Modeling the atmospheric limb emission of CO2 at 4.3 μm in the terrestrial planets

The MIPAS instrument on board Envisat, in Earth orbit, the PFS and OMEGA instruments on Mars Express, and VIRTIS on board Venus Express are currently providing a dataset of limb measurements of the CO₂ atmospheric fluorescence emission at 4.3‐μm from the upper atmosphere of the three planets. These measurements represent an excellent dataset to perform comparative studies between the terrestrial planets’ upper atmospheres, and also to test our theoretical understanding of these emissions. In order to exploit these datasets, we apply a set of non-local thermodynamic equilibrium (non-LTE) models developed at the IAA/CSIC, in Granada, Spain, to a selection of data. In general, the models can explain the main spectral features of the measurements, and also the altitude and solar zenith angle variations. However, the simulations for Mars and Venus give an incorrect ratio of the emissions at two wavelengths, 4.4 and . In order to explain this deficiency, a revision of the most uncertain non-LTE energy transfer parameters has been performed. The quenching rate of ν₃ quanta of high-energy CO₂ states by CO₂ itself could reduce the model-data discrepancy if increased by a factor 2-4, still within its current uncertainty range. This factor, however, is subject to the uncertainty in the thermal structure. A number of simulations with the non-LTE models were also used to study and compare the role of radiative transfer in this spectral region in the three terrestrial planets. Sensitivity studies of density and temperature are also presented, and they permit an analysis of how the differences between the planets and between the three instruments affect their sounding capabilities.     

Observations of water vapour and carbon monoxide in the Martian atmosphere with the SWC of PFS/MEX

In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H₂O and the CO gases are main characters.The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000 cm^?1 (5–50 μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000 cm^?1 (1.2–5.8 μm) with the Short Wavelength Channel (SWC). Although there are several H₂O and CO absorption bands in the spectral range covered by PFS, we used the 3845 cm^?1 (2.6 μm) and the 4235 cm^?1 (2.36 μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose.The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6 pr. μm and a mean mixing ratio of carbon monoxide of about 990 ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure.     

Cassini-VIMS at Jupiter: solar occultation measurements using Io

We report unusual and somewhat unexpected observations of the jovian satellite Io, showing strong methane absorption bands. These observations were made by the Cassini VIMS experiment during the Jupiter flyby of December/January 2000/2001. The explanation is straightforward: Entering or exiting from Jupiter's shadow during an eclipse, Io is illuminated by solar light which has transited the atmosphere of Jupiter. This light, therefore becomes imprinted with the spectral signature of Jupiter's upper atmosphere, which includes strong atmospheric methane absorption bands. Intercepting solar light refracted by the jovian atmosphere, Io essentially becomes a “mirror” for solar occultation events of Jupiter. The thickness of the layer where refracted solar light is observed is so large (more than 3000 km at Io's orbit), that we can foresee a nearly continuous multi-year period of similar events at Saturn, utilizing the large and bright ring system. During Cassini's 4-year nominal mission, this probing technique should reveal information of Saturn's atmosphere over a large range of southern latitudes and times.     

Cassini VIMS observations of the Galilean satellites including the VIMS calibration procedure

The Visual and Infrared Mapping Spectrometer (VIMS) observed the Galilean satellites during the Cassini spacecraft's 2000/2001 flyby of Jupiter, providing compositional and thermal information about their surfaces. The Cassini spacecraft approached the jovian system no closer than about 126 Jupiter radii, about 9 million kilometers, at a phase angle of <90°, resulting in only sub-pixel observations by VIMS of the Galilean satellites. Nevertheless, most of the spectral features discovered by the Near Infrared Mapping Spectrometer (NIMS) aboard the Galileo spacecraft during more than four years of observations have been identified in the VIMS data analyzed so far, including a possible ¹³C absorption. In addition, VIMS made observations in the visible part of the spectrum and at several new phase angles for all the Galilean satellites and the calculated phase functions are presented. In the process of analyzing these data, the VIMS radiometric and spectral calibrations were better determined in preparation for entry into the Saturn system. Treatment of these data is presented as an example of the VIMS data reduction, calibration and analysis process and a detailed explanation is given of the calibration process applied to the Jupiter data.     

Identification of spectral units on Phoebe

We apply a multivariate statistical method to the Phoebe spectra collected by the VIMS experiment onboard the Cassini spacecraft during the flyby of June 2004. The G-mode clustering method, which permits identification of the most important features in a spectrum, is used on a small subset of data, characterized by medium and high spatial resolution, to perform a raw spectral classification of the surface of Phoebe. The combination of statistics and comparative analysis of the different areas using both the VIMS and ISS data is explored in order to highlight possible correlations with the surface geology. In general, the results by Clark et al. [Clark, R.N., Brown, R.H., Jaumann, R., Cruikshank, D.P., Nelson, R.M., Buratti, B.J., McCord, T.B., Lunine, J., Hoefen, T., Curchin, J.M., Hansen, G., Hibbitts, K., Matz, K.-D., Baines, K.H., Bellucci, G., Bibring, J.-P., Capaccioni, F., Cerroni, P., Coradini, A., Formisano, V., Langevin, Y., Matson, D.L., Mennella, V., Nicholson, P.D., Sicardy, B., Sotin, C., 2005. Nature 435, 66-69] are confirmed; but we also identify new signatures not reported before, such as the aliphatic CH stretch at 3.53 μm and the ∼4.4 μm feature possibly related to cyanide compounds. On the basis of the band strengths computed for several absorption features and for the homogeneous spectral types isolated by the G-mode, a strong correlation of CO₂ and aromatic hydrocarbons with exposed water ice, where the uniform layer covering Phoebe has been removed, is established. On the other hand, an anti-correlation of cyanide compounds with CO₂ is suggested at a medium resolution scale.     

