Soil radon in winter months under snowpack in Hokkaido, Japan

Soil radon (²²²Rn) has been monitored during winter months under cool-temperate deciduous stands of different surface geology in Tomakomai and in Sapporo, Hokkaido, Japan. Radon level was lower in Tomakomai of immature soil of porous volcanic ash emitted from an active volcano (Mt. Tarumae), compared with those in Sapporo of alluvial sediments. In Tomakomai, mean value of the ²²²Rn activity concentration was higher in winter (570 Bq m^?3) than in summer (350 Bq m^?3) at a depth of 1 m, which is consistent with the results in cold and dry winter reported in the literature. In contrast, soil radon decreasing with decreasing soil temperature from mid-September (5.0 kBq m^?3) remained low (2.6 kBq m^?3) under persistent snow in Sapporo, which had already been observed in the same location. Measurements of the activity concentrations of ²²²Rn in snow and in snow air as well as in soil air indicate that the small amount of ²²²Rn is released from the ground surface to the overlying snowpack with a ²²²Rn flux density of 0.4 mBq m^?2 s^?1 under thick snow cover in Sapporo.     

Reconstruction and post-event analysis of a flash flood in a small ungauged basin: a case study in Slovak territory

Flash floods are one of the major natural hazards occurring in small streams with a negative effect on the country as well as on human lives. Heavy rainfall occurred on July 20, 2014 and July 21, 2014 and caused severe surface water flooding and a flash flood in the Malá Fatra National Park (Slovakia). The most affected was Vrátna Valley with the Varínka stream. This study presents a reconstruction and post-event analysis of a flash flood on small ungauged basin located in this protected area of Slovakia. The reconstruction included hydraulic terrain measurements on estimating the flood’s culmination and documenting the flood’s development. The measurements were taken at three cross sections of the Varínka stream. This paper is focused mainly on post-event analysis of the Varínka stream in two profiles: Strá?a (gauged profile) and Tiesňavy (ungauged cross section). Subsequently, the extremeness of the flash flood was preliminary evaluated. Results of the post-event analysis showed that the July 2014 flood was not the highest flood in this area despite its catastrophic consequences. By studying historical materials, we came to the conclusion that in the past (e.g. in 1848 or 1939) some devastating floods in this area had occurred, which had disastrous consequences for the population. The second part of the study is focused on comparing this flash flood with three major floods which have occurred in Slovak territory since 1998. The first flood occurred on the 20th of July, 1998 on the Malá Svinka stream, and the two others are floods which occurred on the 7th of June, 2011 in the Small Carpathian Mountains: on the Gidra stream in Píla village and on the Parná stream in Horné Ore?any village. Such comparison of flash floods from different geographical regions and different rainfall events can provide comprehensive information about their regimes, threats and disastrous effects.     

A late Holocene climate record in stalagmites from Modrič Cave (Croatia)

Few terrestrial Holocene climate records exist from south‐eastern Europe despite its important geographical position as a transitional climatic zone between the Mediterranean and mainland continental Europe. Here we present new petrographic and stable isotope data for two Holocene speleothems from Modri? Cave, Croatia (44°15′N, 15°32′E), a coastal Adriatic site (120 m inland). Modern meteorological and cave conditions have been monitored for 2 years to understand the links between climate variability and stable isotope time‐series records in speleothems. Typical of a Mediterranean‐type climate, a negative water balance exists between April and September, so that recharge of the aquifer is restricted to the winter months. The weighted mean δ¹⁸O of the rainfall is ?5.96‰ (2σ = 2.83), and the weighted mean D/H rainfall value is ?36.83‰ (2σ = 19.95), slightly above the Global Meteoric Water Line, but well below the Mediterranean Meteoric Water Line. Modern calcite from the tops of each stalagmite exhibits δ¹⁸O values that are close to isotopic equilibrium with their respective drip water values. Unfortunately, the relatively young ages and low uranium contents (ca. 50 p.p.b.) of both stalagmites hamper the use of U‐series dating. Radiocarbon dates have been used instead to constrain their chronology using a dead carbon correction. Apart from some Isotope Stage 3 material (ca. 55 ka), both stalagmites were deposited during the late Holocene. Climatic conditions during the late Holocene are inferred to have been sufficiently wet to maintain stalagmite growth and any hiatuses appear to be relatively short lived. Inferred changes in the stalagmite diameters during deposition are linked to δ¹³C and δ¹⁸O variations, indicating alternating periods of drier and wetter conditions. Drier conditions are inferred for the late Roman Ages warm period and the mid‐Medieval Warm Period. Wetter conditions are associated with the Little Ice Age. Copyright © 2012 John Wiley & Sons, Ltd.     

