Evaluation of climatic change through harmonic analysis

In the present work, a precipitation and temperature series from Barcelona (Spain) are analysed in order to detect the possible existence of climatic changes or cycles. The analysis is carried out both from the temporal and spectral standpoints. The techniques used range from the classical periodogram and Blackman-Tukey method through to the Maximum Entropy method. The results do not show the existence of climatic cycles, though they do show a clear tendency toward increased precipitation and decreased temperature, since the last years of series.     

Calcium-aluminum-rich inclusions in the Allende meteorite: evidence for a liquid origin

We have made a detailed examination of the mineralogy, textures and assemblages of six calcium-aluminum-rich inclusions (CAI) in the Allende meteorite. They can be classified into four types—hibonite-bearing, fassaite- and olivine-bearing, feldspathoid-bearing and fassaite-bearing CAI that are hibonite and olivine free. Examples of each type appear to have crystallized from a liquid rather than by agglomeration of solid nebular condensates. Some lines of evidence for a liquid origin are (1) the presence of spherical and ovoid shapes, (2) rims containing minerals (e.g. hibonite, perovskite) that are more refractory than minerals inside the inclusion, (3) eutectic and poikilitic textures, (4) minerals that are completely enclosed by more refractory minerals and (5) glass and fine-grained grossular stringers.Thermodynamic calculations and comparisons with liquidus phase diagrams indicate that the CAI could have been produced by direct condensation to metastable subcooled liquids that subsequently crystallized (blander and Katz, 1967) or by remelting of an equilibrium high-temperature condensate by impact. The diopside rims in some hibonite-bearing CAI and the paucity of metal in fassaite-olivinebearing CAI are more consistent with direct condensation of a liquid. The sluggishness of solid-solid reactions at the relatively high temperatures at which the CAI formed argues against assuming equilibrium in calculations at lower temperatures.     

Mesoscale variability in the Bransfield Strait region (Antarctica) during Austral summer

The Bransfield Strait is one the best-known areas of Antarctica’s oceanic surroundings. In spite of this, the study of the mesoscale variability of its local circulation has been addressed only recently.This paper focuses on the mesoscale structure of local physical oceanographic conditions in the Bransfield Strait during the Austral summer as derived from the BIOANTAR 93 cruise and auxiliary remote sensing data. Moreover, data recovered from moored current meters allow identification of transient mesoscale phenomena.     

A large marine ecosystem governance framework

A large marine ecosystem (LME) governance framework, developed from a need to effectively address the sustainable management of the shared living marine resources of the Caribbean, is proposed. The framework is based on four propositions and focuses on a linked examination of two well-known components of LME-level governance: the policy cycle process by which decisions are made and the multi-level nature of LMEs. It accommodates the diversity of policy cycles at multiple levels and the linkages among them required for effective governance of LMEs. The framework takes into account of factors such as context, purpose, jurisdictional scale, capacity and complexity and provides a means to identify critical areas for intervention.     

Delimitation of ground failure zones due to land subsidence using gravity data and finite element modeling in the Querétaro valley, México

Sedimentary basins of arid and semiarid zones are often subject to regimes of intense ground-water withdrawal as it is normally the only source of water for development of communities. An associated phenomenon is land subsidence, which can develop to ground failures, and consequently, damage to infrastructure. Aquifer deformation can be analyzed using a stress–strain or a flux–force approach depending on the aquifer material (compact or loose) and on whether the water withdrawal forms a predominant flow direction toward a cone of depression. Geometry of the aquifer system also plays an important role as uneven thickness induces differential compaction and hence, tensional and shear stresses on the ground mass. In this work we present a stress–strain approach to analyze subsidence for an unconfined aquifer of varying thickness; this is done in two steps, namely when the aquifer is in equilibrium, and when it is totally depleted. Using this scheme in a region where ground failure is evident, a portion of the aquifer system of the Querétaro valley is analyzed. The geometry of the hydrologic basement is first modeled using gravity measurements properly correlated with wells and field data. Then a stress analysis is implemented using the finite element method in order to identify probable zones of ground weakness, which are calibrated with known ground failures. The results indicate that both, tensional and shear stress are present, which induce ground failure in the form of surface faults.     

