Low-head hyperfiltration through Jurassic-Cretaceous metamorphic Darrington Phyllite discs (from the Northwest Cascades of Washington State, USA)

Membrane behavior in naturally occurring and engineering systems refers to the restriction of solute migration through a membrane relative to the migration of the solvent. Hyperfiltration is the net flux that results when two solutions of different concentration are separated by a membrane and an external force is applied in excess of the osmotic pressure. Clay membranes containing layered fabric have higher efficiencies than membranes with random fabrics. Therefore, low-permeability rocks with a foliated fabric might exhibit membrane properties. Four hyperfiltration experiments were conducted on samples of Darrington Phyllite from the Easton Metamorphic Suite of the Northwest Cascades, Washington (USA). Chloride solutions were passed through thin, intact discs at relatively low heads. At the end of the experiments, dissolved chloride concentrations had increased 110–140 % and calculated reflection coefficients ranged from 0.87 to 0.88; this was attributed to partial solute rejection by the phyllite. Natural scenarios in which phyllite might exhibit membrane properties include (1) shallow perched aquifers bounded by phyllite, (2) overpressured aquifers bounded by phyllite, (3) phyllite-bounded aquifers with significant vertical groundwater flows, and (4) ultrafiltration during metamorphic devolatilization at depth. Membrane processes exhibited by phyllite may also contribute to the formation of some low-temperature ore bodies.     

Access and Equity in Greenspace Provision: A Comparison of Methods to Assess the Impacts of Greening Vacant Land

This research explores three methods of measuring access to greenspace in Philadelphia and their implications for assessing equity in access based on race and socioeconomic status. These three methods are then used to assess the impacts of a vacant land greening program which turns vacant lots into temporary greenspaces. This research explores the differences between findings when access to greenspace is measured based on distance to any greenspace, total amount of greenspace to which residents have access, or a hybrid measure in which access is determined based on proximity to a threshold amount of greenspace. Not only do assessments of equity differ between the three approaches, but so do determinations of the impact of greening vacant land. Blacks, Hispanics and renters are more likely to live close to a public greenspace than whites or homeowners, but live in proximity to smaller overall amounts of greenspace. Greening vacant land increases the proportion of all residents who live within walking distance of a greenspace and lessens but does not eliminate differences in total greenspace access. The greatest effects of greening vacant land are seen in addressing differences in relative likelihood of having access to a threshold amount of greenspace.     

The Use of Environmental Features on Tactile Maps by Navigators Who Are Blind

Maps designed for and used by sighted audiences benefit from map symbol standardization and convention but, with very limited exception (most notably two European projects), neither standardization nor convention guides the design and use of symbols for tactile maps. In this project, we developed and field tested symbolization for and use of tactile street maps. The development process included consultation with the literature as well as with field experts (orientation and mobility teachers, Braillists, and teachers working with students who are blind or have low vision). Following development, we undertook a three-year field testing and validation phase, in which we conducted pilot testing and formal testing with travelers who are blind or have low vision. Research results reveal not only a discriminable and useful tactile symbol set but also environmental feature use by travelers who are blind or have low vision.     

Defining Optimal Freshwater Flow for Oyster Production: Effects of Freshet Rate and Magnitude of Change and Duration on Eastern Oysters and <Emphasis Type="Italic">Perkinsus marinus</Emphasis> Infection

In coastal Louisiana, the development of large-scale freshwater diversion projects has led to controversy over their effects on oyster resources. Using controlled laboratory experiments in combination with a field study, we examined the effects of pulsed freshwater events (freshet) of different magnitude, duration, and rate of change on oyster resources. Laboratory and field evidence indicate that low salinity events (<5 psu) decreased Perkinsus marinus infection intensities. Furthermore, when salinity was low (<5 psu), parasite infection intensities continued to decrease even as temperatures exceeded 20°C. At the same time, oyster growth was positively correlated with salinity. To maximize oyster production, data indicate that both low and high salinity events will be necessary.     

Relaxational effects in radiating stellar collapse

Relaxational effects in stellar heat transport can in many cases be significant. Relativistic Fourier–Eckart theory is inherently quasi-stationary, and cannot incorporate these effects. The effects are naturally accounted for in causal relativistic thermodynamics, which provides an improved approximation to kinetic theory. Recent results, based on perturbations of a static star, show that relaxation effects can produce a significant increase in the central temperature and temperature gradient for a given luminosity. We use a simple stellar model that allows for non-perturbative deviations from staticity, and confirms qualitatively the predictions of the perturbative models.     

