Generation of isoprenoid compounds,notably prist-1-ene,via photo- and autoxidative degradation of vitamin E

In order to mimic the photodegradation of vitamin E during phytoplankton senescence and study the behaviour of the resulting photoproducts during cell lysis, vitamin E dispersed in seawater was irradiated with solar light in the presence of hematoporphyrin as sensitizer. Under these conditions, singlet oxygen-mediated photooxidation and free radical oxidation (autoxidation) acted simultaneously on the substrate, affording 4,8,12-trimethyltridecanal, 4,8,12-trimethyltridecanoic acid, 6,10,14-trimethylpentadecan-2-one, α-tocopherylquinone, 4,8,12,16-tetramethylheptadecan-4-olide, 2,3-epoxy-α-tocopherylquinone and 5,6-epoxy-α-tocopherylquinone as minor products. Different mechanisms were proposed to explain the formation of these different isoprenoids. The main products (85% of the degraded substrate) appeared to be previously described diastereoisomeric trimeric oxidation products of vitamin E, whose pyrolysis during gas chromatography–mass spectrometry (GC–MS) afforded 2,6,10,14-tetramethylpentadec-1-ene (prist-1-ene). On the basis of their greater ability to produce prist-1-ene during pyrolysis than intact vitamin E and their highly favoured production in phytoplanktonic cells, these trimers are proposed as likely sources of this isoprenoid alkene, previously identified in many pyrolysates from immature kerogens.     

Accelerated ions observed in the plasma sheet boundary layer: Beams or streams?

We present an analysis of two crossings of the plasma sheet boundary layer (PSBL) in Earth’s magnetotail by a quartet of Cluster satellites, accomplished both in the absolutely quiet geomagnetic interval and in the restoration period between two substorms. It is found that in the quiet period, field-aligned electric currents were not observed in the PSBL, in spite of presence in this region of high-velocity ions moving toward Earth along the magnetic field lines at velocities of ∼1400 km/s. This means that in the given event, ions and electrons moved together; i.e., high-velocity ions were a part of the accelerated plasma flow. In the disturbed period, the Cluster satellites detected a system of two oppositely directed field-aligned currents, which can be associated with the presence of the X line rather close to the Earth. Owing to multipoint Cluster observations, we managed to estimate the spatial size of a current structure (along the normal to the PSBL surface), which was equal, for a current flowing toward Earth along the high-latitude PSBL boundary, to about 1600 km, which is comparable with the value of the inertial radius of ions. This agrees with the scenario of spatial separation of charges and formation of the Hall system of currents in the magnetic reconnection region. The duration of observation of the given current structure was ∼12 min., which points to the quasi-steady-state character of reconnection.     

ASK: Auroral Structure and Kinetics in action

Mina Ashrafi, winner of the Rishbeth Prize at the 2007 NAM, describes the work in her group at Southampton on the questions that a new multi-spectral imager – ASK – can answer about auroral structure and processes.     

江西省汛期暴雨气候特点及预报方法综合分析

概括介绍了江西省汛期暴雨的气候特点、汛期暴雨环流形势和天气系统特征,以及针对江西省汛期暴雨的预报方法研究进展。最后,提出了未来一段时间江西省暴雨预报方法研究的主要方向,认为应该将暴雨过程的天气尺度和中尺度特征与地形特征相结合,开发暴雨预报方法并建立暴雨预报模式。