the effect of sediment load as Kuhlan and Shuqra Formations were deposited as pre-rift deposits. The average total subsidence value of the basement during the deposition of Shuqra Formation was 276?m. The highest subsidence rates during this time are observed northeast of the study area. Rapid subsidence initiated in the Upper Jurassic driven by mechanical extension of the rift, resulting in the deposition of Madbi and Safer Formations, or the so-called Syn-rift deposits. The average tectonic subsidence value of the basements during the deposition of Madbi Formation was 368?m. The highest subsidence rates during this time are observed southwest of the study area. Mechanical extension ceased at about 145?Ma, being replaced by a phase of post-rift subsidence, resulting in more widespread uniform sedimentation, with reduced tectonic subsidence rates forming post-rift deposits represented by Nayfa Formation, Sa??ar Formation, Biyad Formation, and Mahra Group. The total subsidence value of the basement during the deposition of the post-rift sediments increases gradually due to the increase of the sediment load as the rate of deposition was high especially northeast of the area.     

Age and tectonic setting of the Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide deposit, southern Iran

The Bavanat Cu–Zn–Ag Besshi-type volcanogenic massive sulfide (VMS) deposit occurs within the Surian volcano-sedimentary complex in the Sanandaj–Sirjan zone (SSZ) of southern Iran. The Surian complex is comprised of pelite, sandstone, calcareous shale, basalt, gabbro sills, and thin-bedded limestone. Mineralization occurs as stratiform sheet-like and tabular orebodies hosted mainly by greenschist metamorphosed feldspathic and quartz feldspathic sandstone, basalt, and pelites. The basalts of the Surian complex show predominantly tholeiitic to transitional affinities, with a few samples that are alkalic in composition. Primitive mantle-normalized trace and rare earth element (REE) patterns of the Surian basalts display depletions in light REE, negative anomalies of Nb, Ta, and Ti, and positive anomalies of P. Positive P anomalies are indicative of minor crustal contamination. Furthermore, Th enrichments in the mid-ocean ridge basalt-normalized patterns of the Surian basalts are characteristic of rifted arc basalts emplaced in continental margin subduction zones. The high MgO content (>6?wt.%) of most Surian basalts and low TiO₂ content of two samples (0.53 and 0.62?wt.%) are characteristic of boninites. The aforementioned features of the basalts indicate arc tholeiites emplaced in intra-arc rift environments and continental margin subduction zones. U–Pb dating by laser ablation- inductively coupled plasma mass spectrometry of detrital zircons extracted from the host feldspathic and quartz feldspathic sandstone yields various ages that are predominantly Permian and Triassic; however, the youngest zircons give a mean Early Jurassic concordant U–Pb age of 191?±?12?Ma. This age, together with geological and petrochemical data, indicate that VMS mineralization formed in the Early Jurassic in pull-apart basins within the SSZ. These basins and the VMS mineralization may be temporally related to an intra-arc volcano–plutonic event associated with Neo-Tethyan oblique subduction.     

A new well behaved class of charge analogue of Adler’s relativistic exact solution

The paper presents a new class of parametric interior solutions of Einstein–Maxwell field equations in general relativity for a static spherically symmetric distribution of a charged perfect fluid with a particular form of electric field intensity. This solution gives us wide range of parameter, K (0.69≤K≤7.1), for which the solution is well behaved hence, suitable for modeling of superdense star. For this solution the gravitational mass of a superdense object is maximized with all degree of suitability by assuming the surface density of the star equal to the normal nuclear density ρ _nm=2.5×10¹⁷kg?m^?3. By this model we obtain the mass of the Crab pulsar M _Crab=1.401M _⊙ and the radius, R _Crab=12.98 km constraining the moment of inertia I _NS,38>1.61 for the conservative estimate of Crab nebula mass 2M _⊙ and M _Crab=2.0156M _⊙ with radius, R _Crab=14.07 km constraining the moment of inertia I _NS,38>3.04 for the newest estimate of Crab nebula mass 4.6M _⊙ which are quite well in agreement with the possible values of mass and radius of Crab pulsar. Besides this, our model yields the moments of inertia for PSR J0737-3039A and PSR J0737-3039B are I _A,38=1.4624 and I _B,38=1.2689 respectively. It has been observed that under well behaved conditions this class of parametric solution gives us the maximum gravitational mass of causal superdense object 2.8020M _⊙ with radius 14.49 km, surface redshift z _R =0.4319, charge Q=4.67×10²⁰ C, and central density ρ _c =2.68ρ _nm.     

Elemental characterization of black shales of Khyber Pakthunkhawa (KPK) region of Pakistan using AAS

Black shale samples were collected from Chimiari Khyber Pakthunkhawa region of Pakistan and were analyzed for elemental compositions. Atomic Absorption Spectrophotometry (AAS) was utilized for the determination of elements in the digested solutions. The analysis of black shale was performed precisely with relative standard deviation (RSD) lower than 2%. Results showed that the samples contained high concentrations of Ca (11.98 %), Al (7.09%), Fe (3.03%), Mg (0.59%) and Ti (0.58%).     