The release of dissolved actinium to the ocean: A global comparison of different end-members

The measurement of short-lived ²²³Ra often involves a second measurement for supported activities, which represents ²²⁷Ac in the sample. Here we exploit this fact, presenting a set of 284 values on the oceanic distribution of ²²⁷Ac, which was collected when analyzing water samples for short-lived radium isotopes by the radium delayed coincidence counting system. The present work compiles ²²⁷Ac data from coastal regions all over the northern hemisphere, including values from ground water, from estuaries and lagoons, and from marine end-members. Deep-sea samples from a continental slope off Puerto Rico and from an active vent site near Hawaii complete the overview of ²²⁷Ac near its potential sources.The average ²²⁷Ac activities of nearshore marine end-members range from 0.4 dpm m^− 3 at the Gulf of Mexico to 3.0 dpm m^− 3 in the coastal waters of the Korean Strait. In analogy to ²²⁸Ra, we find the extension of adjacent shelf regions to play a substantial role for ²²⁷Ac activities, although less pronounced than for radium, due to its weaker shelf source. Based on previously published values, we calculate an open ocean ²²⁷Ac inventory of 1.35 * 10¹⁸ dpm ²²⁷Ac_ex in the ocean, which corresponds to 37 moles, or 8.4 kg. This implies a flux of 127 dpm m⁻² y^− 1 from the deep-sea floor. For the shelf regions, we obtain a global inventory of ²²⁷Ac of 4.5 * 10¹⁵ dpm, which cannot be converted directly into a flux value, as the regional loss term of ²²⁷Ac to the open ocean would have to be included.Ac has so far been considered to behave similarly to Ra in the marine environment, with the exception of a strong Ac source in the deep-sea due to ²³¹Pa_ex. Here, we present evidence of geochemical differences between Ac, which is retained in a warm vent system, and Ra, which is readily released [Moore, W.S., Ussler, W. and Paull, C.K., 2008-this issue. Short-lived radium isotopes in the Hawaiian margin: Evidence for large fluid fluxes through the Puna Ridge. Marine Chemistry]. Another potential mechanism of producing deviations in ²²⁷Ac/²²⁸Ra and daughter isotope ratios from the expected production value of lithogenic material is observed at reducing environments, where enrichment in uranium may occur. The presented data here may serve as a reference for including ²²⁷Ac in circulation models, and the overview provides values for some end-members that contribute to the global Ac distribution.     

On radiating stellar collapse with shear

Relativistic models of radiating stellar collapse with shear require careful checking of all the equations and quantities involved. We illustrate this by showing that, in a recently proposed model, the metric ansatz is in fact too restrictive to allow any radial evolution to occur, and only tangential evolution is possible. Furthermore, the assumption of pressure isotropy is shown to reduce the model to the static case without radiation or shear.     

The role of hydrocarbons in the lonospheres of the outer planets

The role of hydrocarbons as a possible sink for H⁺ and H₃⁺ ions in the lower ionosphere of the outer planets is examined. Calculations indicate that H⁺ and H₃⁺ are efficiently converted to hydrocarbon ions on reaction with methane. The terminal ions, CH₅⁺ and C₂H₅⁺ are rapidly neutralized in dissociative recombination with electrons. Extreme ultraviolet photolysis of hydrocarbons as a potential additional source of lower elevation ions in investigated.     

Coastal Bathymetry from Hyperspectral Remote Sensing Data: Comparisons with High Resolution Multibeam Bathymetry

We present a large-scale quantitative test of a hyperspectral remote-sensing reflectance algorithm. We show that coastal bathymetry can be adequately derived through model inversions using data from the Airborne Visible-Infrared Imaging Spectrometer instrument. Data are analyzed from a shore-perpendicular transect 5 km offshore Sarasota, Florida at water depths ranging from 10 m to 15.5 m. Derived bottom depths are compared to a high-resolution multibeam bathymetry survey. Model-derived depths are biased 4.9% shallower than the mean of the multibeam depths with an RMS error of 7.83%. These results suggest that the model performs well for retrieving bottom depths from hyperspectral data in subtropical coastal areas in water depths ranging from 10 m to 15.5 m.     

Barrier island stratigraphy and Holocene history of west-central Florida

Although the morphology of the barrier-inlet system along the west-central Florida coast is quite complicated, the stratigraphy of these barriers is rather simple. The basal Holocene unit in most cores is an organic-rich, muddy sand that represents a vegetated, paralic marine, coastal environment similar to that which is north and south of the present barrier system. Above that unit is a muddy, bioturbated sand that displays a marine fauna at most locations but also contains Crassostrea virginica in a few places. These sediments accumulated in a low-energy marine setting that may or may not have been protected by a barrier island. Much of this facies also represents sediment that was delivered as washover deposits in an intertidal or subtidal setting and was subsequently bioturbated. The facies that can be attributed to a barrier island with some certainty are no more than 3000 years old, and on most islands, are much younger. These are the shelly sand and sorted sand facies. The shelly strata represent deposition in nearshore, beach, supratidal washover or intertidal spillover environments, and tidal inlet and tidal delta channels, whereas the sorted sand is typical of eolian deposition in dunes or the backbeach and some tidal delta elements. The presence of Holocene oyster beds offshore of a present barrier suggests that some of these islands formed significantly offshore and moved to their present position through washover. It is likely that most of these barriers initially formed through upward shoaling by waves. Although there is significant morphologic difference between the wave-dominated and mixed-energy, drumstick barrier islands, their stratigraphy is quite similar. The only significant difference is the presence of extensive progradation on at least part of the drumstick islands and a relatively high amount of former washover deposits on the wave-dominated type.