The Rožná uranium deposit (Bohemian Massif, Czech Republic): shear zone-hosted, late Variscan and post-Variscan hydrothermal mineralization

Three major mineralization events are recorded at the Rožná uranium deposit (total mine production of 23,000 t U, average grade of 0.24% U): (1) pre-uranium quartz-sulfide and carbonate-sulfide mineralization, (2) uranium, and (3) post-uranium quartz-carbonate-sulfide mineralization. (1) K–Ar ages for white mica from wall rock alteration of the pre-uranium mineralization style range from 304.5 ± 5.8 to 307.6 ± 6.0 Ma coinciding with the post-orogenic exhumation of the Moldanubian orogenic root and retrograde-metamorphic equilibration of the high-grade metamorphic host rocks. The fluid inclusion record consists of low-salinity aqueous inclusions, together with H₂O-CO₂-CH₄, CO₂-CH₄, and pure CH₄ inclusions. The fluid inclusion, paragenetic, and isotope data suggest that the pre-uranium mineralization formed from a reduced low-salinity aqueous fluid at temperatures close to 300°C. (2) The uraniferous hydrothermal event is subdivided into the pre-ore, ore, and post-ore substages. K–Ar ages of pre-ore authigenic K-feldspar range from 296.3 ± 7.5 to 281.0 ± 5.4 Ma and coincide with the transcurrent reorganization of crustal blocks of the Bohemian Massif and with Late Stephanian to Early Permian rifting. Massive hematitization, albitization, and desilicification of the pre-ore altered rocks indicate an influx of oxidized basinal fluids to the crystalline rocks of the Moldanubian domain. The wide range of salinities of fluid inclusions is interpreted as a result of the large-scale mixing of basinal brines with meteoric water. The cationic composition of these fluids indicates extensive interaction with crystalline rocks. Chlorite thermometry yielded temperatures of 260°C to 310°C. During this substage, uranium was probably leached from the Moldanubian crystalline rocks. The hydrothermal alteration of the ore substage followed, or partly overlapped in time, the pre-ore substage alteration. K–Ar ages of illite from ore substage alteration range from 277.2 ± 5.5 to 264.0 ± 4.3 Ma and roughly correspond with the results of chemical U–Pb dating of authigenic monazite (268 ± 50 Ma). The uranium ore deposition was accompanied by large-scale decomposition of biotite and pre-ore chlorite to Fe-rich illite and iron hydrooxides. Therefore, it is proposed that the deposition of uranium ore was mostly in response to the reduction of the ore-bearing fluid by interaction with ferrous iron-bearing silicates (biotite and pre-ore chlorite). The Th data on primary, mostly aqueous, inclusions trapped in carbonates of the ore substage range between 152°C and 174°C and total salinity ranges over a relatively wide interval of 3.1 to 23.1 wt% NaCl eq. Gradual reduction of the fluid system during the post-ore substage is manifested by the appearance of a new generation of authigenic chlorite and pyrite. Chlorite thermometry yielded temperatures of 150°C to 170°C. Solid bitumens that post-date uranium mineralization indicate radiolytic polymerization of gaseous and liquid hydrocarbons and their derivatives. The origin of the organic compounds can be related to the diagenetic and catagenetic transformation of organic matter in Upper Stephanian and Permian sediments. (3) K–Ar ages on illite from post-uranium quartz-carbonate-sulfide mineralization range from 233.7 ± 4.7 to 227.5 ± 4.6 Ma and are consistent with the early Tethys-Central Atlantic rifting and tectonic reactivation of the Variscan structures of the Bohemian Massif. A minor part of the late Variscan uranium mineralization was remobilized during this hydrothermal event.     

Statistical Analysis of Water Quality Parameters in Seven Major Serbian Rivers during 2004‒2013 Period

Rivers on territory of the Republic of Serbia can be separated to three sea drainage basins: Black, Adriatic and Aegean. Majority of rivers belong to the Black Sea drainage basin. The Danube is the most important river in Serbia and one of the most important rivers of Europe. All rivers investigated in this paper represent direct or indirect tributaries of the Danube River and as that, they are belonging to the Black Sea drainage basin. In this study, the water quality status and the spatial and temporal trends of seven major rivers in Serbia were assessed through the application of ten parameters of Water Quality Index. Ten year (2004–2013) public database of environmental data was used. Into considerations were taken differences between every river individually and difference between sample positions on every single river. Based on the chemical parameters of water quality, it can be seen that the biggest rivers in Serbia show different values of WQ parameters. The highest WQ value is measured on the Drina River, while the lowest value is measured on the Ju?na Morava and the Tisza River. Analyses of parameters per period of year show that there is a statistically significant difference between values during warm and cold periods.     

