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941.
S. I. Mayr H. Burkhardt Yu. Popov A. Wittmann 《International Journal of Earth Sciences》2008,97(2):385-399
Internal surface, formation factor, Nuclear Magnetic Resonance (NMR)-T2 relaxation times and pore radius distributions were
measured on representative core samples for the estimation of hydraulic permeability. Permeability is estimated using various
versions of the classic Kozeny–Carman-equation (K–C) and a further development of K–C, the fractal PaRiS-model, taking into
account the internal surface. In addition to grain and pore size distribution, directly connected to permeability, internal
surface reflects the internal structure (“micro morphology”). Lithologies could be grouped with respect to differences in
internal surface. Most melt rich impact breccia lithologies exhibit large internal surfaces, while Tertiary post-impact sediments
and Cretaceous lithologies in displaced megablocks display smaller internal surfaces. Investigations with scanning electron
microscopy confirm the correlation between internal surface and micro morphology. In addition to different versions of K–C,
estimations by means of NMR, pore radius distributions and some gas permeability measurements serve for cross-checking and
calibration. In general, the different estimations from the independent methods and the measurements are in satisfactory accordance.
For Tertiary limestones and Suevites bulk with very high porosities (up to 35%) permeabilites between 10−14 and 10−16 m2 are found, whereas in lower Suevite, Cretaceous anhydrites and dolomites, bulk permeabilites are between 10−15 and 10−23 m2. 相似文献
942.
Hydrogeologic assessment of escalating groundwater exploitation in the Indus Basin, Pakistan 总被引:1,自引:1,他引:0
Groundwater development has contributed significantly to food security and reduction in poverty in Pakistan. Due to rapid population growth there has been a dramatic increase in the intensity of groundwater exploitation leading to declining water tables and deteriorating groundwater quality. In such prevailing conditions, the hydrogeological appraisal of escalating groundwater exploitation has become of paramount importance. Keeping this in view, a surface water–groundwater quantity and quality model was developed to assess future groundwater trends in the Rechna Doab (RD), a sub-catchment of the Indus River Basin. Scenario analysis shows that if dry conditions persist, there will be an overall decline in groundwater levels of around 10 m for the whole of RD during the next 25 years. The lower parts of RD with limited surface water supplies will undergo the highest decline in groundwater levels (10 to 20 m), which will make groundwater pumping very expensive for farmers. There is a high risk of groundwater salinization due to vertical upconing and lateral movement of highly saline groundwater into the fresh shallow aquifers in the upper parts of RD. If groundwater pumping is allowed to increase at the current rate, there will be an overall decline in groundwater salinity for the lower and middle parts of RD because of enhanced river leakage. 相似文献
943.
Point scale studies in different settings of glacial geology show a large local variation of redox conditions. There is a need to develop an upscaling methodology for catchment scale models. This paper describes a study of field-scale heterogeneity of redox-interfaces in a till aquitard within an area of 600?×?600 m. The results showed significant variation of the depths to the redox-interface and thickness of the aquitard. Nitrate was present above the redox-interface but reduced to non-detectable levels a few metres below the interface. An upscaling approach for an area of 92 km2 is proposed. Two models are proposed to predict the depth to the redox-interface in the aquitard and the resulting nitrate recharge concentrations to an underlying aquifer. The first model assumes that the depth to the redox-interface reflects the hydraulic head in the aquitard, and the second model assumes that the depth of the redox-interface is randomly distributed according to a log-normal probability distribution function. The upscaling approach using the random redox model estimated recharge concentrations comparable to the observed concentration in the underlying aquifer. The presented upscaling approach is applicable in distributed catchment models where sub-grid variability cannot be represented by the large grids. 相似文献
944.
945.
Autumn Oczkowski Scott Nixon Kelly Henry Peter DiMilla Michael Pilson Stephen Granger Betty Buckley Carol Thornber Richard McKinney Joaquin Chaves 《Estuaries and Coasts》2008,31(1):53-69
Narragansett Bay has been heavily influenced by human activities for more than 200 years. In recent decades, it has been one
of the more intensively fertilized estuaries in the USA, with most of the anthropogenic nutrient load originating from sewage
treatment plants (STP). This will soon change as tertiary treatment upgrades reduce nitrogen (N) loads by about one third
or more during the summer. Before these reductions take place, we sought to characterize the sewage N signature in primary
(macroalgae) and secondary (the hard clam, Mercenaria mercenaria) producers in the bay using stable isotopes of N (δ15N) and carbon (δ13C). The δ15N signatures of the macroalgae show a clear gradient of approximately 4‰ from north to south, i.e., high to low point source
loading. There is also evidence of a west to east gradient of heavy to light values of δ15N in the bay consistent with circulation patterns and residual flows. The Providence River Estuary, just north of Narragansett
Bay proper, receives 85% of STP inputs to Narragansett Bay, and lower δ15N values in macroalgae there reflected preferential uptake of 14N in this heavily fertilized area. Differences in pH from N stimulated photosynthesis and related shifts in predominance of
dissolved C species may control the observed δ13C signatures. Unlike the macroalgae, the clams were remarkably uniform in both δ15N (13.2 ± 0.54‰ SD) and δ13C (−16.76 ± 0.61‰ SD) throughout the bay, and the δ15N values were 2–5‰ heavier than in clams collected outside the bay. We suggest that this remarkable uniformity reflects a
food source of anthropogenically heavy phytoplankton formed in the upper bay and supported by sewage derived N. We estimate
that approximately half of the N in the clams throughout Narragansett Bay may be from anthropogenic sources. 相似文献
946.
