Mineralogy and Isotope Geochemistry of Active Submarine Hydrothermal Field at Suiyo Seamount, Izu–Bonin Arc, West Pacific Ocean

This report presents mineralogical, geochemical and isotopic data on samples obtained using the Benthic Multi‐coring System (BMS) to drill a submarine hydrothermal deposit developed in a caldera on the summit of the Suiyo Seamount in the Izu–Bonin Island Arc, south of Japan. This deposit is regarded as the first example of Kuroko‐type sulfide mineralization on a volcano at the volcanic front of an island arc. The mineralization and hydrothermal alteration below the 300 × 150‐m area of active venting was investigated to depths of 2–9 m below the sea floor. Drilling beneath the area of active venting recovered a sequence of altered volcanic rocks (dacite lavas, pyroclastic rocks of dacite–rhyolite compositions and pumice) associated with sulfide veining and patches/veins of anhydrite. No massive sulfide was found, however, and the subsea‐floor mineralization to 10 m depth is dominated by anhydrite and clay minerals with some sulfides. Sulfide‐bearing samples contained high Au (up to 42 ppm), Ag (up to 263 ppm), As (up to 1550 ppm), Hg (up to 55 ppm), Sb (up to 772 ppm), and Se (up to 24 ppm). Electron probe microanalyzer indicated that realgar, orpiment, and mimetite were major As‐bearing minerals. The sulfides were also characterized by high Zn (>10%) compared to Cu (<6.3%) and Pb (<0.6%). The δ²⁰²Hg/¹⁹⁸Hg, δ²⁰²Hg/¹⁹⁹Hg and δ²⁰²Hg/²⁰⁰Hg of the sulfide‐bearing dacite samples and a sulfide chimney decreased with increasing Hg/Zn concentration ratio. The variation of the δ²⁰²Hg/¹⁹⁸Hg ranged from ?2.8 to +0.5‰ to relative to S‐HG02027. The large range of these δ²⁰²Hg/¹⁹⁸Hg was greater than might be expected for such a heavy element and may be due to a predominance of kinetic effects. The variation of δ²⁰²Hg/¹⁹⁸Hg of sulfide‐bearing dacite samples suggested that light Hg isotope in the vapor mixed with oxygenated seawater near sea floor during mineralization. Lead isotope ratios of the sulfide were very similar to those of the dacite lava, suggesting that lead is of magmatic origin. The ⁸⁷Sr/⁸⁶Sr ratio (0.70872) of anhydrite was different from that of the dacite lava, and suggests an Sr derivation predominantly from seawater. Hydrothermal alteration of the dacite in the Suiyo hydrothermal field was characterized by Fe‐sulfides, anhydrite, barite, montmorillonite, chlorite/montmorillonite mixed‐layer minerals, mica, and chlorite with little or no feldspar or cristobalite. Hydrothermal clay minerals changed with depth from montmorillonite to chlorite/montmorillonite mixed‐layer minerals to chlorite and mica. Hydrogen isotope ratios of chlorite/montmorillonite and mixed‐layer, mica‐chlorite composites obtained below the active venting sites ranged from ?49 to ?24‰, suggesting seawater as the dominant fluid causing alteration. Oxygen isotope ratios of anhydrite ranged from 9.2 to 10.4‰ and anhydrite formation temperatures were calculated to be 188–207°C. Oxygen isotope ratios ranged from +5.2 to +9.2‰ for montmorillonite, +3.2 to +4.5‰ for chlorite/montmorillonite mixed‐layer minerals, and +2.8 to +3.8‰ in mixtures of chlorite and mica. The formation temperatures of montmorillonite and of the chlorite–mica mixture were 160–250°C and 230–270°C, respectively. The isotope temperatures for clay minerals (220–270°C) and anhydrite (188°C) were significantly lower than the borehole temperature (308.3°C) measured just after the drilling, suggesting that temperature at this site is now higher than when clay minerals and anhydrite were formed.     

