Redox front formation in an uplifting sedimentary rock sequence: An analogue for redox-controlling processes in the geosphere around deep geological repositories for radioactive waste

Subsurface redox fronts control the mobilization and fixation of many trace elements, including potential pollutants such as certain radionuclides. Any safety assessment for a deep geological repository for radioactive wastes needs to take into account adequately the long-term redox processes in the geosphere surrounding the repository. To build confidence in understanding these processes, a redox front in a reduced siliceous sedimentary rock distributed in an uplifting area in Japan has been studied in detail. Geochemical analyses show increased concentrations of Fe and trace elements, including rare earth elements (REEs), at the redox front, even though concentrations of reduced rock matrix constituents show little change. Detailed SEM observations revealed that fossilized microorganisms composed of amorphous granules made exclusively of Fe and Si occur in the rock’s pore space. Microbial 16S rDNA analysis suggests that there is presently a zonation of different bacterial groups within the redox band, and bacterial zonation played an important role in the concentration of Fe-oxyhydroxides at the redox front. These water–rock–microbe interactions can be considered analogous to the processes occurring in the redox fronts that would develop around geological repositories for radioactive waste. Once formed, the Fe-oxyhydroxides within such a front would be preserved even after reducing conditions resume following repository closure.     

Carbon isotope chemostratigraphy of a Precambrian/Cambrian boundary section in the Three Gorge area, South China: Prominent global-scale isotope excursions just before the Cambrian Explosion

Carbon isotope chemostratigraphy has been used for worldwide correlation of Precambrian/Cambrian (Pc/C) boundary sections, and has elucidated significant change of the carbon cycle during the rapid diversification of skeletal metazoa (i.e. the Cambrian Explosion). Nevertheless, the standard δ¹³C curve of the Early Cambrian has been poorly established mainly due to the lack of a continuous stratigraphic record. Here we report high-resolution δ¹³C chemostratigraphy of a drill core sample across the Pc/C boundary in the Three Gorge area, South China. This section extends from an uppermost Ediacaran dolostone (Dengying Fm.), through a lowermost Early Cambrian muddy limestone (Yanjiahe Fm.) to a middle Early Cambrian calcareous black shale (Shuijingtuo Fm.). As a result, we have identified two positive and two negative isotope excursions within this interval. Near the Pc/C boundary, the δ¹³C_carb increases moderately from 0 to + 2‰ (positive excursion 1: P1), and then drops dramatically down to − 7‰ (negative excursion 1: N1). Subsequently, the δ¹³C_carb increases continuously up to about + 5‰ at the upper part of the Nemakit–Daldynian stage. After this positive excursion, δ¹³C_carb sharply decreases down to about − 9‰ (N2) just below the basal Tommotian unconformity. These continuous patterns of the δ¹³C shift are irrespective of lithotype, suggesting a primary origin of the record. Moreover, the obtained δ¹³C profile, except for the sharp excursion N2, is comparable to records of other sections within and outside of the Yangtze Platform. Hence, we conclude that the general feature of our δ¹³C profile best represents the global change in seawater chemistry. The minimum δ¹³C of the N1 (− 7‰) is slightly lower than carbon input from the mantle, thus implying an enhanced flux of ¹³C-depleted carbon just across the Pc/C boundary. Hence, the ocean at that time probably became anoxic, which may have affected the survival of sessile or benthic Ediacaran biota. The subsequent δ¹³C rise up to + 5‰ (P2) indicates an increase of primary productivity or an enhanced rate of organic carbon burial, which should have resulted in lowering pCO₂ and following global cooling. This scenario accounts for the cause of the global-scale sea-level fall at the base of the Tommotian stage. The subsequent, very short-term, and exceptionally low δ¹³C (− 9‰) in N2 could have been associated with the release of methane from gas hydrates due to the sea-level fall. The inferred dramatic environmental changes (i.e., ocean anoxia, increasing productivity, global cooling and subsequent sea-level fall with methane release) appear to coincide with or occur just before the Cambrian Explosion. This may indicate synchronism between the environmental changes and rapid diversification of skeletal metazoa.     