Nathan S. Hall R. Wayne Litaker Elizabeth Fensin Jason E. Adolf Holly A. Bowers Allen R. Place Hans W. Paerl 《Estuaries and Coasts》2008,31(2):402-418
A dense bloom of the ichthyotoxic dinoflagellate Karlodinium veneficum was discovered in the Neuse River Estuary, North Carolina, on 19 October 2006 and was associated with four subsequent fish
kills. Microscopic, photopigment, DNA, and toxicological techniques confirmed bloom identity and toxicity. High-resolution
spatio-temporal data from ship-board and fixed automated sampling stations provided a unique opportunity to investigate the
environmental conditions that initiated, maintained, and terminated the K. veneficum bloom. Bloom initiation and growth were favored by high nutrient availability and reduced dispersal during the period of
declining riverine discharge after Tropical Storm Ernesto. K. veneficum out-competed other co-occurring dinoflagellates, perhaps because of the production of karlotoxins that are known to act as
grazing deterrents and to facilitate mixotrophic feeding. Once the bloom was established, small-scale hydrodynamic processes,
coupled with vertical migration, concentrated cells along a frontal convergence to high densities (>200,000 cells per milliliter).
By 26 October 2006, wind mixing and possible nutrient stress disrupted the bloom. Release of cell-bound toxins during the
bloom collapse likely accounted for the associated fish kill events where fish were reported as exhibiting typical symptoms
of karlotoxin poisoning. The dynamics of this bloom underscore the tight control of harmful algal blooms by meteorological
forcing, hydrology, and sediment nutrient input in this shallow lagoonal estuary. 相似文献
947.
Martin Rosner Michael Wiedenbeck Thomas Ludwig 《Geostandards and Geoanalytical Research》2008,32(1):27-38
An analytical artefact is reported here related to differences in instrumental mass fractionation between NIST SRM glasses and natural geological glasses during SIMS boron isotope determinations. The data presented demonstrated an average 3.4‰ difference between the NIST glasses and natural basaltic to rhyolitic glasses mainly in terms of their sputtering-induced fractionation of boron isotopes. As no matrix effect was found among basaltic to rhyolitic glasses, instrumental mass fractionation of most natural glass samples can be corrected by using appropriate glass reference materials. In order to confirm the existence of the compositionally induced variations in boron SIMS instrumental mass bias, the observed offset in SIMS instrumental mass bias has been independently reproduced in two laboratories and the phenomenon has been found to be stable over a period of more than one year. This study highlights the need for a close match between the chemical composition of the reference material and the samples being investigated. 相似文献
948.
Jeremy M. Testa W. Michael Kemp Walter R. Boynton James D. Hagy III 《Estuaries and Coasts》2008,31(6):1021-1037
We conducted a quantitative assessment of estuarine ecosystem responses to reduced phosphorus and nitrogen loading from sewage
treatment facilities and to variability in freshwater flow and nonpoint nutrient inputs to the Patuxent River estuary. We
analyzed a 19-year dataset of water quality conditions, nutrient loading, and climatic forcing for three estuarine regions
and also computed monthly rates of net production of dissolved O2 and physical transport of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) using a salt- and water-balance model.
Point-source loading of DIN and DIP to the estuary declined by 40–60% following upgrades to sewage treatment plants and correlated
with parallel decreases in DIN and DIP concentrations throughout the Patuxent. Reduced point-source nutrient loading and concentration
resulted in declines in phytoplankton chlorophyll-a (chl-a) and light-saturated carbon fixation, as well as in bottom-layer O2 consumption for upper regions of the estuary. Despite significant reductions in seaward N transport from the middle to lower
estuary, chl-a, turbidity, and surface-layer net O2 production increased in the lower estuary, especially during summer. This degradation of water quality in the lower estuary
appears to be linked to a trend of increasing net inputs of DIN into the estuary from Chesapeake Bay and to above-average
river flow during the mid-1990s. In addition, increased abundance of Mnemiopsis leidyi significantly reduced copepod abundance during summer from 1990 to 2002, which favored increases in chl-a and allowed a shift in total N partitioning from DIN to particulate organic nitrogen. These analyses illustrate (1) the value
of long-term monitoring data, (2) the need for regional scale nutrient management that includes integrated estuarine systems,
and (3) the potential water quality impacts of altered coastal food webs. 相似文献
949.
This paper presents an application of rock engineering system (RES) in an attempt to reveal and assess the inherent instability
potential of 388 sites where equivalent landslides have been manifested and recorded in the region of Karditsa County, Greece.
The main objective has been defining the principal causative and triggering factors responsible for the manifestation of landslide
phenomena, quantify their interactions, obtain their weighted coefficients, and calculate the instability index, which refers
to the inherent potential instability of each natural slope of the examined region. From the statistical interpretation of
the data reported in a well-documented database and concerning the examined failure sites, a clear correlation between the
instability index and the area affected by a single landslide event has been revealed. Almost the entire failure sites, 98%
of the examined slope sites, exhibit an instability index value over 55, a value which is thought to be a critical threshold
for landslide manifestation concerning natural slopes in Karditsa County. It is argued that the presented RES methodology,
engaging the selected set of parameters, could be considered as an effective expert's tool for ranking, in an objectively
optimal and simple way, the instability potential of natural slopes in Karditsa County, and thus providing a tool for sound
zoning landslide hazard. 相似文献
950.
There has been increasing concern about the lack of involvement by social scientists and humanists in a global change program,
although many social scientists are already directly involved in various aspects of research on environmental change, and
their research interests are clearly central to a global change research agenda. Based on a historical review, the role of
social science disciplines as well as social science institutes in an emerging multidecadal global change program is discussed.
Both “plan of action” and “plan of inaction” are suggested to avoid potential pitfalls due to the rush development of a social
science program into the existing global climate change problem. 相似文献