Assessment of drought over the past two millennia using near-shore sediment cores from a Canadian boreal lake

Lack of long-term studies on drought in the boreal region of northwest Ontario limits our ability to assess the vulnerability of this region to climate change. We investigated changes in diatoms, scaled chrysophytes, and sedimentary pigments in two near-shore cores from Gall Lake to infer limnological and water-level changes over the last two millennia. The two coring locations, at modern water depths of 7.5 and 11.5 m, were selected to contrast inferences for past lake level based on distance from the modern water-depth boundary between predominantly benthic and planktonic diatom assemblages in surface sediments (6.0 m). Diatom-inferred depth inferences were more variable in the core from 7.5-m water depth, consistent with the hypothesis that the greatest changes occurred at water depths closest to the benthic:planktonic boundary. Both sites revealed a pronounced drought from ~AD 950 to 1300, synchronous with the medieval climate anomaly (MCA). This finding suggests a northeast expansion of the arid MCA into northwest Ontario, extending the known spatial extent of this megadrought. Scaled chrysophytes and sedimentary pigments suggest a recent increase in thermal stratification. Our findings indicate this region is more susceptible to changes in moisture than was previously suspected based on the instrumental record for the past century.     

The Henry's Law Constants of the Haloacetic Acids

Henry's law constants K_H (mol kg^-1 atm^-1) have been measured between 278.15 K and 308.15 K for the following organic acids: CH₂FCOOH (ln(K_H[298.15 K]) = 11.3 ± 0.2), CH₂ClCOOH (11.59 ± 0.14), CH₂BrCOOH (11.94 ± 0.21), CHF₂COOH (10.32 ± 0.10), CHCl₂COOH (11.69 ± 0.11), CHBr₂COOH (12.33 ± 0.29), CBr₃COOH (12.61 ± 0.21), and CClF₂COOH (10.11 ± 0.12). The variation of K_H with temperature was determined for all acids except CH₂FCOOH and CBr₃COOH, with _r H° for the dissolution reaction ranging from –85.2 ± 2.6 to –57.1 ± 2.5 kJ mol^-1, meaning that their solubility is generally more sensitive to temperature than is the case for the simple carboxylic acids. The Henry's law constants show consistent trends with halogen substitution and, together with their high solubility compared to the parent (acetic) acid (ln(K_H[298.15 K]) = 8.61), present a severe test of current predictive models based upon molecular structure. The solubility of haloacetic acids and strong dissociation at normal pH mean that they will partition almost entirely into cloud and fog in the atmosphere (0.05–1.0 g H₂O m^-3), but can reside in both phases for the liquid water contents typical of aerosols (10^-5-10^-4 g H₂O m^-3).     

Bacterial communities are sensitive indicators of contaminant stress

With many environments worldwide experiencing at least some degree of anthropogenic modification, there is great urgency to identify sensitive indicators of ecosystem stress. Estuarine organisms are particularly vulnerable to anthropogenic contaminants. This study presents bacterial communities as sensitive indicators of contaminant stress. Sediments were collected from multiple sites within inner and outer zones of three heavily modified and three relatively unmodified estuaries. Bacterial communities were censused using Automated Ribosomal Intergenic Spacer Analysis and analysed for a suite of metal and PAH contaminants. Shifts in both bacterial community composition and diversity showed strong associations with sediment contaminant concentrations, particularly with metals. Importantly, these changes are discernable from environmental variation inherent to highly complex estuarine environments. Moreover, variation in bacterial communities within sites was limited. This allowed for differences between sites, zones and estuaries to be explained by variables of interest such as contaminants that vary between, but not within individual sites.     

The Qso Hosts I Zw 1 and 3C 48: Prototypes of a Merger-Driven Quasar Evolution?

I Zw 1 and 3C 48 are two neighboring template objects at a later stage of the hypothesized merger-driven evolutionary sequence from ultra-luminous infrared galaxies (ULIRGs) to quasi-stellar objects (QSOs). Since galaxy mergers are assumed to trigger the evolution, it is important to confirm the merger properties of transitionary objects. Using multi-wavelength observations and N-body simulations, the merger histories of I Zw 1 and 3C 48 have been investigated in two separate case studies. Here, the results from both studies are compared and their relevance for the evolutionary hypothesis is discussed.This research is partly based on observations with ISAAC at the Very Large Telescope (VLT) of the European Southern Observatory (ESO) under projects 67.B-0009 and 67.B-0019.     

