The composition of M-type asteroids: Synthesis of spectroscopic and radar observations

We have conducted a radar-driven observational campaign of 22 main-belt asteroids (MBAs) focused on Bus–DeMeo Xc- and Xk-type objects (Tholen X and M class asteroids) using the Arecibo radar and NASA Infrared Telescope Facilities (IRTF). Sixteen of our targets were near-simultaneously observed with radar and those observations are described in a companion paper (Shepard, M.K., and 19 colleagues [2010]. Icarus, in press). We find that most of the highest metal-content asteroids, as suggested by radar, tend to exhibit silicate absorption features at both 0.9 and 1.9 μm, and the lowest metal-content asteroids tend to exhibit either no bands or only the 0.9 μm band. Eleven of the asteroids were observed at several rotational longitudes in the near-infrared and significant variations in continuum slope were found for nine in the spectral regions 1.1–1.45 μm and 1.6–2.3 μm. We utilized visible wavelength data (Bus, S.J., Binzel, R.P. [2002b]. Icarus 158, 146–177; Fornasier, S., Clark, B.E., Dotto, E., Migliorini, A., Ockert-Bell, M., Barucci, M.A. [2010]. Icarus 210, 655–673.) for a more complete compositional analysis of our targets. Compositional evidence is derived from our target asteroid spectra using two different methods: (1) a χ² search for spectral matches in the RELAB database, and (2) parametric comparisons with meteorites. This paper synthesizes the results of the RELAB search and the parametric comparisons with compositional suggestions based on radar observations. We find that for six of the seven asteroids with the highest iron abundances, our spectral results are consistent with the radar evidence (16 Psyche, 216 Kleopatra, 347 Pariana, 758 Mancunia, 779 Nina, and 785 Zwetana). Three of the seven asteroids with the lowest metal abundances, our spectral results are consistent with the radar evidence (21 Lutetia, 135 Hertha, 497 Iva). The remaining seven asteroids (22 Kalliope, 97 Klotho, 110 Lydia, 129 Antigone, 224 Oceana, 678 Fredegundis, and 771 Libera) have ambiguous compositional interpretations when comparing the spectral analogs to the radar analogs. The number of objects with ambiguous results from this multi-wavelength survey using visible, near-infrared, and radar wavelengths indicates that perhaps a third diagnostic wavelength region (such as the mid-infrared around 2–4 μm, the mid-infrared around 10–15 μm, and/or the ultraviolet around 0.2–0.4 μm) should be explored to resolve the discrepancies.     

Iron Isotope Variations in Coastal Seawater Determined by Multicollector ICP-MS

In this paper, we applied a reliable technique for measuring Fe isotope variations in coastal seawater at nanomolar levels. Iron was directly pre-concentrated from acidified seawater samples onto a nitrilotriacetic acid chelating resin and further purified using anion-exchange resin. Sample recovery, determined using a standard addition method, was essentially quantitative. Iron was then determined using a high-resolution multicollector ICP-MS (Neptune) coupled to an ApexQ desolvation introduction system. The external precision for δ⁵⁶Fe values was 0.11‰ (2s) when using total a Fe quantity between 25 and 100 ng. We initially applied this technique to measure the Fe isotope composition of dissolved Fe from several coastal environments in the north-eastern United States and we observed a range of δ⁵⁶Fe values between -0.9‰ and 0.1‰ relative to the IRMM-14 reference material. Iron isotope compositions of several reference water materials for inter-laboratory comparisons were also reported. Our results suggest that iron in coastal seawater, derived from benthic diagenesis and/or groundwater has negative Fe isotopic signatures that are distinct from other iron sources such as atmospheric deposition and rivers.     

Development of cloud detection methods using CFH,GTS1, and RS80 radiosondes

The accuracies of three instruments in measuring atmospheric column humidity were assessed during an upper troposphere and lower stratosphere observation campaign conducted from 7 to 13 August 2009 in ...     

Additions to the freshwater ostracod fauna of New Zealand

Several species of ostracods, new to New Zealand, are described, including Darwinula sphagna n.sp. and Cypridopsis obstinata n.sp. Limnocythere duffi Hornibrook, 1955 is placed in the genus Gomphocythere Sars, 1924, and a colour variation of Newnhamia fenestrata King, 1855 is discussed.     

Asteroid (101955) 1999 RQ36: Spectroscopy from 0.4 to 2.4 μm and meteorite analogs

