Flow dynamics at the origin of thin clayey sand lacustrine turbidites: Examples from Lake Hazar,Turkey

Turbidity currents and their deposits can be investigated using several methods, i.e. direct monitoring, physical and numerical modelling, sediment cores and outcrops. The present study focused on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in eleven clusters of closely spaced thin beds. Depositional processes and sources for three of those eleven clusters are studied at three coring sites. Bathymetrical data and seismic reflection profiles are used to understand the specific geomorphology of each site. X‐ray, thin sections and CT scan imagery combined with grain‐size, geochemical and mineralogical measurements on the cores allow characterization of the turbidites. Turbidites included in each cluster were produced by remobilization of surficial slope sediment, a process identified in very few studies worldwide. Three types of turbidites are distinguished and compared with deposits obtained in flume studies published in the literature. Type 1 is made of an ungraded clayey silt layer issued from a cohesive flow. Type 2 is composed of a partially graded clayey sand layer overlain by a mud cap, attributed to a transitional flow. Type 3 corresponds to a graded clayey sand layer overlain by a mud cap issued from a turbulence‐dominated flow. While the published experimental studies show that turbulence is damped by cohesion for low clay content, type 3 deposits of this study show evidence for a turbulence‐dominated mechanism despite their high clay content. This divergence may in part relate to input variables, such as water chemistry and clay mineralogy, that are not routinely considered in experimental studies. Furthermore, the large sedimentological variety observed in the turbidites from one coring site to another is related to the evolution of a sediment flow within a field‐scale basin made of a complex physiography that cannot be tackled by flume experiments.     

Potential use of faujasite–phillipsite and phillipsite–chabazite tuff in purification of treated effluent from domestic wastewater treatment plants

Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.     

Geophysical signature of the vien-type uranium mineralization of Wadi Eishimbai, Southern Eastern Desert, Egypt

The application of various geophysical tools with different responses succeeded in fixing U-mineralization in Wadi Eishimbai area. The area was studied using detailed ground spectrometric, magnetic, and filtered very low-frequency electromagnetic (VLF-EM) surveys. The interpretation of the obtained spectrometric maps clearly reflects the sharp increase of equivalent uranium (eU) content. Meanwhile, K and Th contents show sharp decreases. The eU/equivalent thorium (eTh) ratio correlates positively with eU concentrations and negatively with eTh concentrations, indicating an increase in U potentiality than the surrounding granite. The N?CS shear zone displays an eU content ranging from 20 to 140?ppm. The ENE-trending lamprophyre is characterized by elongated uranium anomalies trending in the E?CW direction, with values >90?ppm. Equivalent uranium content of the brecciated granite attains values up to 700?ppm. The ground magnetic and VLF-EM surveys played important roles in providing structural information which are proven useful in geological mapping and mineral exploration for the discovery of uranium mineralization in the study area. This study follows the expected subsurface extension of the Sela shear zone under Wadi sediments. The ground total magnetic intensity map shows a relatively narrow and an elongated shape for the lamprophyre anomaly extending for about 600?m in the Wadi toward the western direction. VLF-EM contour maps of the two used frequencies (17.1 and 28.5?kHz) show excellent agreement, indicating that the shear zone is distinguished with slightly strong conductivity westwards as an extension of the main shear zone. It is elongated in an ENE?CWSW trend and extends in the western direction, referring to the existence of conductive materials. Most of the NW/SE-trending faults cause sudden changes in the magnetic and VLF-EM contour spacing over an appreciable distance, which suggests a discontinuity in depth due to their left-lateral strike-slip displacements. The interpreted faults, with an ENE?CWSW trend representing the main trend of Sela shear zone through which hydrothermal solutions flowed, cause high alteration and uranium mineralization.     

Hydro-mechanical evaluation of stabilized mine tailings

. In this study, mine tailings waste was stabilized using a combination of lime, fly ash type "C", and aluminum. Treated samples were subjected to mineral identification for evaluating the formation of ettringite and gypsum. Also, unconfined compression, hydraulic conductivity, and cyclic freeze and thaw tests were performed to evaluate the hydro-mechanical properties of the stabilized samples. Experimental results have shown that the application of lime and fly ash type "C" to high sulfate content tailings has improved its plasticity, workability, and volume stability. Moreover, upon addition of aluminum to lime and fly ash in a sulfate-rich environment, ettringite and calcium sulfo-aluminate hydrate are formed in these samples. Application of 5% lime, 10% fly ash type "C", in combination with 110 ppm aluminum, resulted in the formation of a solid monolith capable of producing more than 1,000 kPa of unconfined compressive strength, and reduced tailings permeability to 1.96᎒^–6 cm s^–1, which is less than the recommended permeability of 10^–5 cm s^–1 by most environmental protection agencies for reusability of solidified/stabilized samples. The permeability of the treated tailings samples remained below the recommended permeability, even after exposing the treated samples to 12 freeze and thaw cycles. Therefore, based on the experimental results, it is concluded that treatment of high sulfate-content tailings with lime and fly ash, combined with the availability of aluminum for reactions, is a successful method of solidifying highly reactive mine tailings.     

