Evidence for the loss of snow-deposited MSA to the interstitial gaseous phase in central Antarctic firn

We have examined several MSA (methanesulfonic acid) records from the upper 200 m of the Antarctic ice sheet and in particular the new Dome F profile. At all the four sites studied, concentration profiles exhibit similar patterns as a function of depth. They suggest that snow metamorphism and solid phase migration are responsible for a marked release of gaseous MSA to interstitial firn air as well as probably to the free atmosphere, in particular at extremely low accumulation sites. Snow acidity can also modify MSA concentration. It is proposed that, below the upper few metres where the communication with the free atmosphere is possible, gaseous MSA may remain in the firn layers and be entrapped later in air bubbles at pore close-off, i.e. when firn is transformed into ice. Chemical measurements on the firn core do not take into account the MSA released to the gaseous phase, but this fraction is measurable in ice samples. In spite of these alterations occurring in the firn layers, relative changes of the atmospheric MSA concentration in the past are probably still there deep within the Antarctic ice sheet. However, for glacial periods, different processes have to be considered in relation to modified aerosol properties.     

Bond rolling resistance and its effect on yielding of bonded granulates by DEM analyses

A discrete element modelling of bonded granulates and investigation on the bond effect on their behaviour are very important to geomechanics. This paper presents a two‐dimensional (2‐D) discrete element theory for bonded granulates with bond rolling resistance and provides a numerical investigation into the effect of bond rolling resistance on the yielding of bonded granulates. The model consists of mechanical contact models and equations governing the motion of bonded particles. The key point of the theory is that the assumption in the original bond contact model previously proposed by the authors (55th CSCE‐ASCE Conference, Hamilton, Ont., Canada, 2002; 313–320; J. Eng. Mech. (ASCE) 2005; 131 (11):1209–1213) that bonded particles are in contact at discrete points, is here replaced by a more reliable assumption that bonded particles are in contact over a width. By making the idealization that the bond contact width is continuously distributed with the normal/tangential basic elements (BE) (each BE is composed of spring, dashpot, bond, slider or divider), we establish a bond rolling contact model together with bond normal/tangential contact models, and also relate the governing equations to local equilibrium. Only one physical parameter β needs to be introduced in the theory in comparison to the original bond discrete element model. The model has been implemented into a 2‐D distinct element method code, NS2D. Using the NS2D, a total of 86 1‐D, constant stress ratio, and biaxial compressions tests have been carried out on the bonded granular samples of different densities, bonding strengths and rolling resistances. The numerical results show that: (i) the new theory predicts a larger internal friction angle, a larger yielding stress, more brittle behaviour and larger final broken contact ratio than the original bond model; (ii) the yielding stress increases nonlinearly with the increasing value of β, and (iii) the first‐yield curve (initiation of bond breakage), which define a zone of none bond breakage and which shape and size are affected by the material density, is amplified by the bond rolling resistance in analogous to that predicted by the original bond model. Copyright © 2006 John Wiley & Sons, Ltd.     

Modelling of deformation response and chemo‐mechanical coupling in chalk

A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd.     

A multi‐level parallelized substructuring‐frontal solution for coupled thermo/hydro/mechanical problems in unsaturated soil

This paper proposes a multi‐level parallelized substructuring–frontal combined algorithm for the analysis of the problem of thermo/hydraulic/mechanical behaviour of unsaturated soil. Temperature, displacement, pore water pressure and pore air pressure are treated as the primary variables in a non‐linear analysis. Details are given firstly of the substructuring–frontal combined approach. The incorporation of the algorithm in a multi‐level parallel strategy is then discussed. The parallel processing can thus be carried out at different substructural levels. The method thus developed impacts, in a positive way, on both computer storage requirement and execution time. Copyright © 2003 John Wiley & Sons, Ltd.     

Descriptors of impulsive signal levels commonly used in underwateracoustics

Impulsive acoustic waveforms are characterized by a different set of derived quantities than are continuous waveforms. This note presents commonly accepted definitions, units, and symbols used to describe the magnitude of impulsive underwater signals     

Multistep matched-field inversion for broad-band data from ASIAEX2001

This paper discusses the results of geoacoustic inversion carried out using explosive charge data from the Asian Seas International Acoustic Experiment (ASIAEX) East China Sea (ECS) Experiment. A multifrequency incoherent matched-field inversion processor and a genetic algorithm (GA) are used for the inversion. A multistep matched field inversion approach is presented, which makes use of the varying sensitivities of wave fields at various frequencies to reduce the inversion problem into a sequence of smaller inversions with fewer unknowns to estimate at each stage. Different parameters are estimated using data at different frequencies according to their sensitivities. Inversion results for different areas in the ECS region are summarized and compared with core data.