Restoration of the eutrophic Orbetello lagoon (Tyrrhenian Sea, Italy): water quality management

The Orbetello lagoon (Tyrrhenian coast, Italy) receives treated urban and land based fishfarms wastewater. The development of severe eutrophication imposed the three main activity adoption focuses on (1) macroalgae harvesting; (2) pumping of water from the sea; (3) confining wastewater to phytotreatment ponds. The responses to these interventions were rapid and macroalgal reduction growth and seagrass return were recorded. Since 1999, a new macroalgal development was recorded. The aim of this research was to discover whether the recent macroalgal growth can be attributed to the continuing wastewater influx from the remaining persistent anthropic sources (PAS) or from the sediment nutrient release. A monitoring programme was carried out between August 1999 and July 2000 in order to measure dissolved inorganic nitrogen and phosphorus in the wastewaters entering into the lagoon and in central lagoon areas, seaweed and seagrass distribution and lagoon N, P annual budgets. The results showed higher N and P values close to PAS. The distribution of the macroalgal species confirms that the available P comes almost entirely from these remaining PAS. In conclusion, the environmental measures adopted produced a significant reduction in algal biomass development in the lagoon; the macroalgal harvesting activities produced a sediment disturbance with following oxidize conditions, which make P unavailable in the lagoon water, excepting close the PAS.     

High-pressure thermo-elastic properties of beryl (Al<Subscript>4</Subscript>Be<Subscript>6</Subscript>Si<Subscript>12</Subscript>O<Subscript>36</Subscript>) from ab initio calculations,and observations about the source of thermal expansion

Ab initio calculations of thermo-elastic properties of beryl (Al₄Be₆Si₁₂O₃₆) have been carried out at the hybrid HF/DFT level by using the B3LYP and WC1LYP Hamiltonians. Static geometries and vibrational frequencies were calculated at different values of the unit cell volume to get static pressure and mode-γ Grüneisen’s parameters. Zero point and thermal pressures were calculated by following a standard statistical-thermodynamics approach, within the limit of the quasi-harmonic approximation, and added to the static pressure at each volume, to get the total pressure (P) as a function of both temperature (T) and cell volume (V). The resulting P(V, T) curves were fitted by appropriate EoS’, to get bulk modulus (K ₀) and its derivative (K′), at different temperatures. The calculation successfully reproduced the available experimental data concerning compressibility at room temperature (the WC1LYP Hamiltonian provided K ₀ and K′ values of 180.2 Gpa and 4.0, respectively) and the low values observed for the thermal expansion coefficient. A zone-centre soft mode \( P6/mcc \to P\bar{1} \) phase transition was predicted to occur at a pressure of about 14 GPa; the reduction of the frequency of the soft vibrational mode, as the pressure is increased, and the similar behaviour of the majority of the low-frequency modes, provided an explanation of the thermal behaviour of the crystal, which is consistent with the RUM model (Rigid Unit Model; Dove et al. in Miner Mag 59:629–639, 1995), where the negative contribution to thermal expansion is ascribed to a geometric effect connected to the tilting of rigid polyhedra in framework silicates.     

Regional models of flow-duration curves of perennial and intermittent streams and their use for calibrating the parameters of a rainfall–runoff model

Abstract

One of the main challenges faced by hydrologists and water engineers is the estimation of variables needed for water resources planning and management in ungauged river basins. To this end, techniques for transposing information, such as hydrological regional analyses, are widely employed. A method is presented for regionalizing flow-duration curves (FDCs) in perennial, intermittent and ephemeral rivers, based on the extended Burr XII probability distribution. This distribution shows great flexibility to fit data, with accurate reproduction of flow extremes. The performance analysis showed that, in general, the regional models are able to synthesize FDCs in ungauged basins, with a few possible drawbacks in the application of the method to intermittent and ephemeral rivers. In addition to the regional models, we summarize the experience of using synthetic FDCs for the indirect calibration of the Rio Grande rainfall–runoff model parameters in ungauged basins.

