Hydrogen isotopic composition of water from fossil micrometeorites in howardites

We have measured the hydrogen isotopic composition (D/H ratios) of the water from 13 carbonaceous chondritic microclasts (CCMs, size <1 mm) trapped in two howardites (Kapoeta and Yamato-793497) early in the evolution of Solar System. The division into tochilinite-rich; magnetite-rich, olivine-poor; magnetite-rich, olivine-rich CCM types is corroborated by the hydrogen isotopic compositions. Both mineralogy and hydrogen isotopic compositions demonstrate that tochilinite-rich CCMs represent CM2 chondritic matter. In contrast, there is no good match between the isotopic and mineralogical properties of the magnetite-rich CCMs and the known groups of carbonaceous chondrites, suggesting that magnetite-rich CCMs represent a new kind of chondritic matter, not yet sampled in meteorite collections. This demonstrates that the view of the asteroid belt revealed by the collection of meteorites is incomplete. The study of (micro)clasts offers a unique opportunity to better decipher the nature and relative abundance of asteroids.The average hydrogen isotopic composition of water belonging to CCMs, D/H = (152.0 ± 4.8) × 10⁻⁶ (1σ_m), is similar to that of Antarctic micrometeorites (AMMs), D/H = (161.2 ± 3.8) × 10⁻⁶ (1σ_m). The similarity, in terms of mineralogy and hydrogen isotopic composition, between CCMs and AMMs demonstrates that the composition of the micrometeorites has not been modified over the whole history of the Solar System. It indicates that the composition of the micrometeorite flux onto Earth has been, and is, dominated by a mixture of CM2-like; magnetite-rich, olivine-poor; magnetite-rich, olivine-rich carbonaceous chondritic matter exemplified by CCMs found in howardites. Because CCMs have not suffered atmospheric entry, they provide an abundant source of pristine micrometeorites.The average D/H ratio of the whole population of CCMs is identical within errors to that of the Earth (149 ± 3 × 10⁻⁶). The match between the CCMs D/H ratio and that of the Earth is especially remarkable because 1) three different populations of CCMs are needed to make the D/H ratio of the Earth; 2) there is no single carbonaceous chondrite group for which a similar match exists. This observation suggests that CCMs population might be representative of the late veneer agent(s) that delivered water to the Earth.     

Site preservation along an active meandering and avulsing river: The Red River,Arkansas

The low-gradient Red River is a rapidly migrating, sinuous stream with easily erodible banks. Avulsion is common at many scales, from individual meander bends that are cut off to major sections of the river that form multiple, complex meander belts. The present meander belt can be subdivided into mappable landforms—termed phases—that are associated with river courses of different ages and thus associated with archeological sites of different ages. Within the study area two phases are present. The younger Modern meander belt phase has formed within the past 0.2–0.3 ky, precluding preservation of prehistoric archaeological sites. Any protohistoric artifacts that may have been preserved in this meander belt phase would be deeply buried because as much as 2 m of the vertical accretion sediment has accumulated between artificial levees in <0.1 ky and 1–2 m of sediment has accumulated beyond the artificial levees in <0.2 ky. Archeological site preservation in this highly mobile fluvial end member can be used as a predictor for other, similar streams. A large prehistoric site is preserved on an older (0.5–1 kya) Late Prehistoric meander belt phase associated with an abandoned river course. In the study area a Fourche Maline 7 period (A.D. 800–900) through Caddo IV period (ca. A.D. 1500–1700) archeological site (3MI3/30) is preserved on this slightly higher altitude portion of the flood plain. At locations proximal to the river, the site may be buried by overbank sediment 0.4 m thick, but at more distant locations the site is at the surface or only buried by thin overbank sediment because of low sedimentation rates (0.04 cm yr⁻¹) over the span of a millennium. Sites, such as 3MI3/30, that are occupied contemporaneous with overbank sedimentation may be stratified; however, localized erosion and removal of some archeological material may occur where channelized flow crosses the natural levee. © 1998 John Wiley & Sons, Inc.     

