Setting nutrient thresholds to support an ecological assessment based on nutrient enrichment, potential primary production and undesirable disturbance

The EU Water Framework Directive recognises that ecological status is supported by the prevailing physico-chemical conditions in each water body. This paper describes an approach to providing guidance on setting thresholds for nutrients taking account of the biological response to nutrient enrichment evident in different types of water. Indices of pressure, state and impact are used to achieve a robust nutrient (nitrogen) threshold by considering each individual index relative to a defined standard, scale or threshold. These indices include winter nitrogen concentrations relative to a predetermined reference value; the potential of the waterbody to support phytoplankton growth (estimated as primary production); and detection of an undesirable disturbance (measured as dissolved oxygen). Proposed reference values are based on a combination of historical records, offshore (limited human influence) nutrient concentrations, literature values and modelled data. Statistical confidence is based on a number of attributes, including distance of confidence limits away from a reference threshold and how well the model is populated with real data. This evidence based approach ensures that nutrient thresholds are based on knowledge of real and measurable biological responses in transitional and coastal waters.     

Lithogeochemical localisation of disseminated gold in the White River area, Yukon, Canada

Gold mineralisation in the White River area, 80 km south of the highly productive Klondike alluvial goldfield, is hosted in amphibolite facies gneisses in the same Permian metamorphic pile as the basement for the Klondike goldfield. Hydrothermal fluid which introduced the gold was controlled by fracture systems associated with middle Cretaceous to early Tertiary extensional faults. Gold deposition occurred where highly fractured and chemically reactive rocks allowed intense water–rock interaction and hydrothermal alteration, with only minor development of quartz veins. Felsic gneisses were sericitised with recrystallisation of hematite and minor arsenic mobility, and extensively pyritised zones contain gold and minor arsenic (ca 10 ppm). Graphitic quartzites (up to 5 wt.% carbon) caused chemical reduction of mineralising fluids, with associated recrystallisation of metamorphic minerals (graphite, pyrrhotite, pyrite, chalcopyrite) in host rocks and veins, and introduction of arsenic (up to 1 wt.%) to form arsenopyrite in veins and disseminated through host rock. Veins have little or no hydrothermal quartz, and up to 19 wt.% carbon as graphite. Late-stage oxidation of arsenopyrite in some graphitic veins has formed pharmacosiderite. Gold is closely associated with disseminated and vein sulphides in these two rock types, with grades of up to 3 ppm on the metre scale. Other rock types in the White River basement rocks, including biotite gneiss, hornblende gneiss, pyroxenite, and serpentinite, have not developed through-going fracture systems because of their individual mineralogical and rheological characteristics, and hence have been little hydrothermally altered themselves, have little hydrothermal gold, and have restricted flow of fluids through the rock mass. Some small post-metamorphic quartz veins (metre scale) have been intensely fractured and contain abundant gold on fractures (up to 40 ppm), but these are volumetrically minor. The style of gold mineralisation in the White River area is younger than, and distinctly different from, that of the Klondike area. Some of the mineralised zones in the White River area resemble, mineralogically and geochemically, nearby coeval igneous-hosted gold deposits, but this resemblance is superficial only. The White River mineralisation is an entirely new style of Yukon gold deposit, in which host rocks control the mineralogy and geochemistry of disseminated gold, without quartz veins.     

Erosion rates on different timescales derived from cosmogenic 10Be and river loads: implications for landscape evolution in the Rhenish Massif, Germany