Occurrence of diagenetic pseudobreccias within the paleokarst zone of the upper Dammam Formation in Kuwait, Arabian Gulf

A paleokarstic zone capping the Middle Eocene dolomitic Dammam Formation delineates a regional disconformity with the overlying Mio-Pleistocene fluvial deposits in Kuwait. This formation outcrops in a quarry located in the southeast of Kuwait and occurs in the subsurface of Umm Ghudair water field, west Kuwait. Karstification has affected the upper member of the Dammam Formation, which is formed of extensively chertified, vuggy chalky biodolomicrite. Karstification is manifested by two phases: a dissolution phase that was responsible for the occurrence of surface and near surface karst features and a precipitation phase during which a karst carapace and dolocretic and calcitic pseudobreccias were developed. Petrographic investigations of both the biodolomicrites host rock and the karst lithotypes revealed a complex diagenetic history that encompasses the following diagenetic events, arranged in a chronological order: (a) replacive dolomitization, (b) precipitative dolomitization, (c) precipitative silica, (d) replacive silica, (e) karstification, (f) development of karst carapace [calcretization and calcitization (development of calcitic psuedobreccia)], (g) dolocretization (development of dolocretic psuedobreccia), (h) mild karstification, (i) calcite precipitation, and (j) silica precipitation. The development of the karst carapace at the unconformity surface between the Eocene Dammam Formation dolomicrites and the overlying Mio-Pleistocene Kuwait Group clastics has played a significant role in the hydrological characteristics of Kuwait usable groundwater resources. It is recommended that the occurrence of similar diagenetic processes within the Arabian carbonate shelf deposits be investigated.     

Petrology and geochemistry of prograde deserpentinized peridotites from Happo-O’ne, Japan: Evidence of element mobility during deserpentinization

The prograde deserpentinized peridotites from the talc zone in the Happo-O’ne complex, central Japan, show differences in their field relation and mineral assemblage with the high-P retrograde peridotites of the other part of the complex. They show a mineral assemblage, olivine + talc + antigorite ± prograde tremolite ± chlorite, formed by thermal metamorphism around the granitic intrusion at T, 500-650 °C and P < 7 kbar. The olivine has numerous opaque inclusions and high Fo (91.5-96.5) relative to the retrograde olivine, reflecting its formation by deserpentinization. The prograde tremolite, which is low in Al₂O₃ (<1.0 wt.%), Cr₂O₃ (<0.35 wt.%), and Na₂O (<0.6 wt.%) but high in Mg# (up to 0.98) and SiO₂ (up to 59.9 wt.%), is different in size, shape and chemistry from the retrograde tremolite. The prograde peridotites display a U-shaped REE pattern (0.02-0.5 times PM), similar to diopside-zone retrograde metaperidotites, possible protoliths. They are enriched in LILE (e.g., Cs, Pb, Sr, Rb) relative to HFSE (e.g., Ta, Hf, Zr, Nb), like their protoliths, because of their local re-equilibration with the fluid released during dehydration of the protoliths. They have high contents of REE and some trace elements (e.g., Cs, Th, U, Ta) relative to their protoliths because of an external-element addition from the granitic magma. In-situ analyses of peridotitic silicates confirmed that the prograde tremolite and talc display a spoon-shaped primitive mantle (PM)-normalized REE pattern (0.1-3 times PM) in which LREE are higher than HREE contents. The prograde tremolite is depleted in Al, Na, Cr, Sc, V, Ti, B, HREE and Li, but is enriched in Si, Cs, U, Th, HFSE (Hf, Zr, Nb, Ta), Rb and Ba relative to the retrograde tremolite; the immobile-element depletion in this tremolite is inherited from its source (antigorite + secondary diopside), whereas the depletion of mobile elements (e.g., Li, B, Na, Al) is ascribed to their mobility during the deserpentinization and/or the depleted character of the source of tremolite. The enrichment of HFSE and LILE in the prograde tremolite is related to an external addition of these elements from fluid/melt of the surrounding granitic magma and/or in situ equilibrium with LILE-bearing fluid released during dehydration of serpentinized retrograde metaperidotites and olivine-bearing serpentinites (protoliths). The prograde olivine is higher in REE and most trace-element contents than the retrograde one due to the external addition of these elements; it is enriched in B, Co and Ni, but depleted in Li that was liberated during deserpentinization by prograde metamorphism.     