Geochemically induced shifts in catabolic energy yields explain past ecological changes of diffuse vents in the East Pacific Rise 9°50'N area

The East Pacific Rise (EPR) at 9°50'N hosts a hydrothermal vent field (Bio9) where the change in fluid chemistry is believed to have caused the demise of a tubeworm colony. We test this hypothesis and expand on it by providing a thermodynamic perspective in calculating free energies for a range of catabolic reactions from published compositional data. The energy calculations show that there was excess H₂S in the fluids and that oxygen was the limiting reactant from 1991 to 1997. Energy levels are generally high, although they declined in that time span. In 1997, sulfide availability decreased substantially and H₂S was the limiting reactant. Energy availability dropped by a factor of 10 to 20 from what it had been between 1991 and 1995. The perishing of the tubeworm colonies began in 1995 and coincided with the timing of energy decrease for sulfide oxidizers. In the same time interval, energy availability for iron oxidizers increased by a factor of 6 to 8, and, in 1997, there was 25 times more energy per transferred electron in iron oxidation than in sulfide oxidation. This change coincides with a massive spread of red staining (putative colonization by Fe-oxidizing bacteria) between 1995 and 1997. For a different cluster of vents from the EPR 9°50'N area (Tube Worm Pillar), thermodynamic modeling is used to examine changes in subseafloor catabolic metabolism between 1992 and 2000. These reactions are deduced from deviations in diffuse fluid compositions from conservative behavior of redox-sensitive species. We show that hydrogen is significantly reduced relative to values expected from conservative mixing. While H₂ concentrations of the hydrothermal endmember fluids were constant between 1992 and 1995, the affinities for hydrogenotrophic reactions in the diffuse fluids decreased by a factor of 15 and then remained constant between 1995 and 2000. Previously, these fluids have been shown to support subseafloor methanogenesis. Our calculation results corroborate these findings and indicate that the 1992-1995 period was one of active growth of hydrogenotrophic communities, while the system was more or less at steady state between 1995 and 2000.     

Determining effective wellbore permeability from a field pressure test: a numerical analysis of detection limits

We propose a simple pressure test that can be used in the field to determine the effective permeability of existing wellbores. Such tests are motivated by the need to understand and quantify leakage risks associated with geological storage of CO₂ in mature sedimentary basins. If CO₂ is injected into a deep geological formation, and the resulting CO₂ plume encounters a wellbore, leakage may occur through various pathways in the “disturbed zone” surrounding the well casing. The effective permeability of this composite zone, on the outside of the well casing, is an important parameter for models of leakage. However, the data that exist on this key parameter do not exist in the open literature, and therefore specific field tests need to be done in order to reduce the uncertainty inherent in the leakage estimates. The test designed and analyzed herein is designed to measure effective wellbore permeability within a low-permeability caprock, bounded above and below by permeable reservoirs, by pressurizing the reservoir below and measuring the response in the reservoir above. Alternatively, a modified test can be performed within the caprock without directly contacting the reservoirs above and below. We use numerical simulation to relate pressure response to effective well permeability and then evaluate the range of detection of the effective permeability based on instrument measurement error and limits on fracture pressure. These results can guide field experiments associated with site characterization and leakage analysis.     

Influence of Intra- and Interspecific Interactions on Short-term Movement of the Amphipod Corophium volutator in Varying Environmental Conditions

Movement of animals on intertidal mudflats can have profound consequences for population and community dynamics. Such movement is often influenced by biotic interactions, but the abiotic environment can also be important, affecting the strength of species’ interactions and even changing their outcome. Here, we focused on two biotic interactions and examined their effect on movement of the burrow-dwelling amphipod Corophium volutator: intraspecific interactions (specifically, the effect of conspecific density) and interspecific interactions with a competitor–predator, the mud snail Ilyanassa obsoleta (=Nassarius obsoletus). We assessed the magnitude of the temporal variation and examined the influence of pertinent abiotic variables (lunar cycle, presence of tide pools). Despite substantial temporal variation in movement levels, density of conspecifics did not influence emigration or immigration rates of C. volutator. Mud snails negatively affected immigration of C. volutator, and this was consistent across all lunar phases. However, mud snails influenced mortality and emigration of C. volutator in a contrasting way relative to lunar phases; sometimes amphipods evaded snails and survived, but at other times did not emigrate and were killed. The presence of tide pools did not change the nature or strength of the snail–amphipod interaction. Our results further clarify the complex interactions between C. volutator and I. obsoleta and suggest that resources on the mudflat are sufficient to sustain high densities of amphipods in a density-independent manner. Further, they highlight the importance of considering multiple environmental variables when examining interspecific interactions.     

