Mediterranean outflow through the Strait of Gibraltar since 18,000 Years B.P.: Mineralogical and geochemical arguments

Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.     

Comparison of three oxidation methods used for the analysis of the dissolved organic carbon in seawater

Three methods for the determination of dissolved organic carbon in seawater were compared. Samples were analysed using persulphate oxidation, high-temperature combustion, and ultraviolet photo-oxidation. The dissolved organic carbon content of the seawater samples ranged from 0.6 to 1.6 mg C/I. This study shows that results of high-temperature oxidation and photo-oxidation procedures differ by less than 5%, whereas results with persulphate oxidation are about 15% less than those obtained with the high-temperature oxidation. The relative merits of each of the oxidation techniques for the determination of organic matter in seawater are discussed.     

Effect of dispersion on impulsive waves

The generation and propagation of surface waves resulting from suddenly created disturbances over water surfaces is investigated. The initial boundary conditions defining the disturbance are given either by a velocity of the free surface, an initial elevation of the free surface or a pressure impulsively applied on the free surface. It is shown that the corresponding three forms of solutions are related by a simple time derivative. Linear solutions are obtained in the cases where the wave motion is assumed to be nondispersive, mildly dispersive and fully dispersive, as well as in the case where the motion is given by the method of stationary phase. Criteria are established to indicate the limit of validity of each method.     

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.     

The Meso-Cenozoic thermo-tectonic evolution of the Eastern Pyrenees: an <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar fission track and (U–Th)/He thermochronological study of the Canigou and Mont-Louis massifs

Vertical displacements on the SW–NE Têt fault (Eastern Pyrenees Axial Zone, France), which separates the Variscan Canigou-Carança and Mont-Louis massifs, were constrained using a thermochronologic multi-method approach. ⁴⁰Ar/³⁹Ar data from the granitic Mont-Louis massif record its Variscan cooling history and reveal no ages younger than Early Cretaceous, while the Canigou-Carança gneiss massif records systematically younger ⁴⁰Ar/³⁹Ar ages. These younger ⁴⁰Ar/³⁹Ar ages in the Canigou-Carança gneiss massif are the result of partial to total rejuvenation of argon isotopic systems related to a thermal flow coeval with the Cretaceous HT-BP metamorphism in the North Pyrenean Zone. Only the deepest rocks from the Canigou-Carança suffered this extensive Mid-Cretaceous thermal overprint probably due to differential burial around 4 km at that time. The post Mid-Cretaceous vertical displacements along the Têt fault are recorded by “low” temperature thermochronology using K-feldspar ⁴⁰Ar/³⁹Ar, zircon and apatite fission track and (U–Th)/He datings. The Mont-Louis granite samples experienced a long period of protracted cooling reflecting a lack of thermo-tectonic activity in this area from Late Palaeozoic to Early Cenozoic, followed by cooling from 55–60 Ma to Late Eocene at a mean rate of 15–20°C/Ma in the final stage. This cooling stage corresponds to Têt fault reactivation with a reversed component, promoting exhumation of the Mont-Louis roof zone contemporaneously with the south-vergent Pyrenean thrusting. In the Canigou-Carança massif, the main cooling event occurred from 32 to 18 Ma at a maximum rate of 30°C/Ma during Early Oligocene followed by a more moderate rate of 3°C/Ma from Late Oligocene to Early Burdigalian, coeval with the normal reactivation of the Têt fault in brittle conditions that accommodated the final exhumation of the massif during the opening of the Gulf of Lion.     

Inner part observation of theβ pictoris disk

The inner regions of the circumstellar disk around Pictoris might be dust-free due to a possible planet which may have cleared up dust particles. We present a new observational technique based on the use of an anti-blooming CCD in order to directly image this zone. The structure of the disk is revealed down to 2 arcsec from the star (30 AU). We show that the Pic disk brightness is neutral inV, R, andI _C , but drops down when going inward inB, possibly related to a change in the dust composition. Also, a slight disk asymmetry is present but inverted from the outer to the inner zones.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.     