Redeposition of volcaniclastic sediments by a tsunami 4600 years ago at Kushima City,south-eastern Kyushu,Japan

The Hyuga-nada Sea, south-eastern Kyushu, Japan, is located between a strong (Nankai Trough) and a weak interplate coupling zone (Ryukyu Trench). Over the past 400 years this area has only experienced Magnitude 7·5 earthquakes or smaller and associated small-scale tsunamis. However, this short historical record most likely does not include the full range of high magnitude, low frequency giant earthquakes that might have occurred in the region. Thus, it is still unclear whether giant earthquakes and their associated tsunamis have occurred in this region. This paper reports on a prehistoric tsunami deposit discovered in a coastal lowland in south-eastern Kyushu facing the Hyuga-nada Sea. There is a reddish-brown pumiceous layer preserved in a non-marine, organic-rich mud sequence obtained from onshore sediment cores. This layer is recognized as the ca 4600 year old Kirishima-Miike tephra (that is now placed around 4500 years ago) sourced from Mount Kirishima, southern Kyushu. Another whitish pumiceous layer is evident below the Kirishima-Miike tephra in almost all of the sediment cores. A relatively high percentage of marine and brackish diatoms is recorded within this lower pumiceous layer (but not in the surrounding muds or in the overlying Kirishima-Miike tephra), indicating a marine or beach sediment source. Plant material obtained from organic-rich mud immediately below the event layer was dated to ca 4430 to 4710 cal yr bp , providing a limiting-maximum age for this marine incursion event. The presence of marine diatoms below the event layer is probably explained by pre-seismic subsidence. An absence of the resting spore of the planktonic brackish diatom Cheatoceros and the appearance of the freshwater diatom Eunotia serra immediately above the event layer probably represents a marked change to a relatively low-salinity environment. Assuming that there were no significant local geomorphological changes, such as drainage obstruction caused by formation of a new barrier spit, it is considered that co-seismic or immediate post-seismic uplift are the most likely explanations for this notable environmental change. Based on the crustal movements noted before and after the marine incursion, this event is interpreted here as an earthquake-generated tsunami. Moreover, because of these notable seismic crustal movements the tsunamigenic earthquake probably occurred immediately offshore of the study site.     

Shock-induced phase change in BaZnGeO4 crystals

Shock-loading experiments are performed on single-crystal specimens of BaZnGeO₄ (BZG) between 13 and 51 GPa using a propellant gun and a two-stage light gas gun. Observation by an optical microscope reveals that all the shocked specimens are made of fragmented blocks of 10 ～ 100 μm in size. X-ray analyses indicate that the samples shocked to pressures above 41 GPa became a polycrystalline state of BZG with a weakly textured structure. A small amount of dissociation products of BaGeO₃ (pyroxene type) and ZnO (wurtzite type) are detected in this pressure range. Between 27 and 19 GPa, a new phase which is thought to be produced by considerable deformations in the ring structure consisting of ZnO₄ and GeO₄ tetrahedra is observed. Below 19 GPa, shocked specimens are brought into a well aligned mosaic structure, but no significant change in the crystal structure is detected.     

Middle Miocene to Quaternary primary basalt and high magnesian andesite magmas of North Hokkaido, Japan: Source mantle characteristics and degrees of partial melting

Abstract   Middle Miocene to Quaternary primitive basalts and high magnesian andesite (HMA) in North Hokkaido resulted from three periods of intense volcanism; early-stage (12–10 Ma), middle-stage (9–7 Ma) and late-stage (3–0 Ma). Based on the chemical compositions of olivines and chromian spinels and bulk chemistry of the primitive rocks, we examined depths of segregation of the calculated primary magmas and the degrees of partial melting of the source mantle. In the context of asthenospheric mantle upwelling, petrological data from the present study can be accounted for by the secular change in the depth of magma segregation from the upwelled asthenospheric mantle, which is composed of fertile peridotite. Thus, the early-stage primary magmas were generated by higher degrees of partial melting of the shallower part of hot asthenospheric mantle, whereas the middle- and late-stage primary magmas resulted from lower degrees of partial melting of a deeper part of the asthenospheric mantle. The early-stage HMA magma was generated by partial melting of the remnant subcontinental lithospheric mantle composed of refractory peridotite. This melting might have resulted from an increased geothermal gradient caused by upwelling of hot asthenosphere.     