Modification of North Pacific Intermediate Water around Mixed Water Region

The mixing processes in the Mixed Water Region (MWR) that lead to changes in the properties of North Pacific Intermediate Water (NPIW) have been studied using observational data sets obtained in May–June 1998. Neutral surfaces, the equation of water mass conversion rate on neutral surfaces and the equation of vertical velocity across neutral surfaces have been used to distinguish dominant processes by assuming the horizontal scale to be the streamer scale (under 100 km). The possibility of double diffusive convection is also discussed in relation to the density ratio. These results may be summarized as follows: (1) the difference between the potential density surface and the neutral surface may rise to −0.04 kg/m³ around the source water of NPIW; (2) horizontal diffusion causes strong modifications of the source water of NPIW; (3) the density range within which strong modification of the source water of NPIW occurs becomes dense from the northern part of MWR near the Oyashio Front to the southern part near the Kuroshio Front, and to the eastern part. Our modeling of these processes shows that cabbeling has effects on the density increment of the source water of NPIW in the northern and southern part of MWR. Double diffusive convection has effects on the density increment of the source water of NPIW, mainly in the northern part of MWR. The possible density increment due to cabbeling in these areas is estimated to be 0.01≈0.03 kg/m³. The possible density increment due to double diffusive convection is 0.01≈0.03 kg/m³. The total density increment due to cabbeling and double diffusive convection amounts to 0.06 kg/m³. This revised version was published online in July 2006 with corrections to the Cover Date.     

Heat content change in the surface isothermal layer of a warm core ring in the sea east of Japan

Heat content change in the surface isothermal layer of a typical warm core ring in the sea east of Japan is described based on approximately 90 CTD profiles obtained by one profiling float. Erosion of the seasonal thermocline and development of a surface isothermal layer from the mid-summer to the early winter of 1999 are clearly seen. While heat content change between two consecutive profiles with a 35-hour time interval is much noisier, its 10-day running mean is consistent with net surface heat flux, indicating that surface heat flux dominates the temporal heat content change in the surface isothermal layer in the warm core ring.     

Forecast of volcanic eruptions by chemical methods

From the magmatic emanations differentiation point of view it is possible to calculate some ratios such as F/CO₂, Cl/CO₂, SO₂/CO₂, SO₂/H₂S, H₂S/CO₂ and CO₂/N₂ in the tumarolic gases for the forecasting of volcanic activity. In order to predict the cruptions of a volcano it is needed to select several fumaroles or hot springs having different regimes of variation of the above ratios. The study of some fumaroles composition at the Asama. Mihara, Kirishima and other volcanoes in Japan showed a close connection between volcanic gas compositions and state of the volcanoes.     

Coherency of rupture and seismic spectrum

In considering the seismic spectrum, one of the methods to incorporate irregularity of fault motion statistically is to introduce the concept of coherency of fracture. In a classic paper,Aki (1967) investigated the scaling law of seismic spectrum on the basis of a statistical model in which an exponentially decaying function is fitted to the autocorrelation function of the dislocation velocity. It is found, however, thatAki's model does not necessarily express irregular fault motion, but corresponds to a smooth dislocation. We show that an analytical function of dislocation velocity gives the same autocorrelation function and the same seismic spectrum as those ofAki's model. In actual fault motion, there is considerable evidence which indicates that the dislocation is not continuous and smooth over the whole fault plane, but is often segmented in several parts. In order to take into consideration this feature we introduce a generalized autocorrelation function of the dislocation velocity in which many coherent fractures smaller than the size of the fault dimension are included. It is shown that the more small-scale coherent fractures, the larger the seismic wave energy in the high frequency range.Kanamori andAllen (1986) showed that a large ratio of seismic wave energy relative to the seismic moment means a large effective stress drop. On the other hand, it is well known that when a fault plane is segmented in several parts, stress drop becomes large (e.g.,Madariaga, 1979;Rudnicki andKanamori, 1981). These two results are fused in our model, because we find that large seismic wave energy is obtained when the fault motion includes small-scale fractures.Kanamori andAllen (1986) also showed that there is a tendency for earthquakes with long repeat times to have a large effective stress drop. Our model implies that a fracture corresponding to earthquakes with long recurrence intervals is more complex, and the strength is large, as also suggested byCao andAki (1986) using a numerical simulation. It should be noted that to the zeroth order, an approximate scaling relation is observed among earthquakes, which means that a large earthquake consists of a relatively large-scale coherent fracture. This fact seems to suggest that the condition of occurrence of a large earthquake is related to the maturing of a source region in which a large coherent fracture becomes feasible.