We determined erosion rates on timescales of 10¹–10⁴ years for two catchments in the northeastern Rhenish Massif, in order to unravel the Quaternary landscape evolution in a Variscan mountain range typical of central Europe. Spatially averaged erosion rates derived from in situ produced ¹⁰Be concentrations in stream sediment of the Aabach and M?hne watersheds range from 47 ± 6 to 65 ± 14 mm/ka and integrate over the last 9–13 ka. These erosion rates are similar to local rates of river incision and rock uplift in the Quaternary and to average denudation rates since the Mesozoic derived from fission track data. This suggests that rock uplift is balanced by denudation, i.e., the landscape is in a steady state. Short-term erosion rates were derived from suspended and dissolved river loads subsequent to (1) correcting for atmospheric and anthropogenic inputs, (2) establishing calibration curves that relate the amount of suspended load to discharge, and (3) estimating the amount of bedload. The resulting solid mass fluxes (suspended and bedload) agree with those derived from the sediment volume trapped in three reservoirs. However, resulting geogenic short-term erosion rates range from 9 to 25 mm/ka and are only about one-third of the rates derived from ¹⁰Be. Model simulations in combination with published sediment yield data suggest that this discrepancy is caused by at least three factors: (1) phases with higher precipitation and/or lower evapotranspiration, (2) rare flood events not captured in the short-term records, and (3) prolonged periods of climatic deterioration with increased erosion and sediment transport on hillslopes.     

The upper cenozoic evolution of the Duero and Ebro fluvial systems (N-Spain): part I. paleogeography; part II. geomorphology

Lack of age dates in the terrigenous Cenozoic sediments of the Duero and the Ebro sedimentary basins has complicated tecto-stratic correlation across the two basins. We tentatively synthesize a range of existing studies and new data to construct a rough general paleogeography throughout Upper Cenozoic times. The more extensive erosion of the Ebro has been previously attributed to the earlier moment of opening. We tentatively analyse lithostratic data to conclude that the lower knick-point and different lithologies have also contributed to the deeper erosion in the Ebro Basin. We conclude from lithostratic data and field evidence that the W half of the Rioja was part of the Duero in earlier times and that the escarpment retreated westward through the Rioja in four subsequent episodes of erosion. The tilt of the NW Duero is a consequence of isostatic rebound to this erosion.     

A new pathway for Deep water exchange between the Natal Valley and Mozambique Basin?

Although global thermohaline circulation pathways are fairly well known, the same cannot be said for local circulation pathways. Within the southwest Indian Ocean specifically there is little consensus regarding the finer point of thermohaline circulation. We present recently collected multibeam bathymetry and PARASOUND data from the northern Natal Valley and Mozambique Ridge, southwest Indian Ocean. These data show the Ariel Graben, a prominent feature in this region, creates a deep saddle across the Mozambique Ridge at ca. 28°S connecting the northern Natal Valley with the Mozambique Basin. Results show a west to east change in bathymetric and echo character across the northern flank of the Ariel Graben. Whereby eroded plastered sediment drifts in the west give way to aggrading plastered sediment drift in the midgraben, terminating in a field of seafloor undulations in the east. In contrast, the southern flank of the Ariel Graben exhibits an overall rugged character with sediments ponding in bathymetric depressions in between rugged sub/outcrop. It is postulated that this change in sea-floor character is the manifestation of deep water flow through the Ariel Graben. Current flow stripping, due to increased curvature of the graben axis, results in preferential deposition of suspended load in an area of limited accommodation space consequently developing an over-steepened plastered drift. These deposited sediments overcome the necessary shear stresses, resulting in soft sediment deformation in the form of down-slope growth faulting (creep) and generation of undulating sea-floor morphology. Contrary to previous views, our works suggests that water flows from west to east across the Mozambique Ridge via the Ariel Graben.     

