Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Implementation of a coupled plastic damage distinct lattice spring model for dynamic crack propagation in geomaterials

This paper studies dynamic crack propagation by employing the distinct lattice spring model (DLSM) and 3‐dimensional (3D) printing technique. A damage‐plasticity model was developed and implemented in a 2D DLSM. Applicability of the damage‐plasticity DLSM was verified against analytical elastic solutions and experimental results for crack propagation. As a physical analogy, dynamic fracturing tests were conducted on 3D printed specimens using the split Hopkinson pressure bar. The dynamic stress intensity factors were recorded, and crack paths were captured by a high‐speed camera. A parametric study was conducted to find the influences of the parameters on cracking behaviors, including initial and peak fracture toughness, crack speed, and crack patterns. Finally, selection of parameters for the damage‐plasticity model was determined through the comparison of numerical predictions and the experimentally observed cracking features.     

Petrogenesis of anomalous K-enriched MORB from the Southwest Indian Ridge: 11°53′E to 14°38′E

Glassy pillow basalts with unusual geochemical characteristics for mid-ocean ridge basalt (MORB) have been dredge sampled from the Southwest Indian Ridge between 12 and 15°E during Leg ANT IV/4 of the F.S. POLARSTERN. Lavas from 4 of 6 dredges are moderately nepheline normative, highly K-enriched (0.5–1.77 wt% K₂O) alkali basalts and hawaiites. Mg-numbers indicate that many of the lavas are fairly primitive (Mg No.=63–67), yet show extreme enrichment in incompatible elements; e.g. Nb (24–60 ppm), Ba (170–470 ppm) and Sr (258–460 ppm). Incompatible-element ratios such as Zr/Nb (3–5) and Y/Nb (0.46–1.1) are extremely low even for E-type (enriched) MORB, whereas (La/Yb)_n ratios are particularly high (3.4–7.8). ⁸⁷Sr/⁸⁶Sr (0.70290–0.70368), ¹⁴³Nd/¹⁴⁴Nd (0.51302–0.51284) and ²⁰⁶Pb/²⁰⁴Pb (18.708–19.564) isotopic ratios further indicate the geochemically enriched nature of these lavas, which range from the compositional field for depleted N-type (normal) MORB towards the composition of Bouvet Island lavas. Mutually correlated incompatible-element and Sr-, Nd- and Pb-isotopic ratios allow a fairly well constrained model to be developed for the petrogenesis of these unusually alkalic mid-ocean ridge lavas. The alkalic nature and degree of enrichment in incompatible elements is ascribed to particularly low degrees of partial melting (3–5 wt%), at greater than usual depth, of a source region that has experienced prior geochemical enrichment (by veining) related to the upwelling Bouvet mantle plume. To account for the observed compositional variations, a model is proposed whereby mixing between partial melts derived from these geochemically enriched silicate veins, and an incipient to low percentage (±2%) melt from the surrounding geochemically depleted suboceanic asthenosphere occurs as a consequence of increasing degree of melting with adiabatic upwelling. Eruption of these alkalic lavas in this spreading ridge environment is attributed to a temporary hiatus in tholeiitic volcanism and associated spreading along this section of the Southwest Indian Ridge, related to readjustment of spreading direction to a more stable plate geometry.     

Late Quaternary (Marine Isotope Stage 3 to Recent) sedimentary evolution of the Basque shelf (southern Bay of Biscay)

Late Quaternary (MIS 3 to Recent) oceanographic evolution of the Basque shelf has been analysed for the first time based on the sedimentological analysis of three cores obtained from the middle and outer shelves. The cores are located in two interfluves separated by the San Sebastian canyon. The variability of the percentage of the planktonic foraminifera species Neogloboquadrina pachyderma sin. and of δ¹⁸O_bull allowed us to identify the influence of colder and warmer waters in the Basque shelf during the late Quaternary. From ～56 cal. ka BP to the end of the Last Glacial Maximum (19 cal. ka BP) the sedimentary record shows a decreasing trend in the mean grain size that correlates with the eustatic sea‐level fall. The last Deglaciation (19–11.5 cal. ka BP) is characterized by a sea‐level rise that produced an important hiatus in the western outer shelf. During the Holocene, the middle and outer shelves present different behaviours. From 11.5 to 6.7 cal. ka BP, in the outer shelf the sea‐level rise that started during the Deglaciation produced a hiatus, whereas in the middle shelf the sedimentary succession records the presence of warm to temperate waters. Between 6.7–4.9 cal. ka BP, the entrance of cold surface water‐masses that only affected the middle shelf has been identified, and temperate to warm waters occurred in the outer shelf. The cold surface water‐masses retreated during 4.9–4.3 cal. ka BP in the middle shelf. Finally, from 4.3 cal. ka BP to Recent, the middle shelf registers a hiatus due to sea‐level stabilization after a generalized transgression, synchronous to a decrease in the energy of the water‐masses in the outer shelf. In conclusion, the environmental changes detected in the Basque shelf are attributed to both regional and eustatic sea‐level changes.     

Transport in a 2-D saturated porous medium: A new method for particle tracking

A new method for solving the transport equation based on the management of a large numbe of particles in a discretized 2-D domain is presented. The method uses numerical variables to represent the number of particles in a given mesh and is more complex than the 1-D problem. The first part of the paper focuses on the specific management of particles in a 2-D problem. The method also would be valid for three dimensions as long as the medium can be modeled similar to a layered system. As the particles are no longer tracked individually, the algorithm is fast and does not depend on the number of particles present. The numerical tests show that the method is nearly numerical dispersion free and permits accurate calculations even for simulations of low-concentration transport. Because each mesh is considered as a closed system between two successive time steps, it is easy to add adsorption phenomenon without any problem of numerical stability. The model is tested under conditions that are extremely demanding for its operating mode and gives a good fit to analytical solutions. The conditions in which it can be used to best advantage are discussed.     