Reductions in TBT concentrations in UK estuaries following legislation in 1986 and 1987

In 1986 the Government of the United Kingdom (UK) introduced legislation to control the sale of tribytltin (TBT)-based paints. From 1986 to 1989 monitoring was undertaken, whereby samples of water, sediment, oysters (Crassostrea gigas) and mussels (Mytilus edulis) were collected from six estuaries and water samples from five marinas/harbours, and analysed for TBT. In 1989 the concentrations of TBT in water, oysters and mussels were generally only one-third to one-quarter of those observed in 1986. The most marked decrease in concentrations of TBT in oysters and mussels occurred in 1987–1988, following the 1987 ban on the use of TBT-based paints on small boats and mariculture equipment. As the concentrations of TBT in oyster tissues had decreased there has been improvement in oyster growth in terms of both meat production and growth of thin (i.e. normally shaped) shells. Oysters with a normal shell shape can now be grown in five of the six estuaries which were monitored. In contrast to the reduction in concentrations of TBT noted in water and bivalves, changes in concentrations of TBT in sediments showed no clear trend from 1986 to 1989.     

Cloning a new cytochrome P450 isoform (CYP356A1) from oyster Crassostrea gigas

We have cloned the full-length cDNA of the first member of a new cytochrome P450 (CYP) family from the Pacific oyster Crassostrea gigas. This new CYP gene was obtained based on an initial 331bp fragment previously identified among the list of the differentially expressed genes in oysters exposed to untreated domestic sewage. The full-length CYP has an open reading frame of 1500bp and based on its deduced amino acid sequence was classified as a member of a new subfamily, CYP356A1. A phylogenetic analysis showed that CYP356A1 is closely related to members of the CYP17 and CYP1 subfamilies. Semi-quantitative RT-PCR was performed to analyze the CYP356A1 expression in different tissues of the oyster (digestive gland, gill, mantle and adductor muscle). Results showed slightly higher CYP356A1 expression in digestive gland and mantle, than the other tissues, indicating a possible role of the CYP356A1 in xenobiotic biotransformation and/or steroid metabolism.     

Deep high spectral resolution spectroscopy and chemical composition of ionized nebulae

High spectral resolution spectroscopy has proved to be very useful for the advancement of chemical abundances studies in photoionized nebulae, such as H II regions and planetary nebulae (PNe). Classical analyses make use of the intensity of bright collisionally excited lines (CELs), which have a strong dependence on the electron temperature and density. By using high resolution spectrophotometric data, our group has led the determination of chemical abundances of some heavy element ions, mainly O⁺⁺, O⁺, and C⁺⁺ from faint recombination lines (RLs), allowing us to deblend them from other nearby emission lines or sky features. The importance of these lines is that their emissivity depends weakly on the temperature and density structure of the gas. The unresolved issue in this field is that recombination lines of heavy element ions give abundances that are about 2–3 times higher than those derived from CELs – in H II regions – for the same ion, and can even be a factor of 70 times higher in some PNe. This uncertainty puts into doubt the validity of face values of metallicity that we use as representative not only for ionized nebulae in the Local Universe, but also for star‐forming dwarf and spiral galaxies at different redshifts. Additionally, high‐resolution data can allow us to detect and deblend faint lines of neutron capture element ions in PNe. This information would introduce further restrictions to evolution models of AGBs and would help to quantify the chemical enrichment in s‐elements produced by low and intermediate mass stars. The availability of an échelle spectrograph at the E‐ELT will be of paramount interest to: (a) extend the studies of heavyelement recombination lines to low metallicity objects, (b) to extend abundance determinations of s‐elements to planetary nebulae in the extragalactic domain and to bright Galactic and extragalactic H II regions. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Brightness fluctuations in the K-line wings

A power-spectrum and cross-spectrum analysis has been made of measurements of temporal fluctuations of intensity observed in the K-line wing (2.07 Å from line center) and of simultaneous measurements of temporal fluctuations of Doppler displacement of the cores of 3931.122 Fe i and 3933 Ca ii (K₃). The measurements were made in a quiet region near the center of the Sun's disk. We find that the average power spectra of the intensity fluctuations have two significant peaks of about equal strength: one at 0.0033 Hz (300-s period); and one at about 0.001 Hz (1000-s period). The average rms value of these intensity fluctuations is 0.0435±0.0082. Maximum brightness comes before maximum violet displacement of the Fe i line. The mean of the best determined phases is 137° and of all the data 108°. At those places on the Sun where the 300-s oscillations can be identified in the k₃ core, the Doppler displacement of the Fe i line leads that of the K₃ core by a mean phase angle of 27°.