230Th/234U and 14C dating of a lowstand coral reef beneath the insular shelf off Irabu Island, Ryukyus, southwestern Japan

Abstract   High-resolution seismic reflection profiles delineated the distribution of mound-shaped reflections, which were interpreted as reefs, beneath the insular shelf western off Irabu Island, Ryukyus, southwestern Japan. A sediment core through one of the mounded structures was recovered from the sea floor at a depth of −118.2 m by offshore drilling and was dated by radiometric methods. The lithology and coral fauna of the core indicate that the mounded structure was composed of coral–algal boundstone suggesting a small-scaled coral reef. High-precision α-spectrometric ²³⁰Th/²³⁴U dating coupled with calibrated accelerator mass spectrometric ¹⁴C ages of corals obtained reliable ages of this reef ranging from 22.18 ± 0.63 to 30.47 ± 0.98 ka. This proves that such a submerged reef was formed during the lowstand stage of marine oxygen isotope stages 3–2. The existence of low-Mg calcite in the aragonitic coral skeleton of 22.18 ± 0.63 ka provides evidence that the reef had once been exposed by lowering of the relative sealevel to at least −126 m during the last glacial maximum in the study area. There is no room for doubt that a coral reef grew during the last glacial period on the shelf off Irabu Island of Ryukyus in the subtropical region of western Pacific.     

Morphology and propagation styles of Miocene submarine basanite lavas at Stanley, northwestern Tasmania, Australia

Miocene submarine basanite pillows, lava lobes, megapillows and sheet lavas in the Stanley Peninsula, northwestern Tasmania, Australia, are well-preserved in three dimensions. The pillows have ropy wrinkles, transverse wrinkles, symmetrical wrinkles, contraction cracks and three types of spreading cracks on their surfaces, and concentric and radial joints in the interior. The lava lobes have ropy wrinkles and contraction cracks on their surfaces. The megapillows are cylindrical with a smoothly curved upper surface and steep sides, and are characterized by distinct radial columnar joints in the interior. They are connected to pillows that propagate radially from its basal margin. The sheet lavas are tabular and have vertical columnar joints in the interior. The largest sheet lava shows a remarkable gradation from a lower 5-m-thick pillow facies to an upper massive facies. The pillows, lava lobes, megapillows and sheet lavas are inferred to have been emplaced completely below sea level but in a shallow marine environment. Their morphological features suggest that the pillows grew by episodic rupture of a near-solid crust and emergence of hot lava, whereas the lava lobes propagated by continuous stretching of the outer skin at the flow front. The megapillows and sheet lavas were master feeder channels by which molten lava was conveyed to the advancing pillows. The sheet lavas propagated by repeated processes of pillow formation and overriding by an upper massive part. Alternating pillow and massive facies commonly found in ocean-floor drill cores and exposed in cross-section in many subaqueous volcanic successions may have formed by propagation of pillows from the basal margins of advancing sheet lavas.     

Viscosity measurements of hydrous rhyolitic melts using the fiber elongation method

We have devised a new, simple and easy technique to measure the viscosity of hydrous silicate melts by combining an autoclave for melt hydration and the fiber elongation method for viscosity measurement. Using this, we measured the viscosity of hydrous rhyolitic melts whose water content ranges from 0.02 to 0.58 wt%. We observed a drastic decrease in viscosity against water content: 0.1 wt% water decreases the viscosity about an order of magnitude. Even when the water content is only 0.02 wt%, the viscosity decreased about half an order of magnitude. These results clearly demonstrate that the effect of water on viscosity should not be ignored even when it occurs as a trace constituent. We compared our experimental data with those derived from a non-Arrhenian viscosity model, which is considered to be applicable to calc-alkaline samples. This model succeeded in expressing the viscosity variation against water content but was unable to accurately predict the measured viscosity of liquids.Editorial responsibility: D. Dingwell     