Biostratigraphy and Paleoecology of Maastrichtian Sediments in the Zagros Basin, Iran

To enable the lithostratigraphic and biostratigraphic study of the Gurpi Formation,within the ‘Dezak’ or Globigerina Marl,a stratigraphic section at Booraki,located to the NNW of Shiraz,SW Iran,through the late Cretaceous was examined.The formation consists of shale and greenish-gray marls interbedded with cream limestone,brown sandstones and siltstones with an exposed thickness of 160 m in the studied section.Samples were taken at regular intervals in all yielding 14 genera and 16 different species of benthic and planktic foraminifera that allowed determination of the age of the beds as Maastrichtian.To examine the paleoecology of the formation,some important ecological factors including water level,salinity,and oxygen regime change during the depositional courses of the formation were analyzed.The density of foraminiferans decreases from the base to top of the Gurpi Formation whereas the ratio of planktic to benthic Foraminifera(i.e.,P/B) and proportion of shallow-water fauna increase.These foraminiferal changes indicate an increase and decrease in depth,temperature,salinity and oxygen,respectively,at the base and top of the Formation.     

Monte Carlo analysis of the effect of spatial distribution of storms on prioritization of flood source areas

Implementation of structural and non-structural flood control measures in flood-prone watersheds is on increasing demand. Different watershed areas are not necessarily hydrologically similar and impose variable effects on the outlet flow hydrograph. Meanwhile, prioritization of watershed areas in terms of flood generation is essential for economic flood control planning. Previous works have focused on the definition of a flood index that quantifies the contribution of each subwatershed unit or grid cell to the outlet flood hydrograph through the application of unit flood response (UFR) approach. In the present research, for the first time, the effect of spatial pattern of storm events on the flood index variation was assessed via a Monte Carlo uncertainty analysis. To do so, the UFR approach was carried out for a large number of randomly generated rainfall spatial pattern. The proposed methodology was adopted to the Tangrah watershed in northern Iran. The watershed is frequently hit by floods that have historically caused loss of life and properties. The results indicated that for the more frequent flood events, the flood index is quite sensitive to the spatial distribution of rainfall such that for the highest ranked subwatershed (SW6), the standardized variation of the flood index values (i.e., the uncertainty range) decreases from 1.0 to 0.5 when the rainfall depth increases from 20 to 150 mm, respectively. The results further revealed that increasing the rainfall depth from 20 to 150 mm would cause the effect of rainfall spatial distribution on subwatersheds’ flood indices to diminish. The implications are that if flood control measures are designed for more frequent floods with lower return periods, an uncertainty analysis is required to identify the range of flood index variations.     

Seismic response evaluation of the linked column frame system

The linked column frame (LCF) system is proposed as a seismic load resisting system that uses conventional components to limit seismic damage to relatively easily replaced elements. The LCF features a primary lateral system, denoted the linked column, which is made up of dual columns connected with replaceable links, and a secondary flexible moment frame system with beams having fully restrained connections at one end and simple connections at the other. The linked columns are designed to limit seismic forces and provide energy dissipation via link yielding, while preventing damage to the moment frame under certain earthquake hazard levels. A design procedure is proposed that ensures plastic hinges develop in the links of the linked columns at a significantly lower story drift than when plastic hinges develop in the moment frame beams. The large drift difference helps enable design of this system for two distinct performance states: rapid return to occupancy, where only link damage occurs and relatively simple link replacement is possible, and collapse prevention, where both the links and the beams of the moment frame may be damaged. A series of 3‐story, 6‐story, and 9‐story prototype LCF buildings were designed using the proposed design approach. Nonlinear models were developed for the designs with the link models validated using recent experimental results. The seismic response of these systems was investigated for ground motions representing various seismic hazard levels. Results show that the LCF system not only provides collapse prevention, but also has the capability of limiting economic loss by reducing structural damage and allowing for rapid return to occupancy following earthquakes with shorter return periods. Copyright © 2012 John Wiley & Sons, Ltd.     

Nonlinear analysis of seasonality and stochasticity of the Indus River

Abstract

One of the world's largest irrigation networks, based on the Indus River system in Pakistan, faces serious scarcity of water in one season and disastrous floods in another. The system is dominated both by monsoon and by snow and glacier dynamics, which confer strong seasonal and inter-annual variability. In this paper two different forecasting methods are utilized to analyse the long-term seasonal behaviour of the Indus River. The study also assesses whether the strong seasonal behaviour is dominated by the presence of low-dimensional nonlinear dynamics, or whether the periodic behaviour is simply immersed in random fluctuations. Forecasts obtained by nonlinear prediction (NLP) and the seasonal autoregressive integrated moving average (SARIMA) methods show that the performance of NLP is relatively better than the SARIMA method. This, along with the low values of the correlation dimension, is indicative of low-dimensional nonlinear behaviour of the hydrological dynamics. A relatively better performance of NLP, using an inverse technique, may also be indicative of the low-dimensional behaviour. Moreover, the embedding dimension of the best NLP forecasts is in good agreement with the estimated correlation dimension. This provides evidence that the nonlinearity inherent in the monthly river flow due to the snowmelt and the monsoon variations dominate over the high-dimensional components and might be exploited for prediction and modelling of the complex hydrological system.

Citation Hassan, S. A. & Ansari, M. R. K. (2010) Nonlinear analysis of seasonality and stochasticity of the Indus River. Hydrol. Sci. J. 55(2), 250–265.