Is rainfall intensity significant in the rainfall–runoff process within tropical rainforests of northeast Queensland? The Hewlett regression analyses revisited

Following the statistical analyses of long‐term rainfall‐runoff records from research basins in humid temperate latitudes, Hewlett and co‐workers extended the global challenge to disprove their findings that rainfall intensity was non‐significant. This paper responds to Hewlett's challenge as no preceding analyses have involved forested basins in a tropical cyclone‐prone area. Based on a 7 year rainfall‐runoff record, quickflow (QF), peak flow (QP) and quickflow response ratios (QRR) were regressed as dependent variables against rainfall parameters (intensity, P_i, amount, P), storm duration, D and antecedent flow, I. These data sets were categorised into total streamflow (Q) classes and stratified into three seasons, (monsoon, post‐monsoon and dry) for forested and cleared catchments. Where rainfall variable collinearity met acceptable levels, the addition of P_i to regression models including P, D, I contributed up to 9% and 66% of the respective variations in quickflow and peak flow. For the highest Q storm classes (monsoon), P_i alone accounted for up to 67% and 91% of the variation in Q_F and Q_P respectively and was the dominant influence on Q_P for all seasons. The very high rainfall intensities experienced in the monsoon season is a causal factor why these results differ from those of other research drainage basins. Surprisingly, P_i continued to have a significant influence on Q_F for dry season classes when less‐intense rainfall occurs. Further the results were similar for both catchments across all seasons. P was the dominant independent variable affecting Q_F above a threshold Q of 50 mm (monsoon), as rainfall contributes directly to saturation overland flow and return flow under saturated conditions. Further although QRR increased with increasing Q for each season, the regression results for that parameter were poor possibly due to the non‐linearity of the rainfall‐runoff relationship. Copyright © 2010 John Wiley & Sons, Ltd.     

Implementing quality control on a random number stream to improve a stochastic weather generator

For decades, stochastic modellers have used computerized random number generators to produce random numeric sequences fitting a specified statistical distribution. Unfortunately, none of the random number generators we tested satisfactorily produced the target distribution. The result is generated distributions whose mean even diverges from the mean used to generate them, regardless of the length of run. Non‐uniform distributions from short sequences of random numbers are a major problem in stochastic climate generation, because truly uniform distributions are required to produce the intended climate parameter distributions. In order to ensure generation of a representative climate with the stochastic weather generator CLIGEN within a 30‐year run, we tested the climate output resulting from various random number generators. The resulting distributions of climate parameters showed significant departures from the target distributions in all cases. We traced this failure back to the uniform random number generators themselves. This paper proposes a quality control approach to select only those numbers that conform to the expected distribution being retained for subsequent use. The approach is based on goodness‐of‐fit analysis applied to the random numbers generated. Normally distributed deviates are further tested with confidence interval tests on their means and standard deviations. The positive effect of the new approach on the climate characteristics generated and the subsequent deterministic process‐based hydrology and soil erosion modelling are illustrated for four climatologically diverse sites. Copyright © 2007 John Wiley & Sons, Ltd.     

The effect of drawdown on suspended solids and phosphorus export from Columbia Lake,Waterloo, Canada

This study examines the effect of drawdown on the timing and magnitude of suspended solids and associated phosphorus export from a 12 ha reservoir located in an urbanized watershed in southern Ontario, Canada. Water level in Columbia Lake was lowered by 1·15 m over a 2‐week period in November 2001. The total phosphorus (TP) concentrations ranged from 63 to 486 µg L^?1 in Columbia Lake and 71 to 373 µg L^?1 at its outflow. All samples exceeded the Provincial Water Quality Objective of 30 µg TP L^?1. Outflow concentrations of suspended solids and TP increased significantly with decreasing lake level and were attributed to the resuspension of cohesive bottom sediments that occurred at a critical threshold lake level (0·65 m below summer level). Suspended solids at the outflow consisted of flocculated cohesive materials with a median diameter (D₅₀) of c. 5 µm. Particulate organic carbon accounted for 8·5% of the suspended solids export by mass. A total mass of 18·5 t of suspended solids and 62·6 kg TP was exported from Columbia Lake, which represents a significant pulse of sediment‐associated P to downstream environments each autumn during drawdown. The downstream impacts of this release can be minimized if the water level in Columbia Lake is lowered no more than 0·5 m below summer levels. Copyright © 2004 John Wiley & Sons, Ltd.