Limited differences among habitats in deep‐sea macro‐infaunal communities off New Zealand: implications for their vulnerability to anthropogenic disturbance

The spread of human activities into the deep sea may pose a high risk to benthic communities and affect ecosystem integrity. The deep sea is characterized by physical and biological heterogeneity and different habitat types are likely to differ in their vulnerability to anthropogenic impacts. However, across‐habitat comparisons are rare, and no comprehensive ecological risk assessment has yet been developed. To address this gap in our knowledge, we compared macro‐infaunal community structure in four habitats (slope, canyons, seamounts and methane seeps) at depths between 700 and 1500 m in the Hikurangi Margin and Bay of Plenty regions off New Zealand. The most striking contrast in community structure was between the two study regions, due to an order of magnitude difference in macro‐infaunal abundance that we believe was caused by differences in surface productivity and food availability at the sea bed. We found differences in structural and functional attributes of macro‐infaunal communities among some habitats in the Hikurangi Margin (slope, canyon and seep), but not in the Bay of Plenty. We posit that differences between canyon and slope communities on the Hikurangi Margin are due to enhanced food availability inside canyons compared with adjacent slope habitats. Seep communities were characterized by elevated abundance of both symbiont‐bearing and heterotrophic taxa, and were the most distinct, and variable, among the habitats that we considered on the Hikurangi Margin. Communities of seamounts were not distinct from slope or canyon communities on the Hikurangi Margin, probably reflecting similar environmental conditions in these habitats. The communities of deep‐sea canyon and seep habitats on the Hikurangi Margin were sufficiently dissimilar from each other and from slope habitats to warrant separate management consideration. By contrast, the low dissimilarity between communities of canyon and slope habitats in the Bay of Plenty suggests that habitat‐based management is not required in this region, for macro‐infauna at least. Although the two study regions share similar species pools, populations of the Hikurangi Margin region may be less vulnerable than the sparser populations of the Bay of Plenty due to the higher availability of potential colonizers and faster population growth. Thus regions, and habitats in some regions, should be subject to separate ecological risk assessment to help identify the key risks and consequences of human activities, and to inform options for reducing or mitigating impacts.     

QUEST on DASI: a South Pole CMB polarization experiment

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.     

Variability of organic δC and C/N in the Mersey Estuary, U.K. and its implications for sea-level reconstruction studies

Microfossil analysis (e.g. diatoms, foraminifera and pollen) represents the cornerstone of Holocene relative sea-level (RSL) reconstruction because their distribution in the contemporary inter-tidal zone is principally controlled by ground elevation within the tidal frame. A combination of poor microfossil preservation and a limited range in the sediment record may severely restrict the accuracy of resulting RSL reconstructions. Organic δ¹³C and C/N analysis of inter-tidal sediments have shown some potential as coastal palaeoenvironmental proxies. Here we assess their viability for reconstructing RSL change by examining patterns of organic δ¹³C and C/N values in a modern estuarine environment. δ¹³C and C/N analysis of bulk organic inter-tidal sediments and vegetation, as well as suspended and bedload organic sediments of the Mersey Estuary, U.K., demonstrate that the two main sources of organic carbon to surface saltmarsh sediments (terrestrial vegetation and tidal-derived particulate organic matter) have distinctive δ¹³C and C/N signatures. The resulting relationship between ground elevation within the tidal frame and surface sediment δ¹³C and C/N is unaffected by decompositional changes. The potential of this technique for RSL reconstruction is demonstrated by the analysis of part of an early Holocene sediment core from the Mersey Estuary. Organic δ¹³C and C/N analysis is less time consuming than microfossil analysis and is likely to provide continuous records of RSL change.     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.     

Partnering between a geography department and a community initiative to provide a wind resource assessment for the Blueskin Bay region,Otago, New Zealand

This paper explores the partnership between a community group and a geography department to assess the wind energy potential of the Blueskin Bay region in southern New Zealand. The partnership has provided opportunities for research and is of strategic importance. Year‐long wind observations and numerical modelling have revealed that the hills surrounding Blueskin Bay show potential for wind energy generation. Despite challenges for both parties, the university–community partnership has allowed a successful research platform to be established.     

Reconstructing spatio-temporal patterns of debris-flow activity using dendrogeomorphological methods

Debris flows are a major threat in many parts of the Alps, where they repeatedly cause severe damage to infrastructure and transportation corridors or even loss of life. Nonetheless, the spatial behavior of past debris-flow activity and the analysis of areas affected during particular events have been widely neglected in reconstructions so far. It was therefore the purpose of this study to reconstruct spatio-temporal patterns of past debris flows on a forested cone in the Swiss Alps (Bruchji torrent, Blatten, Valais). The analysis of past events was based on a detailed geomorphic map (1:1000) of all forms related to debris flows as well as on tree-ring series from 401 heavily affected trees (Larix decidua Mill. and Picea abies (L.) Karst.) growing in or next to deposits. The samples were analyzed and growth disturbances related to debris-flow activity assessed, such as tangential rows of traumatic resin ducts, the onset of reaction wood or abrupt growth suppression or release.In total, 960 growth disturbances were identified in the samples, belonging to 40 different event years between A.D. 1867 and 2005. In addition, the coupling of tree-ring data with the geomorphic map allowed reconstruction of eleven formerly active channels and spatial representation of individual events. Based on our results we believe that before 1935, debris flows preferentially used those channels located in the western part of the cone, whereas the eastern part of the cone remained widely unaffected. The spatial representation of the 40 events also allowed identification of five different spatial patterns for debris flows at the study site.