Editor D. Koutsoyiannis

Citation Costa, V., Fernandes, W., and Naghettini, M., 2013. Regional models of flow-duration curves of perennial and intermittent streams and their use for calibrating the parameters of a rainfall–runoff model. Hydrological Sciences Journal, 59 (2), 262–277.     

Surface moisture area during rainfall–run‐off events to understand the hydrological dynamics of a basin in a plain region

The understanding of the hydrology of plain basins may be improved by the combined analysis of rainfall–run‐off records and remote sensed surface moisture data. Our work evaluates the surface moisture area (SMA) produced during rainfall–run‐off events in a plain watershed of the Argentine Pampas Region, and studies which hydrological variables are related to the generated SMA. The study area is located in the upper and middle basins of the Del Azul stream, characterized by the presence of small gently hilly areas surrounded by flat landscapes. Data from 9 rainfall–run‐off events were analysed. MODIS surface reflectance data were processed to calculate SMA subsequent to the peak discharge (post‐SMA), and previous to the rainfall events (prev‐SMA), to consider the antecedent wetness. Rainfall–run‐off data included total precipitation depth (P), maximum intensity of rainfall over 6 hr (I6max), surface run‐off registered between the beginning of the event and the day previous to the analysed MODIS scene (R), peak flow (Qp), and flood intensity (IF). In contrast with other works, post‐SMA showed a negative relationship with the R. Three groups of cases were identified: (a) Events of low I6max, high prev‐SMA, and low R were associated with slow and weakly channelized flow over plain areas, leading to saturated overland flow (SOF), with large SMA; (b) events of high I6max, low prev‐SMA, and medium to high R were rapidly transported along the gentle slopes of the basin, related to Hortonian overland flow (HOF) and low post‐SMA; and (c) events of medium to high I6max and prev‐SMA with medium R were related to heterogeneous input‐antecedent‐run‐off conditions combined: Local spatial conditions may have produced HOF or SOF, leading to an averaged response with medium SMA. The interactions between the geomorphology of the basin, the characteristics of the events, and the antecedent conditions may explain the obtained results. This analysis is relevant for the general knowledge of the hydrology of large plains, whose functioning studies are still in their early stages.     

PCDD/Fs in sediments of Central Vietnam coastal lagoons: in search of TCDD

Samples from nine Central Vietnam coastal lagoons, together with three soils and sediments collected in two freshwater reservoirs of the Thua Thien-Hué province, were analysed for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs). Total concentrations are low, from 192 to 2912 pg g⁻¹ and depth profiles in Tam Giang-Cau Hai (TG-CH) sediment cores show only minor changes over time in PCDD/F input and composition. Octachloro dibenzo-p-dioxin (OCDD) is the prevailing congener (approximately 90%), indicating combustion as the main PCDD/F source to these coastal systems, whereas natural formation might be partly responsible for the presence at depth. 2,3,7,8-Tetrachloro dibenzo-p-dioxin (TCDD), largely sprayed together with Agent Orange over the study areas during the war (1961–1971), is absent or very low. This result supports the hypothesis of strong degradation soon after spraying. Multivariate statistical analyses account for the presence of local, short-range sources as observed in the northern part of the TG-CH lagoon.     

Probability hazard map for future vent opening at the Campi Flegrei caldera,Italy

The Campi Flegrei caldera is a restless structure affected by general subsidence and ongoing resurgence of its central part. The persistent activity of the system and the explosive character of the volcanism lead to a very high volcanic hazard that, combined with intense urbanization, corresponds to a very high volcanic risk. One of the largest sources of uncertainty in volcanic hazard/risk assessment for Campi Flegrei is the spatial location of the future volcanic activity. This paper presents and discusses a long-term probability hazard map for vent opening in case of renewal of volcanism at the Campi Flegrei caldera, which shows the spatial conditional probability for the next vent opening, given that an eruption occurs. The map has been constructed by building a Bayesian inference scheme merging prior information and past data. The method allows both aleatory and epistemic uncertainties to be evaluated. The probability map of vent opening shows that two areas of relatively high probability are present within the active portion of the caldera, with a probability approximately doubled with respect to the rest of the caldera. The map has an immediate use in evaluating the areas of the caldera prone to the highest volcanic hazard. Furthermore, it represents an important ingredient in addressing the more general problem of quantitative volcanic hazards assessment at the Campi Flegrei caldera.     