Resistivity structure of a seismic gap along the Atotsugawa Fault, Japan

Seismicity along the Atotsugawa Fault, located in central Japan, shows a clear heterogeneity. The central segment of the fault with low-seismicity is recognized as a seismic gap, although a lot of micro-earthquakes occur along this fault. In order to elucidate the cause of the heterogeneity in seismicity, the electrical resistivity structure was investigated around the Atotsugawa Fault by using the magnetotelluric (MT) method. The regional geoelectrical strikes are approximately parallel to the fault in a low-frequency range. We constructed two-dimensional resistivity models across the fault using TM-mode MT responses to minimize three-dimensional effects on the modeling process. A smooth inversion algorithm was used, and the static-shifts on the apparent resistivity were corrected in the inversion process.A shallow, low resistivity zone along the fault is found from the surface to a depth of 1-2 km in the best-fit model across the high-seismicity segment of the fault. On the other hand, the corresponding low resistivity zone along the low-seismicity segment is limited to a shallower depth less than 1 km. The low resistivity zone along the Atotsugawa Fault is possibly due to fluid in the fracture zone; the segment with higher levels of seismicity may have higher fluid content in the fault zone compared with the lower seismicity segment. On a view of the crustal structure, a lateral resistivity variation in a depth range of 3-12 km is found below the fault trace in the high-seismicity segment, while a resistive layer of wide extent is found at a depth of about 5 km below the fault trace in the low-seismicity segment. The resistive layer is explained by less fluid condition and possibly characterized as high rigidity. Differences in the resistivity structures between low and high-seismicity segments of the fault suggest that the seismic gap in the central part of the Atotsugawa Fault may be interpreted as a locked segment. Thus, MT is an effective method in evaluating a cause and future activity of seismic gaps along active faults.The lower crust appears as a conductive zone beneath the low-seismicity segment, less conductive beneath the high-seismicity segment. Fluid is inferred as a preferable cause of the conductive zone in this study. It is suggested that the conductive lower crust beneath the low-seismicity segment is recognized where fluid is trapped by an impermeable layer in the upper crust. On the other hand, fluid in the lower crust may upwell to the surface along the high-seismicity segment of the fault.     

Vesiculation and crystallization under instantaneous decompression: Numerical study and comparison with laboratory experiments

Vesiculation and crystallization in ascending magmas are key processes that control the eruption behavior, and they interplay each other through the water exsolution process. We conducted a numerical study in order to quantitatively understand the water exsolution and crystallization processes in natural eruptions (decompression history is unknown) and in laboratory experiments (the amount of decompression is constant with time). The numerical results, which take into account homogeneous or heterogeneous nucleation and growth of bubbles with varying diffusivity of water, viscosity, and the amount of decompression, provide a quantitative understanding of their control on bubble formation and water exsolution in the constant amount of decompression. The bubble nucleation in the homogeneous nucleation can be divided into two regimes – the diffusion control regime and viscosity control regime – depending on the modified Peclet number and the effective supersaturation. In the cases of both homogeneous and heterogeneous nucleations, the bubble growth is controlled by diffusion or viscosity, depending on the modified Peclet number and bubble number density. The water exsolution rate, which is controlled by the modified Peclet number in the viscosity control regime and by the bubble number density and diffusive driving force in the diffusion control regime, acts as an effective cooling rate in a decompression-induced crystallization process. A comparison of the numerical results with the results of laboratory experiments suggests that water exsolution proceeds by the diffusion-limited growth of bubbles under disequilibrium vesiculation through the heterogeneous nucleation of bubbles, and this in turn controls the crystallization kinetics of microlite with the homogeneous nucleation of microlite and the diffusion-limited growth of crystal. The several orders of variation of microlite number density with the amount of decompression in laboratory experiments can be interpreted as the effect of the amount of decompression on the driving force for the diffusive bubble growth that controls the water exsolution rate.     

Distribution of boulders at Miyara Bay of Ishigaki Island,Japan: A flow characteristic indicator of tsunami and storm waves

This study investigates the distribution of boulders at Miyara Bay of Ishigaki Island, Japan. These boulders were deposited on a reef flat extending approximately 400–1300 m in width. Most boulders were rectangular to ellipsoidal, without sharp broken edges. They are reef and coral rock fragments estimated as <335 m³ (<633 t). Locally in the bay, the relationship between the boulder weight and position shows that boulders of a given weight have a clear limit on seaward distribution on the reef flat. For example, more than 1, 10, and 100 tons of boulders were deposited, respectively, more than 500, 300, and 100 m from the reef edge. The line is consistent with the possible landward transport limit by maximum storm waves at the Ryukyu Islands, suggesting that the line was formed by the reworking of some boulders by maximally strong storm waves, although we can not exclude the possibility that the line was formed by tsunamis. Furthermore, 68% of boulders at the bay are deposited beyond this line. Therefore, the presence of these boulders at their present positions is difficult to explain solely by storm waves, implying the possible tsunami origin of these boulders. The boulders are characteristically concentrated along the high‐tide line, suggesting the drastic reduction of the tsunami hydraulic force along the line. Previous studies using radiocarbon age dating, as well as our study, imply that at least 69 boulders at Miyara Bay were probably deposited at their present positions by the 1771 Meiwa tsunami, although some of these boulders might have been emplaced and displaced on the reef flat by prior tsunami or storm surges.