Geologic and hydrologic settings for development of freshwater lenses in arid lands

Satellite observations were used to test the validity of previously identified favourable conditions for the formation of freshwater lenses, identify additional potential occurrences, and model modern potential recharge in the Raudhatain Watershed (3696) in northern Kuwait. Favourable conditions include infrequent yet intensive precipitation events, drainage depressions to collect the limited runoff, and presence of conditions (e.g. high infiltration capacity) that promote groundwater recharge and preservation (e.g. underlying saline aquifer) of infiltrating groundwater as freshwater lenses floating over saline aquifer water due to differences in density. Specifically, the following field and satellite‐based observations were noted for the Raudhatain Watershed: (1) Over ~30 precipitation events were identified from the Tropical Rainfall Measuring Mission precipitation data (1998–2009); (2) slope is gentle (2 m/km), and the surface is largely (80%) covered by alluvial deposits with high infiltration capacities (up to 9 m/day); (3) no flows and long‐term ponding were reported at the watershed outlet or detected from Landsat thematic mapper images; (4) infiltration is high based on increases in soil moisture content (from an advanced microwave scanning radiometer) and vegetation index following large precipitation events; and (5) freshwater lenses that overlie highly saline [total dissolved solids (TDS): >35 000] unconfined aquifers underlying the watershed are absent in the southern regions, where infiltrating fresh water mixes with the less saline groundwater (TDS: <10 000). Twenty potential locations (size: 1 to 75 km²) for freshwater lens development were identified in northern Kuwait, and continuous rainfall–runoff models (Soil Water and Assessment Tool) were applied to provide a first‐order estimation of the average annual recharge in the watershed (127 × 10⁶ m³) and freshwater lenses (8.17 × 10⁶ m³). Results demonstrate the settings for enhanced opportunities for groundwater recharge, outline the amounts of and preservation conditions for the groundwater feeding the freshwater lenses, and highlight potential applications and locations of freshwater lenses in similar settings elsewhere in the Arabian Peninsula and beyond. Copyright © 2013 John Wiley & Sons, Ltd.     

Modeling of an actively braced full‐scale building considering control–structure interaction

Recently, the application of active control to seismic‐excited buildings has attracted international attention. To demonstrate the practical applicability of active control, we have conducted experimental tests using a full‐scale three‐storey building equipped with active bracing systems on the shake table at the National Center for Research on Earthquake Engineering (NCREE), Taiwan. Experimental results indicate that the control–structure interaction (CSI) effect is significant. A state‐space analytical model of this actively controlled building taking into account the CSI effect is established in this paper using a system identification technique based on curve‐fitting of transfer functions. To verify the accuracy of the analytical model for simulating the controlled response, four sets of linear quadratic Gaussian (LQG) controllers using acceleration feedback are designed and further experimental tests are conducted for comparison. It is demonstrated that the correlations between the simulation and experimental results are remarkable. The construction of an accurate analytical model is important for active control, and such an analytical model can be used for future benchmark studies of different control algorithms based on numerical simulations. Copyright © 2000 John Wiley & Sons, Ltd.     

87Sr/86Sr ratios in hydrothermal waters and deposits from the East Pacific Rise at 21°N

⁸⁷Sr/⁸⁶Sr ratios of three hydrothermal waters collected on the East Pacific Rise at 21°N define a mixing line between seawater and a hydrothermal end-member at 0.7030 which is derived by seawater-basalt interaction at ca. 350°C and water/rock ratio of about 1.5. Sr concentrations are not affected in the process while Mg uptake from seawater is almost complete. Up to2/3 of this hydrothermal component is involved in anhydrite precipitation while the Sr isotopic ratio in sulfides (chalcopyrite + sphalerite) cannot be distinguished from that of sulfate. It is estimated that ca. 1 × 10¹⁰ moles of strontium are yearly cycled in the hydrothermal systems of mid-oceanic ridges, thereby affecting the⁸⁷Sr/⁸⁶Sr budget of seawater. Mass balance between river runoff, limestone precipitation and ridge basalt alteration suggests that the⁸⁷Sr/⁸⁶Sr ratios of the river runoff are in the range 0.7097–0.7113, and are largely dominated by limestone alteration.     

On the inclusion of ground-based gravity measurements to the calibration process of a global rainfall-discharge reservoir model: case of the Durzon karst system (Larzac, southern France)

This work examines the relevance of the inclusion of ground-based gravity data in the calibration process of a global rainfall-discharge reservoir model. The analysis is performed for the Durzon karst system (Larzac, France). The first part of the study focuses on the hydrological interpretation of the ground-based gravity measurements. The second part of the study investigates further the information content of the gravity data with respect to water storage dynamics modelling. The gravity-derived information is found unable to either reduce equifinality of the single-objective, discharge-based model calibration process or enhance model performance through assimilation.     

Social networks and healthy cities: spreading good practices based on a spanish case study

The city of Vitoria‐Gasteiz in Spain is considered a “healthy city” and has implemented sustainable actions to increase the mobility of its healthcare professionals. The objectives of this study are firstly to account for the use of bicycles at work as a strategy for a healthy city and secondly to propose a conceptual framework for analyzing this network and its capacity to spread their practices The paradigm proposed is that of social networks, within which sharing between contacts is explained by means of two models: the “threshold model” and “opinion leaders”.