Monitoring Etna volcanic plumes using a scanning LiDAR

In this paper, we use data obtained from LiDAR measurements during an ash emission event on 15 November 2010 at Mt. Etna, in Italy, in order to evaluate the spatial distribution of volcanic ash in the atmosphere. A scanning LiDAR system, located at 7?km distance from the summit craters, was directed toward the volcanic vents and moved in azimuth and elevation to analyse different volcanic plume sections. During the measurements, ash emission from the North East Crater and high degassing from the Bocca Nuova Crater were clearly visible. From our analysis we were able to: (1) evaluate the region affected by the volcanic plume presence; (2) distinguish volcanic plumes containing spherical aerosols from those having non-spherical ones; and (3) estimate the frequency of volcanic ash emissions. Moreover, the spatial distribution of ash mass concentration was evaluated with an uncertainty of about 50?%. We found that, even during ash emission episodes characterised by low intensity like the 15 November 2010 event, the region in proximity of the summit craters should be avoided by air traffic operations, the ash concentration being greater than 4?×?10^?3?g/m³. The use of a scanning permanent LiDAR station may usefully monitor the volcanic activity and help to drastically reduce the risks to aviation operations during the frequent Etna eruptions.     

Horizontal cladding panels: in-plane seismic performance in precast concrete buildings

The paper investigates the in-plane performance of horizontal precast reinforced concrete cladding panels, typically adopted in one-storey precast industrial and commercial buildings. Starting from in-field observations of cladding panels failures in recent earthquakes, the seismic performance of typical connections is evaluated by means of experimental tests on full-scale panels under quasi-static cyclic loading. The failure mechanisms highlight the vulnerability of such connections to relative displacements and, therefore, the need to accurately evaluate the connections displacement demand and capacity. An analytical model is developed to describe the force–displacement relationship of the considered connections and compared to the experimental results. In order to determine the seismic vulnerability of such connections and provide design recommendations, linear and nonlinear analyses are conducted taking as reference a precast concrete structure resembling an industrial precast building. The results of the analyses show the importance of a correct estimation of the column’s lateral stiffness in the design process and how an improper erection procedure leads to a premature failure of such connections.     

Adaptation of diet in a changed environment: Increased consumption of lobster krill Munida gregaria (Fabricius, 1793) by Argentine hake

A well‐replicated decadal‐term (2005–2014) stomach content data set was analysed in order to infer inter‐annual fluctuations in the diet of the Argentine hake, Merluccius hubbsi, an opportunistic predator in the San Jorge Gulf (SJG) ecosystem in the Southwest Atlantic. Ten research cruises were carried out each year during January from 2005 to 2014. A total of 18,461 specimens of Me. hubbsi was analysed, of which 6,777 (36.71%) contained food in their stomachs. The diet of Me. hubbsi changed markedly from 2011 onwards, with much greater consumption of the lobster krill Munida gregaria compared to the years before 2011. The frequency of occurrence (%F) of Mu. gregaria in the stomach contents of Argentine hake increased from the year 2009 onwards, most noticeably since 2011, and mostly over the southern region of the SJG. The main predators of Mu. gregaria in the SJG are two species of teleost fish (pink cusk eel, Genypterus blacodes, Argentine seabass, Acanthistius brasilianus) and three Rajidae skates (Zearaja chilensis, Psammobatis spp. and Sympterygia bonapartii), which exhibited decreased catches in the years analysed. The increased consumption of Mu. gregaria by Me. hubbsi, coupled with decreased trends in abundance of the main predators of the lobster krill during the last decade, indicate that top‐down trophic dynamic control occurs in the SJG ecosystem.