We present reflectance spectra from 0.4 to 2.4 μm of Asteroid (101955) 1999 RQ36, the target of the OSIRIS-REx spacecraft mission. The visible spectral data were obtained at the McDonald Observatory 2.1-m telescope with the ES2 spectrograph. The infrared spectral data were obtained at the NASA Infrared Telescope Facility using the SpeX instrument. The average visible spectrum is combined with the average near-infrared wavelength spectrum to form a composite spectrum. We use three methods to constrain the compositional information in the composite spectrum of Asteroid (101955) 1999 RQ36 (hereafter RQ36). First, we perform a least-squares search for meteorite spectral analogs using 15,000 spectra from the RELAB database. Three most likely meteorite analogs are proposed based on the least-squares search. Next, six spectral parameters are measured for RQ36 and their values are compared with the ranges in parameter values of the carbonaceous chondrite meteorite classes. A most likely meteorite analog group is proposed based on the depth of overlap in parameter values. The results of the least-squares search and the parametric comparisons point to CIs and/or CMs as the most likely meteorite analogs for RQ36, and COs and CHs as the least likely. RQ36 has a spectrally “blue” continuum slope that is also observed in carbonaceous chondrites containing magnetite. We speculate that RQ36 is composed of a “CM1”-like material. Finally, we compare RQ36 to other B-type asteroids measured by Clark et al. (Clark, B.E. et al. [2010]. J. Geophys. Res. 115, E06005). The results of this comparison are inconclusive. RQ36 is comparable to Themis spectral properties in terms of its albedo, visible spectrum, and near-infrared spectrum from 1.1 to 1.45 μm. However, RQ36 is more similar to Pallas in terms of its near-infrared spectrum from 1.6 to 2.3 μm. Thus it is possible that B-type asteroids form a spectral continuum and that RQ36 is a transitional object, spectrally intermediate between the two end-members. This is particularly interesting because Asteroid 24 Themis was recently discovered to have H₂O ice on the surface (Rivkin, A., Emery, J. [2010]. Nature 464, 1322–1323; Campins, H. et al. [2010a]. Nature 464, 1320–1321).     

Potential Effects of Climate Change on Two Neotropical Amphibian Assemblages

Although anuran amphibians are diverse and conspicuous in many vertebrate communities, worldwide population declines have been observed. Climatic change is a global factor that has been implicated in some of these declines. In this paper, we speculate on how Neotropical anurans might respond to changes in climate predicted by Hulme and Viner (1998). We focus on two distinct groups of Neotropical anurans: frogs that live and oviposit in leaf litter and frogs that congregate at ponds to breed. Increased temperature, increased length of dry season, decreased soil moisture, and increased inter-annual rainfall variability will affect Neotropical frogs strongly. We expect that these changes will directly affect frogs by changing reproductive success and breeding periodicity, and indirectly by altering the invertebrate prey base. The individual effects will likely translate into changes at the population and community levels. We also speculate on how climatic change will affect Neotropical amphibians that are restricted ecologically and/or geographically. We suggest directions for future research that will increase our ability to predict how amphibians in the New World tropics will respond to climatic change.     

Tropical westerlies over Pangaean sand seas

Cross‐equatorial, westerly winds are key features of tropical circulation in monsoonal regions. Although prominent in numerical climate models of Pangaea (the supercontinent straddling earth's equator, Late Palaeozoic to Early Mesozoic), such flow has not been confirmed previously by migration directions of ancient dunes. Wind‐blown sandstones that span 100 million years of earth history are widely exposed in south‐western USA. If recent palaeomagnetic data from the Colorado Plateau are used to correct Mesozoic palaeogeographic maps, the Plateau is placed about 10° further south than previously assumed, and the prevailing north‐westerly surface winds recorded by dune‐deposited sandstones are explicable as cross‐equatorial westerlies – the hallmark of modern monsoon circulation. Permian to Early Jurassic dunes were driven by north‐westerlies produced by a steep pressure gradient spanning the supercontinent during December–January–February. Although winds are light in most modern, near‐equatorial settings, the East African Jet accounts for more than half the cross‐equatorial flow in June–July–August. The thicknesses of annual depositional cycles within the Navajo Sandstone indicate that the near‐equatorial, north‐westerly winds that drove these particular dunes were stronger than the modern East African Jet. The Early Jurassic dunes that deposited the thick cycles were positioned west of the dominant (southern hemisphere) thermal low and against highlands to the west – a setting very similar to the East African Jet. The mountains along the western coast of Pangaea not only enhanced wind strength, but also cast a rain shadow that allowed active dunes to extend very close to the palaeoequator.     

Sampling Plan Optimization: A Data Review and Sampling Frequency Evaluation Process

Lawrence Livermore National Laboratory (LLNL) uses a cost-effective sampling (CES) methodology to evaluate and review ground water contaminant data and optimize the site's ground water monitoring plan. The CES methodology is part of LLNL's regulatory approved compliance monitoring plan (Lamarre et al. 1996). It allows LLNL to adjust the ground water sampling plan every quarter in response to changing conditions at the site. Since the use of the CES methodology has been approved by the appropriate regulatory agencies, such adjustments do not need additional regulatory approval. This permits LLNL to respond more quickly to changing conditions. The CES methodology bases the sampling frequency for each location on trend, variability, and magnitude statistics describing the contaminants at that location, and on the input of the technical staff (hydrologists, chemists, statisticians, and project leaders). After initial setup is complete, each application of CES takes only a few days for as many as 400 wells. Effective use of the CES methodology requires sufficient data, an understanding of contaminant transport at the site, and an adequate number of monitoring wells downgradient of the contamination. The initial implementation of CES at LLNL in 1992 produced a 40% reduction in the required number of annual routine ground water samples at LLNL. This has saved LLNL $390,000 annually in sampling, analysis, and data management costs.