Trapped liquid from a nepheline syenite: a re-evaluation of Na-, Zr-, F-rich interstitial glass in a xenolith from Tenerife, Canary Islands

Interstitial glass and pyroxene in a nepheline syenite described by Wolff (1987) have been more precisely and accurately re-analysed using a cryogenic microprobe technique. The glass compositions, with Na₂O = 13.4−17.0 wt.% and (Na+K)/Al = 1.81−2.26 at SiO₂ = 53−56.5 wt.% (on a 100% normalised basis) are more extreme than any known erupted magma. ZrO₂ contents of the glasses are 1.4%–1.8% by weight, while F ranges between 1% and 1.4%. The high Zr content is due to the failure of a Zr-silicate phase to precipitate, despite predicted zircon saturation of the liquids above their probable quench temperatures. Partitioning of Zr between pyroxene and liquid is highly variable and apparently controlled by sector zoning; Zr is preferentially incorporated into aegirine {001} growth sectors. The glasses demonstrate the extent to which peralkaline phonolitic liquids can be fractionated in closed magma systems.     

On Stable Chaos in the Asteroid Belt

The twenty most chaotic objects found among first hundred of numbered asteroids are studied. Lyapunov time calculated with and without inner planets indicates that for eleven of those asteroids the strongest chaotic effect results from the resonances with Mars. The filtered semimajor axis displays an abrupt variation only when a close approach to Mars takes place. The study of the behaviour of the critical argument for candidate resonances can reveal which is responsible for the semimajor axis variation. We have determined these resonances for the asteroids in question. For the asteroids chaotic even without the inner planets we have determined the most important resonances with Jupiter, or three-body resonances. This revised version was published online in July 2006 with corrections to the Cover Date.     

Unsuitability of TAC management within an ecosystem approach to fisheries: An ecological perspective

Fisheries management in European waters is gradually moving from a single-species perspective towards a more holistic ecosystem approach to management (EAM), acknowledging the need to take all ecosystem components into account. Prerequisite within an EAM is the need for management processes that directly influence the ecological effects of fishing, such as the mortality of target and non-target species. Up until recently, placing limits on the quantities of fish that can be landed, through the imposition of annual total allowable catches (TACs) for the target species, has been the principal management mechanism employed. However, pressure on non-target components of marine ecosystems is more closely linked to prevailing levels of fishing activity, so only if TACs are closely related to subsequent fishing effort will TAC management serve to control the broader ecosystem impacts of fishing. We show that in the mixed fisheries that characterise the North Sea, the linkage between variation in TAC and the resulting fishing effort is in fact generally weak. Reliance solely on TACs to regulate fishing activity is therefore unlikely to mitigate the impacts of fishing on non-target species. Consequently, we conclude that the relationship between TACs and effort is insufficient for TACs to be used as the principal management tool within an EAM. The implications, and some alternatives, for fisheries management are discussed.     

Effect of viscous damping devices on the response of seismically isolated structures

Viscous and other damping devices are often used as elements of seismic isolation systems. Despite the widespread application of nonlinear viscous systems particularly in Japan (with fewer applications in the USA and Taiwan), the application of viscous damping devices in isolation systems in the USA progressed intentionally toward the use of supplementary linear viscous devices due to the advantages offered by these devices. This paper presents experimental results on the behavior of seismically isolated structures with low damping elastomeric (LDE) and single friction pendulum (SFP) bearings with and without linear and nonlinear viscous dampers. The isolation systems are tested within a six‐story structure configured as moment frame and then again as braced frame. Emphasis is placed both on the acquisition of data related to the structural system (drifts, story shear forces, and isolator displacements) and on non‐structural systems (floor accelerations, floor spectral accelerations, and floor velocities). Moreover, the accuracy of analytical prediction of response is investigated based on the results of a total of 227 experiments, using 14 historic ground motions of far‐fault and near‐fault characteristics, on flexible moment frame and stiff braced frame structures isolated with LDE or SFP bearings and linear or nonlinear viscous dampers. It is concluded that when damping is needed to reduce displacement demands in the isolation system, linear viscous damping results in the least detrimental effect on the isolated structure. Moreover, the study concludes that the analytical prediction of peak floor accelerations and floor response spectra may contain errors that need to be considered when designing secondary systems. Copyright © 2014 John Wiley & Sons, Ltd.     

Trophic modeling of the Northern Humboldt Current Ecosystem, Part I: Comparing trophic linkages under La Niña and El Niño conditions

The El Niño of 1997–98 was one of the strongest warming events of the past century; among many other effects, it impacted phytoplankton along the Peruvian coast by changing species composition and reducing biomass. While responses of the main fish resources to this natural perturbation are relatively well known, understanding the ecosystem response as a whole requires an ecotrophic multispecies approach. In this work, we construct trophic models of the Northern Humboldt Current Ecosystem (NHCE) and compare the La Niña (LN) years in 1995–96 with the El Niño (EN) years in 1997–98. The model area extends from 4°S–16°S and to 60 nm from the coast. The model consists of 32 functional groups of organisms and differs from previous trophic models of the Peruvian system through: (i) division of plankton into size classes to account for EN-associated changes and feeding preferences of small pelagic fish, (ii) increased division of demersal groups and separation of life history stages of hake, (iii) inclusion of mesopelagic fish, and (iv) incorporation of the jumbo squid (Dosidicus gigas), which became abundant following EN. Results show that EN reduced the size and organization of energy flows of the NHCE, but the overall functioning (proportion of energy flows used for respiration, consumption by predators, detritus and export) of the ecosystem was maintained. The reduction of diatom biomass during EN forced omnivorous planktivorous fish to switch to a more zooplankton-dominated diet, raising their trophic level. Consequently, in the EN model the trophic level increased for several predatory groups (mackerel, other large pelagics, sea birds, pinnipeds) and for fishery catch. A high modeled biomass of macrozooplankton was needed to balance the consumption by planktivores, especially during EN condition when observed diatoms biomass diminished dramatically. Despite overall lower planktivorous fish catches, the higher primary production required-to-catch ratio implied a stronger ecological impact of the fishery and stresses the need for precautionary management of fisheries during and after EN. During EN energetic indicators such as the lower primary production/total biomass ratio suggest a more energetically efficient ecosystem, while reduced network indicators such as the cycling index and relative ascendency indicate of a less organized state of the ecosystem. Compared to previous trophic models of the NHCE we observed: (i) a shrinking of ecosystem size in term of energy flows, (ii) slight changes in overall functioning (proportion of energy flows used for respiration, consumption by predators and detritus), and (iii) the use of alternate pathways leading to a higher ecological impact of the fishery for planktivorous fish.