Methane in Martian atmosphere: Average spatial, diurnal, and seasonal behaviour

A large number of spectra measured by the planetary Fourier spectrometer aboard the European Mars Express mission have been studied to identify the average properties of methane in the Martian atmosphere. Using the line at 3018 cm⁻¹, we have studied the seasonal, diurnal, and spatial variations of methane through the analysis of large averages of spectra (more than 1000 measurements). Methane mixing ratio has been obtained simultaneously with water vapour mixing ratio and water ice content, by best fitting (minimising the χ²) the computed averages with synthetic spectra. These spectra were computed for different values of the three parameters (methane and water vapour mixing ratio, and water ice optical depth).The methane mixing ratio shows a slow decrease from northern spring to southern summer with an average value of 14±5 ppbv (part per billion by volume) and it does not show a particular trend with latitude. The methane mixing ratio seems not to be uniform in longitude in the Martian atmosphere, as already reported by Formisano et al. [2004. Detection of methane in the atmosphere of Mars. Science 306, 1758-1761]. Two maxima are present at −40°E and +70°E longitude. In local time, the methane mixing ratio seems to follow the water vapour diurnal cycle. The most important point for future understanding is, however, that there are special orbits in which methane mixing ratio has a very high value.     

Local- and global-scale seismic analyses of historical masonry compounds in San Pio delle Camere (L’Aquila,Italy)

Masonry building aggregates are large parts of the Italian building heritage often designed without respecting seismic criteria. The current seismic Italian code does not foresee a clear calculation method to predict their static nonlinear behaviour. For this reason, in this paper firstly, a simple methodology to forecast the seismic response of masonry aggregates in San Pio delle Camere (L’Aquila, Italy) has been set up starting from the provisions of the Italian Guidelines on Cultural Heritage. The implemented procedure has been calibrated on the results of two FEM structural analysis programs used to investigate three masonry building compounds. As a result, a design chart used to correctly predict the base shear of aggregate masonry units starting from code provisions has been set up. Later on, the large-scale seismic vulnerability and damage appraisal of the inspected historical centre has been done on the basis of a quick methodology, already implemented and experienced by the author in some historical centres of the Campania region. The analysis result was a numerical correlation between vulnerability index and mean damage grade of examined building compounds. In particular, a damage forecast under numerical way has been firstly estimated and then compared with the real one. The post-earthquake scenario has represented an ideal term of comparison for effectively testing the reliability of the employed technique, which should be further extended to other Italian historical centres.     

α-particle observations in the solar wind

The plasma experiment on board of the ESRO satellite HEOS-1 detects solar wind positive ions in the energy range from 200 eV/Z–16000 eV/Z. -particles have been observed for 10% of the time, from December 1968 to March 1969, when in the interplanetary medium -particle and proton bulk velocities are on average equal. The average relative abundance of -particles is 5.5 %.Although in general the two species, hydrogen and helium, have a similar behaviour, very often -particles have an independent time history. Strong discontinuities may be observed in one species, without occurring in the other, or having different characteristics. At certain times, -particles seem to behave as an independent fluid.Well defined fluxes of -particles are observed within the magnetosheath: in several cases -particles, present in the unperturbed solar wind, are found with unchanged energy spectrum through a certain layer behind the proton shock front inside the magnetosheath. This suggests that thermalization of -particles does not occur at the same place as that of protons.     

Sensitivity of goodness-of-fit statistics to rainfall data rounding off

An analysis based on the L-moments theory suggests of adopting the generalized Pareto distribution to interpret daily rainfall depths recorded by the rain-gauge network of the Hydrological Survey of the Sardinia Region. Nevertheless, a big problem, not yet completely resolved, arises in the estimation of a left-censoring threshold able to assure a good fitting of rainfall data with the generalized Pareto distribution. In order to detect an optimal threshold, keeping the largest possible number of data, we chose to apply a “failure-to-reject” method based on goodness-of-fit tests, as it was proposed by Choulakian and Stephens [Choulakian, V., Stephens, M.A., 2001. Goodness-of-fit tests for the generalized Pareto distribution. Technometrics 43, 478-484]. Unfortunately, the application of the test, using percentage points provided by Choulakian and Stephens (2001), did not succeed in detecting a useful threshold value in most analyzed time series. A deeper analysis revealed that these failures are mainly due to the presence of large quantities of rounding off values among sample data, affecting the distribution of goodness-of-fit statistics and leading to significant departures from percentage points expected for continuous random variables. A procedure based on Monte Carlo simulations is thus proposed to overcome these problems.     

The role of the critical ionization velocity phenomena in the production of inner coma cometary plasma

The critical velocity triggering anomalous ionization of the neutral gas by plasma flow is calculated for the model based on the lower hybride instability. It depends strongly on the plasma and gas parameters, denning the instability development of the ionized atoms beam in the counter-streaming plasma.In particular, the possible role of the critical ionization mechanism for Halley's comet is examined. The fulfilment of both Townsend's condition for the selfustained beam plasma discharge and Alfven's condition for the critical velocity mechanism indicates that this mechanism may operate only within 10⁴ km from the cometary nucleus and give an ion production rate close to that observed for Kohoutek's comet.