Adsorptive removal of eight heavy metals from aqueous solution by unmodified and modified agricultural waste: tangerine peel

Analysis was carried out using tangerine peel aiming its use as a potential adsorbent of eight heavy metal ions (Cd, Co, Cr, Cu, Mn, Ni, Pb and Zn) from aqueous solution. This agricultural waste was tested both in its untreated and also chemically modified form. Based on Fourier transformation infrared spectra, a comparison of biosorbent structure before and after chemical treatment was made. Batch adsorption tests were conducted at different pH and mass of sorbent to examine the influence on the effectiveness of simultaneous removal of tested ions. Kinetic studies were conducted at optimum pH 5.0 and sorbent dosage 300 mg. The pseudo-second-order kinetic model best fit the experimental data with high correlation coefficients (r² > 0.9997). By optimizing listed parameters, high removal efficiencies (> 89%) were achieved. According to the results obtained in this study, the remediation of water polluted with heavy metals could be done using modified tangerine peel as an agricultural waste material.     

Decolourisations and biodegradations of model azo dye solutions using a sequence batch reactor,followed by ultrafiltration

The main objective of this study was to investigate the efficiency of biological treatment of azo dye-containing wastewater with a sequencing batch reactor system, followed by ultrafiltration. The performance of the system was quantified by measuring the chemical oxygen demand and azo dye concentration. The biodegradation was carried out under combined alternating anaerobic and aerobic conditions with Nylosan Yellow E2RL SGR as a model azo dye contaminant. The bioprocess revealed a maximal reduction in chemical oxygen demand and dye removal efficiency of 91 and 85%, respectively. After ultrafiltration of effluent from the biological treatment, the efficiency increased to 94% for chemical oxygen demand and to 97% for the azo dye decolourisation. Samples of activated sludge from the bioprocess were collected for microbial characterisation. Bacteria and fungi were isolated and identified by 16S rRNA gene and ITS1-5.8S rDNA-ITS2 sequence analysis, respectively. Serratia marcescens and Klebsiella oxytoca were the most common bacteria with the highest number present during the aerobic and anaerobic phases of the bioprocess. In addition, a high number of Elizabethkingia miricola, Morganella morganii, Comamonas testosteroni, Trichosporon sp. and Galactomyces sp. were detected. Taken together, our results demonstrated that the sequencing batch reactor system combined with ultrafiltration is an efficient technique for treatment of wastewater containing azo dye. Moreover, the ultrafiltration effectively removes the microbiota from the final effluent resulting in stable product water.     

Protection of karst aquifers in the Dinarides in Croatia

 This paper presents karst water protection measures being introduced in the Dinarides of Croatia. The spring sites for the water supply of the town of Rijeka, for its 200 000 inhabitants and the largest harbor of the northeastern side of the Adriatic Sea, have been used as a pilot research area. The European research project was used, and protection of water was generally divided into three phases. A categorization of springs has been made, and five basic protection zones have been distinguished. The rules of behavior in protected zones have been outlined. For the first time, the term water-supply "reserve" has been introduced, referring to the parts of the mountainous region where karst groundwater is recharged. Received: 26 March 1997 · Accepted: 22 July 1997