Tumbi Landslide, Papua New Guinea: rainfall induced?

On 24 January 2012, a fatal landslide with an estimated volume of 3 Mm³ hit villagers and infrastructure in the Tagali Valley, Southern Highlands Province, Papua New Guinea (PNG). Although a moderate event by PNG standards, the associated human casualties and infrastructure destruction give a human as well as a scientific need to review the potential causes for the event. PNG experiences numerous landslides annually, most of which are trigged either by rainfall events or seismic activity. Here, we review the short-term rainfall patterns leading up to the slope failure at Tumbi Quarry and compare the rainfall accumulations obtained over durations of 30, 60 and 90 days prior to the landslide, with comparable rainfall accumulations obtained for other failures observed in PNG over a 12-year period. Additionally, a review of long-term rainfall over a period of 6 months prior to the failure is completed as well as an assessment of seismic activity. Based on our analysis, we believe a seismic trigger to be very unlikely, while the increase in rainfall in the 2 weeks prior to the failure in conjunction with a high-intensity rainfall event at the end of October 2011 could have had a greater influence in enhancing rather than restraining slope failure. This, in addition to natural denudational processes, geological structure and the anthropogenic activity in the vicinity of the landslide, could all have served to affect slope stability.     

The origin of the Naturaliste Plateau,SE Indian Ocean: Implications from dredged basalts

Although a 1972 dredging by USNS Eltanin from the submarine Naturaliste Plateau was reported to yield rocks of continental origin, a re‐examination of the dredge haul shows that the rock clasts are in fact altered tholeiitic basalts. They have affinities both with MOR basalts and, especially, within‐plate basalts. Petrographically they correlate most closely with the Bunbury Tholeiitic Suite on the Australian mainland to the east. The basalts are reworked cobbles in a manganiferous Quaternary slump mass, which contains a quartz‐rich, felsic, detrital mineral suite with a granite‐gneiss provenance. The basalt cobbles were part of a basal conglomerate, which covered large areas of the Plateau. It is suggested that this was laid down from nearby elevated volcanic structures formed during the inception of seafloor spreading and the separation of Greater India from Australia at about 122 Ma BP.     

Tectonic controls on metamorphism, partial melting, and intrusion: timing and duration of regional metamorphism and magmatism in the Ni de Massif, Turkey

Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m². Calculated seismic velocities (V_p) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm³. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (La_N/Yb_N=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton.     

Synthesis in Estuarine and Coastal Ecological Research: What Is It,Why Is It Important,and How Do We Teach It?

During the last two decades, there has been growing interest in the integration of existing ideas and data to produce new synthetic models and hypotheses leading to discovery and advancement in estuarine and coastal science. This essay offers an integrated definition of what is meant by synthesis research and discusses its importance for exploiting the rapid expansion of information availability and for addressing increasingly complex environmental problems. Approaches and methods that have been used in published synthetic coastal research are explored and a list of essential steps is developed to provide a foundation for conducting synthetic research. Five categories of methods used widely in coastal synthesis studies are identified: (1) comparative cross-system analysis, (2) analysis of time series data, (3) balance of cross-boundary fluxes, (4) system-specific simulation modeling, and (5) general systems simulation modeling. In addition, diverse examples are used to illustrate how these methods have been applied in previous studies. We discuss the urgent need for developing curricula for classroom and experiential teaching of synthesis in coastal science to undergraduate and graduate students, and we consider the societal importance of synthetic research to support coastal resource management and policy development. Finally, we briefly discuss the crucial challenges for future growth and development of synthetic approaches to estuarine and coastal research.