Spatial variability in community structure of Dictyoceratida sponges across Torres Strait,Australia

Spatial variability in community structure of dictyoceratid sponges (class Demospongiae; order Dictyoceratida) was examined on coral reefs in Torres Strait, an archipelago of islands and reefs between northern Queensland, Australia, and Papua New Guinea. Dictyoceratid sponge abundances and environmental factors were recorded at four locations, separated by 50–220 km. Each location was subdivided into 5–7 sites, each ?2 km apart. At each site, four 50×2 m belt transects were quantitatively surveyed, recording the dictyoceratid numbers, substrate type (rock, rubble and sand), water clarity, degree of reef slope and depth. Dictyoceratid abundance was similar among locations over large spatial scales, averaging 15.5 individuals per 100 m², but varied significantly among sites within particular locations (i.e. small scale heterogeneity). Twenty-three dictyoceratid species were recorded in Torres Strait, with approximately half (12/23) found in only one location. The canonical correspondence analysis determined that the measured environmental factors explained only 26% of the spatial variation. Cluster analysis revealed a complex dictyoceratid community structure with similarities among neighbouring sites and among sites separated by hundreds of kilometres. Conversely the abundance and composition of dictyoceratids could vary greatly between neighbouring sites 2 km apart and on the same reef complex. The results of this study suggest that spatial variability of dictyoceratid sponges in Torres Strait is influenced by a combination of environmental, biological and stochastic processes.     

Distinguishing strongly rheomorphic tuffs from extensive silicic lavas

High-temperature silicic volcanic rocks, including strongly rheomorphic tuffs and extensive silicic lavas, have recently been recognized to be abundant in the geologic record. However, their mechanisms of eruption and emplacement are still controversial, and traditional criteria used to distinguish conventional ash-flow tuffs from silicic lavas largely fail to distinguish the high-temperature versions. We suggest the following criteria, ordered in decreasing ease of identification, to distinguish strongly rheomorphic tuffs from extensive silicic lavas: (1) the character of basal deposits; (2) the nature of distal parts of flows; (3) the relationship of units to pre-existing topography; and (4) the type of source. As a result of quenching against the ground, basal deposits best preserve primary features, can be observed in single outcrops, and do not require knowing the full extent of a unit. Lavas commonly develop basal breccias composed of a variety of textural types of the flow in a finer clastic matrix; such deposits are unique to lavas. Because the chilled base of an ashflow tuff generally does not participate in secondary flow, primary pyroclastic features are best preserved there. Massive, flow-banded bases are more consistent with a lava than a pyroclastic origin. Lavas are thick to their margins and have steep, abrupt flow fronts. Ashflow tuffs thin to no more than a few meters at their distal ends, where they generally do not show any secondary flow features. Lavas are stopped by topographic barriers unless the flow is much thicker than the barrier. Ash-flow tuffs moving at even relatively slow velocities can climb over barriers much higher than the resulting deposit. Lavas dominantly erupt from fissures and maintain fairly uniform thicknesses throughout their extents. Tuffs commonly erupt from calderas where they can pond to thicknesses many times those of their outflow deposits. These criteria may also prove effective in distinguishing extensive silicic lavas from a postulated rock type termed lava-like ignimbrite. The latter have characteristics of lavas except for great areal extents, up to many tens of kilometers. These rocks have been interpreted as ash-flow tuffs that formed from low, boiling-over eruption columns, based almost entirely on their great extents and the belief that silicic lavas could not flow such distances. However, we interpret the best known examples of lava-like ignimbrites to be lavas. This interpretation should be tested through additional documentation of their characteristics and research on the boiling-over eruption mechanism and the kinds of deposits it can produce. Flow bands, flow folds, ramps, elongate vesicles, and probably upper breccias occur in both lavas and strongly rheomorphic tuffs and are therefore not diagnostic. Pumice and shards also occur in both tuffs and lavas, although they occur throughout ash-flow tuffs and generally only in marginal breccias of lavas. Dense welding, secondary flow, and intense alteration accompanying crystallization at high temperature commonly obliterate primary textures in both thick, rheomorphic tuffs and thick lavas. High-temperature silicic volcanic rocks are dominantly associated with tholeiitic flood basalts. Extensive silicic lavas could be appropriately termed flood rhyolites.     

