The relevance of bisphenol A adsorption during Fenton’s oxidation

The aim of this research was to assess the efficiency of Fenton’s oxidation for degradation of endocrine disruptor bisphenol A (BPA) with emphasis on extent of accompanying adsorption. Adsorption on the waste sludge resulting from the Fenton’s oxidation could represent a significant impact on the final removal efficiency of BPA. Fenton’s oxidation was accomplished at two concentrations of BPA (0.228 and 22.8 mg L^?1); both at the selected molar ratio of reagents Fe²⁺:H₂O₂ (1:10), as a function of reaction time. The kinetics of adsorption of BPA on waste sludge was determined for the same two concentrations of BPA at two concentrations of waste sludge (0.1 and 6.0 g L^?1). In addition to changing concentrations of BPA and sludge, the adsorption process was also influenced by parameters such as temperature, pH and contact time. Adsorption isotherms were determined. Oxidation and adsorption were monitored by gas chromatography combined with mass spectrum. It has been confirmed that BPA is not completely oxidized in Fenton’s oxidation, because it is adsorbed to formed waste ferric sludge and thus necessary precautions for sludge deposition must be observed.     

Determination of groundwater flow regimes in underground storage caverns using tritium and helium isotopes

Understanding groundwater flow and chemical transport is crucial for operating underground storage caverns. Groundwater flow in the study area is mainly affected by cavern operating conditions, and groundwater chemistry in the study area is modified by disinfection activities for removing possible biological clogging and by mixing with cement pore water. It is significant to discern these two effects because wells affected by the disinfection activities, in particular, may have hydrological connections with water curtains in which disinfectant water was injected to remove the biological clogging. Concentration of tritium (³H) and helium isotopes (⁴He), and groundwater chemical compositions were used to confirm that there are hydrological connectivities between the water curtain and the well. Groundwater along the fault areas contains low total dissolved solid (TDS) and high ³H, suggesting that the faults may act as fast flow conduits, which is not inconsistent with previous studies. Certain diagnostic conditions (high concentrations of Na⁺, Cl⁻ and TDS and high pH) are presumed by the effect of disinfection activity, indicating that there are hydrological connections between the water curtain and the wells. This hypothesis is valid in YK2U and YK2L, but is not in YK12L, implying a closed system or an immobile water to explain the isotopic results.     

Response of Single Piles in Marine Deposits to Negative Skin Friction from Long-term Field Monitoring

The behavior of single piles subjected to negative skin friction in soft soil was conducted by analyzing the results from full-scale long-term field measurements and three-dimensional (3D) numerical analyses. A skin friction coefficient (α and β coefficients) of the instrumented piles is back-calculated at different degrees of consolidation (U) of soft marine clay. Back-calculated β-values ranged from 0.15 to 0.35 for clay, and from 0.30 to 0.55 for sand, respectively. In addition, back-calculated α-values ranged from 0.1 to 0.3 for coated pile, and from 0.2 to 0.8 for uncoated pile when undrained shear strength of the soft clay was about 30–60 kPa, respectively. Moreover, this study describes behavior of a pile based on full-coupled 3D finite element (FE) analysis. The appropriate parametric studies needed for verifying the pile-soil interaction with consolidation are presented in this paper. Compared to the results from the measurements, it is shown that the computed results are capable of predicting the pile-soil behavior under consolidation. The major parameters that influence the pile behavior are discussed for different soil-pile conditions.     

Magmatic history of granite-derived mylonites from the southern Desná Unit (Silesicum, Czech Republic)

Summary In the southern part of the Hruby Jeseník Mts. (Silesicum, Bohemian Massif) granitic orthogneisses and quartz-feldspars mylonites occur that were variously deformed, metamorphosed and imbricated with the overlaying Devonian volcano-sedimentary complex during the Variscan orogeny. Based on combined mapping, petrologic and geochemical studies, three main rock groups are distinguished. The fairly primitive nature of the tonalite suite is shown by low ⁸⁷Sr/⁸⁶Sr₅₅₀ ratios (0.7034–0.7038) and positive ε _Nd ⁵⁵⁰ values (+3.8 and +3.1). Isotopic composition of the metagranite suite is similar (ε _Nd ⁵⁵⁰ = +1.9 to +2.9). Both suites probably belong to a single Cadomian calc-alkaline tonalite–granite association, which can be correlated with acid-intermediate plutonic rocks of the eastern Brunovistulicum (Slavkov Terrane). All these units are interpreted as representing dismembered fragments of the same continental margin magmatic arc system. The leucogranite suite is most likely early Variscan in age. The initial Nd isotopic composition (ε _Nd ³³⁰ = +0.8 and +2.3) is consistent with its formation by a Variscan remelting of the metaigneous Cadomian crust represented by the rocks of the tonalite–granite association. The within-plate granite affinity of the leucogranite suite is most likely related to the break-up of the Brunovistulicum during the Variscan orogeny.     

Deuteron whistlers in the outer ionosphere

Summary Upgoing and downgoing deuteron whistlers were found on VLF records made by Interkosmos 5, 14 and 19 satellites even at heights below 1000 km. To account for them, a slight admixture ofD ⁺ ions has been introduced into the ionospheric plasma model with the usual content of only three ion speciesH ⁺,He ⁺ andO ⁺. Relations derived for the calculation of characteristic frequencies in a five-component plasma (e,H ⁺,D ⁺,He ⁺,O ⁺) are given as well as the values of characteristic frequencies calculated on this basis. The observed features of upgoing and downgoing deuteron whistlers could be explained by the calculation results, and it is also possible to formulate some conclusions for the purposes of plasma diagnostics.

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mu um, anmau a ma u u, u a a nmua m 5, 14 u 19 a ma ¶rt;a 1000 . u u a ¶rt;a ¶rt; u na ¶rt;au uH ⁺,He ⁺,O ⁺ aa nuD ⁺ u. m mm ua nma ¶rt;a ¶rt; aamumuu amm ¶rt;a ¶rt;u na. uu aamumuu amm nuu um a¶rt;a mu ¶rt;mu um. a m ¶rt; unam aamumuu ¶rt;mu um ¶rt; u¶rt;au naam na.

     

Climate Change Impacts on Groundwater Resources in the Coastal Karstic Adriatic Area: A Case Study from the Dinaric Karst

Natural Resources Research - The Bokanjac–Poli?nik system, as a complex set of mutually interrelated Dinaric karst catchments and sub-catchments, is a highly vulnerable and limited...     

Orbital rates of earth satellites at resonances to test the accuracy of earth gravity field models

Celestial Mechanics and Dynamical Astronomy - Differences among the Earth gravity field models, which were (in Klokočník and Pospíšilová, 1981) expressed as dispersions of...     

Transformation of coordinates between two horizontal geodetic datums

The following topics are discussed in this paper: the geocentric coordinate system and its different realizations used in geodetic practice; the definition of a horizontal geodetic datum (reference ellipsoid) and its positioning and orientation with respect to the geocentric coordinate system; positions on a horizontal datum and errors inherent in the process of positioning; and distortions of geodetic networks referred to a horizontal datum. The problem of determining transformation parameters between a horizontal datum and the geocentric coordinate system from known positions is then analysed. It is often found necessary to transform positions from one horizontal datum to another. These transformations are normally accomplished through the geocentric coordinate system and they include the transformation parameters of the two datums as well as the representation of the respective network distortions. Problems encountered in putting these transformations together are pointed out.