Particulate content of savanna fire emissions

As part of the FOS-DECAFE experiment at Lamto (Ivory Coast) in January 1991, various aerosol samples were collected at ground level near prescribed fires or under local background conditions, to characterize the emissions of particulate matter from the burning of savanna vegetation. This paper deals with total aerosol (TPM) and carbon measurements. Detailed trace element and polycyclic hydrocarbon data are discussed in other papers presented in this issue.Near the fire plumes, the aerosols from biomass burning are primarily of a carbonaceous nature (C%70% of the aerosol mass) and consist predominantly of submicron particles (more than 90% in mass.) They are characterized by their organic nature (black to total carbon ratio Cb/Ct in the range 3–20%) and their high potassium content (K/Cb0.6). These aerosols undergo aging during their first minutes in the atmosphere causing slight alterations in their size distribution and chemical composition. However, they remain enriched in potassium (K/Cb=0.21) and pyrene, a polycyclic aromatic hydrocarbon, such that both of these species may be used as tracers of savanna burning aerosols. We show that during this period of the year, the background atmosphere experiences severe pollution from both terrigenous sources and regional biomass burning (44% of the aerosol). Daynight variations of the background carbon concentrations suggest that fire ignition and spreading occur primarily during the day. Simultaneous TPM and CO₂ real-time measurements point to a temporal and spatial heterogeneity of the burning so that the ratio of the above background concentrations (TPM/CO₂) varies from 2 to 400 g/kg C. Smoldering processes are intense sources of particles but particulate emissions may also be important during the rapidly spreading heading fires in connection with the generation of heavy brown smoke. We propose emission factor values (EF) for aerosols from the savanna biomass burning aerosols: EF (TPM)=11.4±4.6 and 69±25 g/kg C_{dry plant} and EF(Ct)=7.4±3.4 and 56±16 g C/kg C_{dry plant} for flaming and smoldering processes respectively. In these estimates, the range of uncertainty is mostly due to the intra-fire variability. These values are significantly lower than those reported in the literature for the combustion of other types of vegetation. But due to the large amounts of vegetation biomass being burnt in African savannas, the annual flux of particulate carbon into the atmosphere is estimated to be of the order of 8 Tg C, which rivals particulate carbon emissions from anthropogenic activities in temperate regions.     

Close binary systems before and after mass transfer: A comparison of observations and theory

From a search through the literature 174 close binaries with known absolute dimensions have been sampled. Distinction is made between systems before and after mass exchange. Mass, period and mass ratio distributions and relations of the group of unevolved binaries (i.e., prior to mass exchange) are transformed into corresponding distributions and relations of evolved binaries. The transformations are based upon theM _1f=g(M _1f) relation derived from an extended set of published theoretical computations of the evolution of close binaries. From this relation the following characteristics of the system after mass exchange are computed:M _1f,M _2f (andq _f),P _f. Five different modes of mass transfer were applied for the computation of the values ofP _f andM _2f. The variation of the period was calculated using the formalism given by Vanbeverenet al. (1979). The results are compared to the observations of binary systems after mass exchange, and are discussed together with an analysis of the effect of several selection effects present in the distributions. The main conclusion is that, during mass exchange in close binaries, more than 50% of the mass is lost to the system in the process of transfer, removing a large amount of angular momentum.This research is supported by the National Foundation of Collective Fundamental Research of Belgium (F.K.F.O.) under No. 2.9009.79.     

Electrons in the solar corona

The polarimetric survey of electrons in the K-corona initiated at Pic-du-Midi and Meudon Observatories in 1964 now covers a full solar cycle of activity. The measurements are photometrically calibrated in an absolute scale.In June 1967 a persistent coronal feature was fan-shaped as a lame coronale above quiescent prominences. We deduce an electron density of N ₀ = 1.5 × 10⁸ at 60 000 km above the photosphere, a total number of 14 × 10³⁹ electrons, a hydrostatic temperature of 1.7 × 10⁶ K, and a total thermal energy 3N _eKT = 1.0 × 10³¹ ergs. When a center of activity appeared, a major localized condensation developed to replace the old elongated feature, with N ₀ = 4.5 × 10⁸, a total of 4.5 × 10³⁹ electrons and the same temperature of 1.7 × 10⁶ K.Also, a fan-shaped feature of exceptional intensity was analysed on 8 September 1966, with N ₀ = 6 × 10⁸ and a total of 24 × 10³⁹ electrons.Fan-shaped features are frequent above quiescent prominences. They degenerate above a height of 2R into thinner isolated columns or blades with temperatures also around 1.7 × 10⁶ K.