The restricted buffer capacity of a south Baltic estuary — The oder estuary

In the river Oder high-waters of the river with high nutrient loads and low biological activity mainly occur during winter. Thus, a remarkable portion of the annual load passes the estuary untransformed. During summer high level of biological activity is observed in the whole estuary, but while more than 10 mol/l dissolved inorganic nitrogen (DIN) is found in the Großes Haff, where the theoretical water-residence time is only 1 month, in the western part of the estuary, where the water-residence time is approximately 3 months, all DIN is transformed into organic matter.The transformed nutrients settle partly as biological products, but they are released again in these shallow waters due to biological and physical degradation, and transported into the Baltic Sea.This behaviour may explain why in the sediments of the Oderhaff with a sedimentation rate of 1 mm/year only 1% of the annual nutrient load of the Oder river can be found.     

An infrared spectroscopic and single-crystal X-ray study of malayaite, CaSnSiO5

Powder infrared spectroscopy and X-ray diffraction techniques on single crystals were used to study the thermal behaviour of malayaite, CaSnSiO₅. Infrared spectra show a discontinuity in the temperature evolution of phonon frequencies and absorbance near 500 K. However, crystal structure data collected at 300, 450, 550, 670, and 750 K show no evidence of a symmetry-breaking phase transition and no split positions. The most obvious change with heating is a tumbling motion of the SnO₆ octahedra and an increase of the anisotropic displacement factors of Ca. The thermal evolution of the mean-square vibrational amplitude of the Ca atom shows a pronounced change in slope near 500 K. The evidence suggests that the 500 K anomaly in malayaite is more similar in character to the 825 K (β-γ) transition as opposed to the 496 K (α-β) transition in synthetic titanite. Received: 26 March 1998 / Revised, accepted: 23 December 1998     

Shortage in the midst of plenty: Labour strategies in four Central and Eastern European cities

Labour shortage was an integral feature of the communist system of economic management and one that seemed most unlikely to persist in the face of systemic transformation. A casual examination of the unemployment rates that have emerged throughout most of Central and Eastern Europe (CEE) during the course of the past decade might suggest that this early assumption was correct. However, within the region the aggregate rate of joblessness, as well as the behaviour of national output, mask the fact that certain, major urban centres appear to have weathered well the storms caused by exposure to western markets and stringent fiscal and monetary policies. In these centres transformation has meant, to a greater or lesser degree, industrial modernisation and this begs the question of whether the human capital portfolios of the inherited labour force match up to the requirements of the new environment. This paper examines the meaning of the concept of labour shortage and presents the findings from a survey of employers in four leading cities of three major CEE economies designed to elicit if, and how, manpower requirements are being met in the present climate. The results indicate that, somewhat paradoxically, labour shortage persists in the more flexible markets of the post-communist era and that firms do not expect the situation to change radically in the near future. This revised version was published online in July 2006 with corrections to the Cover Date.     

Monitoring qualitative spatiotemporal change for geosensor networks

Recent technological advances in geosensor networks demand new models of distributed computation with dynamic spatial information. This paper presents a computational model of spatial change in dynamic regions (such as may be derived from discretizations of continuous fields) founded on embeddings of graphs in orientable surfaces. Continuous change, connectedness and regularity of dynamic regions are defined and local transition rules are used to constrain region evolution and enable more efficient inference of a region's state. The model provides a framework for the detection of global high‐level events based on local low‐level ‘snapshot’ spatiotemporal data. The approach has particular relevance to environmental monitoring with geosensor networks, where technological constraints make the detection of global behaviour from local conditions highly advantageous.     