Provenance,weathering, and paleoenvironment of the Upper Cretaceous Duwi black shales,Aswan Governorate,Egypt

The mineralogy and geochemistry of the Upper Cretaceous Duwi black shales of Nile Valley district, Aswan Governorate, Egypt, have been investigated to identify the source rock characteristics, paleoweathering, and paleoenvironment of the source area. The Duwi Formation consists mainly of phosphorite and black shales and is subdivided into three members. The lower and upper members composed mainly of phosphorite beds intercalated with thin lenses of gray shales, while the middle member is mainly composed of gray shale, cracked, and filled with gypsum. Mineralogically, the Duwi black shales consist mainly of smectite and kaolinite. The non-clay minerals are dominated by quartz, calcite, phosphate, dolomite, feldspar, with little gypsum, anhydrite, iron oxides, and pyrite. Based on the CIA, PIA, and CIW values (average?=?84, 94, 95, respectively), it can be concluded that the litho-components of the studied shales were subjected to intense chemical weathering and reflect warm/humid climatic conditions in the depositional basin. The provenance discrimination diagram indicates that the nature of the source rocks probably was mainly intermediate and mafic igneous sources with subordinate recycled sedimentary rocks (Nubia Formation). Geochemical characteristics indicate that the Duwi black shales in Nile Valley district were deposited under anoxic reducing marine environments.     

The best fitting distribution of annual maximum rainfall in Peninsular Malaysia based on methods of L-moment and LQ-moment

This paper discusses patterns of annual and monthly precipitation variability at seven weather stations in east central Europe (1851–2007). Precipitation patterns were compared to three simple regional indices of atmospheric circulation, i.e., western circulation, southern circulation and the cyclonicity (C) index and a relationship between precipitation and the North Atlantic Oscillation index was identified. Correlations of the monthly records and multiple regression, using a principal components’ analysis, helped determine the statistical significance of the dependence of precipitation on the circulation indices. The Mann–Kendall test revealed no trend to change in any of the precipitation series, but a certain spatial regularity could be discerned in the phase of the annual periodic component. A common feature of the variability in central European annual precipitation is the dry period identified in the 1980s and the first half of the 1990s. In the northern part of the region, above-average precipitation was noted from the 1960s through to the mid-1970s as a result of the frequent prevalence of depressions. South of the divide, the wettest period was recorded at the turn of 1930s/1940s. After a number of very wet years in the last decade of the twentieth century and the beginning of the twenty-first century, precipitation began to fall at all of the region’s weather stations. The C index is the strongest circulation-linked factor influencing precipitation in central Europe and it accounts for more than 40% of the variance in spatially averaged wintertime precipitation.     

Spatial distribution and structure of benthic polychaete communities of Essaouira intertidal rocky shores (Atlantic coast of Morocco)

Polychaetes are one of the most important groups of macrobenthic organisms in coastal and marine environments, in terms of diversity and abundance, and play an important role in the functioning of ecosystem. This study aims to describe the structure and spatial distribution of polychaete communities along Essaouira's rocky shoreline(Atlantic coast of Morocco) in relation to the major environmental variables such as granulometry, salinity, temperature, pH, and intertidal range. Twelve sites from these intertidal rocky shores were sampled using a quadrat method during the summer 2016. A total of 4 435 individuals belonging to 34 taxa were recorded. Among the families, Sabellaridae(24%) and Nereididae(23%) were ranked ?rst in terms of abundance of individuals. Sabellaria alveolata(24%) and Perinereis cultrifera(13%) were the dominant species. Diversity( H′) values varied from 2.28 to 3.95. Pielou's index( J′) varied between 0.62 and 0.89. This was essentially due to the low dominance of few species. Cluster analysis was used to characterise Essaouira's rocky shores on the basis of benthic polychaete communities. SIMPER analysis con?rmed the presence of three distinct communities. According to canonical correspondence analysis, the structure and distribution of faunal assemblages of benthic polychaetes was mainly related to topographical complexity, water temperature, hydrodynamic conditions and upwelling. We conclude that these rocky shores show typically high benthic polychaete diversity compared to the taxonomic list of other rocky coasts. In addition, these results constitute a baseline data for the development of a sustainable network for long-term monitoring of benthic polychaete community changes due to ecological factor in?uences and anthropogenic activity impacts.