Density inhomogeneities in the upper mantle of Central Europe and their gravitational effects

Summary Problems of occurrence of density inhomogeneities in the upper mantle are discussed and their gravitational effects in the region of Central Europe are investigated. Attention is namely devoted to the density contrast between the asthenosphere and the lower lithosphere, and its possible dependence on depth.

---

¶rt;am n nu nmm ¶rt;¶rt;m amuu u uaumau ¶rt;mu a mumuu ¶rt; n. uau ¶rt;m n¶rt; nmm mam ¶rt; am u um u auumu mu aau.

     

Optimization of Earth crust profiles by collocation

Summary A mathematical aid for optimizing Earth crust profiles was derived.     

Magnetic properties of high-Ti basaltic rocks from the Krušné hory/Erzgebirge MTS. (Bohemia/Saxony), and their relation to mineral chemistry

This study provides new thermomagnetic and petrographic data on specific basaltic rock association from the broader vicinity of the Lou?ná-Oberwiesenthal volcanic centre, western Bohemia/Saxony. Two types of volcanic rocks were recognized there: (i) high-Ti types (3.5–5.2 wt% TiO₂) represented by (mela)nephelinite s.s., and sporadically present (ii) medium-Ti types (2.5–3.5 wt% TiO₂) of olivine nephelinite, nepheline basanite and phonotephrite compositions. In order to examine the rock-magnetic behaviour, they were studied for their variations in the Curie temperature (T_C) and field-dependent susceptibility, spinel group minerals, chemistry and petrology. Magnetic susceptibility of ulvöspinel-rich titanomagnetite, as a dominant magnetic carrier, depends on the amplitude of measured magnetic field, whereas pure magnetite is field-independent. Field dependence parameter ^kHD of the studied basaltic rocks ranges from 0.8 to 18.7%, TiO₂ contents in titanomagnetite range from 12.7 to 20.1 wt.%. TiO₂ content in titanomagnetite does not correlate with whole-rock TiO₂ content (2.8 to 5.6 wt.%). The content of substituted titanium in the sublattice of magnetite is also sensitively reflected in the Curie temperature, ranging from 200 to 580°C. The spinel group minerals are designated as titanomagnetite with the dominance of ulvöspinel, magnetite and magnesioferrite components, or titanomagnetite with the magnetite, ulvöspinel and magnesioferrite components. Only two samples are characterized by a significant presence of Cr-spinel and magnesiochromite components forming cores of titanomagnetites. The titanomagnetite-bearing rocks in the studied area, likewise the low- to medium-Ti basaltic rocks from the ?eské st?edoho?í Mts., provide similar thermomagnetic curves.     

Assessing volcanic origins within detrital zircon populations——A case study from the Mesozoic non-volcanic margin of southern Australia

Detrital zircon U/Pb geochronology is a common tool used to resolve stratigraphic questions,inform basin evolution and constrain regional geological histories.In favourable circumstances,detrital zircon populations can contain a concomitant volcanic contribution that provides constraints on the age of deposition.However,for non-volcanic settings,proving isolated detrital zircon grains are from contemporaneous and potentially remote volcanism is challenging.Here we use same grain(U-Th)/He thermochronology coupled with U/Pb geochronology to identify detrital zircon grains of contemporary volcanic origin.(U-Th)/He ages from Cretaceous zircon grains in southern Australia define a single population with a weighted mean age of 104±6.1 Ma.indistinguishable from zircon U/Pb geochronology and palynology(～104.0-107.5 Ma).Detrital zircon trace-element geochemistry is consistent with a continental signature for parent rocks and coupled with detrital grain ages,supports derivation from a2000 km distant early-to mid-Cretaceous Whitsunday Volcanic Province in eastern Australia.Thus,integration of biostratigraphy,single-grain zircon double-dating(geochronology and thermochronology)and grain geochemistry enhances fingerprinting of zircon source region and transport history.A distal volcanic source and rapid continental-scale transport to southern Australia is supported here.