Water Table Uncertainties due to Uncertainties in Structure and Properties of an Unconfined Aquifer

We consider two sources of geology‐related uncertainty in making predictions of the steady‐state water table elevation for an unconfined aquifer. That is the uncertainty in the depth to base of the aquifer and in the hydraulic conductivity distribution within the aquifer. Stochastic approaches to hydrological modeling commonly use geostatistical techniques to account for hydraulic conductivity uncertainty within the aquifer. In the absence of well data allowing derivation of a relationship between geophysical and hydrological parameters, the use of geophysical data is often limited to constraining the structural boundaries. If we recover the base of an unconfined aquifer from an analysis of geophysical data, then the associated uncertainties are a consequence of the geophysical inversion process. In this study, we illustrate this by quantifying water table uncertainties for the unconfined aquifer formed by the paleochannel network around the Kintyre Uranium deposit in Western Australia. The focus of the Bayesian parametric bootstrap approach employed for the inversion of the available airborne electromagnetic data is the recovery of the base of the paleochannel network and the associated uncertainties. This allows us to then quantify the associated influences on the water table in a conceptualized groundwater usage scenario and compare the resulting uncertainties with uncertainties due to an uncertain hydraulic conductivity distribution within the aquifer. Our modeling shows that neither uncertainties in the depth to the base of the aquifer nor hydraulic conductivity uncertainties alone can capture the patterns of uncertainty in the water table that emerge when the two are combined.     

Application of Hilbert‐like transforms for enhanced processing of full tensor magnetic gradient data

Commonly, geomagnetic prospection is performed via scalar magnetometers that measure values of the total magnetic intensity. Recent developments of superconducting quantum interference devices have led to their integration in full tensor magnetic gradiometry systems consisting of planar‐type first‐order gradiometers and magnetometers fabricated in thin‐film technology. With these systems measuring directly the magnetic gradient tensor and field vector, a significantly higher magnetic and spatial resolution of the magnetic maps is yield than those produced via conventional magnetometers. In order to preserve the high data quality in this work, we develop a workflow containing all the necessary steps for generating the gradient tensor and field vector quantities from the raw measurement data up to their integration into high­resolution, low­noise, and artefactless two‐dimensional maps of the magnetic field vector. The gradient tensor components are processed by superposition of the balanced gradiometer signals and rotation into an Earth‐centred Earth‐fixed coordinate frame. As the magnetometers have sensitivity lower than that of gradiometers and the total magnetic intensity is not directly recorded, we employ Hilbert‐like transforms, e.g., integration of the gradient tensor components or the conversion of the total magnetic intensity derived by calibrated magnetometer readings to obtain these values. This can lead to a better interpretation of the measured magnetic anomalies of the Earth's magnetic field that is possible from scalar total magnetic intensity measurements. Our conclusions are drawn from the application of these algorithms on a survey acquired in South Africa containing full tensor magnetic gradiometry data.     

First record of the Australian ascidian Eudistoma elongatum in northern New Zealand

A colonial ascidian was first reported by marine farmers in Houhora Harbour, Northland, New Zealand in early 2005 and subsequently found on oyster racks in Parengarenga Harbour and the Bay of Islands. The Northland ascidian was identified with a combination of morphological characters and DNA cytochrome c oxidase I (COI) sequence data, as Eudistoma elongatum, a species native to Australia, where it is found from northern New South Wales to Northern Queensland, and distinguished from Eudistoma circumvallatum, the only reported species in this genus from New Zealand. Ascidian larvae are weak dispersers and long distance dispersal of E. elongatum is likely to be enhanced by vectors such as oyster barges and/or movement of cultured oysters. In its native range, E. elongatum is restricted to areas with a minimum winter sea temperature of 16°C. Assuming similar biological limitations apply in New Zealand, the spread of E. elongatum might be restricted to northern New Zealand (north of latitude 37°S).     

A new record of Colpocoryphe (Trilobita) from the Skiddaw Group of the Cross Fell inlier,northern England

The trilobite Colpocoryphe sp. is described for the first time from the Kirkland Formation, Llanvirn, of the Skiddaw Group in the Cross Fell inlier. It is considered to be closely related to a form previously recorded from the upper Arenig of the Lake District. This new record supports the previously suggested Gondwanan aspects of the northern England Avalonian fauna during the early Ordovician. Copyright © 2000 John Wiley & Sons, Ltd.