Hydrogeochemical and multi-tracer investigations of arsenic-affected aquifers in semi-arid West Africa

The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.     

Statistical distribution of gravitational-lensing excursion angles: winding ways to us from the deep Universe

We investigate statistical distributions of differences in gravitational-lensing deflections between two light rays, the so-called lensing excursion angles. A probability distribution function of the lensing excursion angles, which plays a key role in estimates of lensing effects on angular clustering of objects (such as galaxies, quasi-stellar objects and also the cosmic microwave background temperature map), is known to consist of two components: a Gaussian core and an exponential tail. We use numerical gravitational-lensing experiments in a ΛCDM cosmology for quantifying these two components. We especially focus on the physical processes responsible for generating these two components. We develop a simple empirical model for the exponential tail which allows us to explore its origin. We find that the tail is generated by the coherent lensing scatter by massive haloes with   M > 10¹⁴  h ⁻¹ M_⊙  at   z < 1  and that its exponential shape arises due to the exponential cut-off of the halo mass function at that mass range. On scales larger than 1 arcmin, the tail does not have a practical influence on the lensing effects on the angular clustering. Our model predicts that the coherent scatter may have non-negligible effects on angular clustering at subarcminute scales.     

Relations between denudation,glaciation, and sediment deposition: implications from the Plio‐Pleistocene Central Alps

Despite abundant data on the early evolution of the Central Alps, the latest stage exhumation history, potentially related to relief formation, is still poorly constrained. We aim for a better understanding of the relation between glaciation, erosion and sediment deposition. Addressing both topics, we analysed late Pliocene to recent deposits from the Upper Rhine Graben and two modern river sands by apatite fission‐track and (U‐Th‐Sm)/He thermochronology. From the observed age patterns we extracted the sediment provenance and paleo‐erosion history of the Alpine‐derived detritus. Due to their pollen and fossil record, the Rhine Graben deposits also provide information on climatic evolution, so that the erosion history can be related to glacial evolution during the Plio‐Pleistocene. Our data show that Rhine Graben deposits were derived from Variscan basement, Hegau volcanics, Swiss Molasse Basin, and the Central Alps. The relations between glaciation, Alpine erosion, and thermochronological age signals in sedimentary rocks are more complex than assumed. The first Alpine glaciation during the early Pleistocene did not disturb the long‐term exhumational equilibrium of the Alps. Recent findings indicate that main Alpine glaciation occurred at ca. 1 Ma. If true, then main Alpine glaciation was coeval with an apparent decrease of hinterland erosion rates, contrary to the expected trend. We suggest that glaciers effectively sealed the landscape, thus reducing the surface exposed to erosion and shifting the area of main erosion north toward the Molasse basin, causing sediment recycling. At around 0.4 Ma, erosion rates increased again, which seems to be a delayed response to main glaciation. The present‐day erosion regime seems to be dominated by mass‐wasting processes. Generally, glacial erosion rates did not exceed the pre‐glacial long‐term erosion rates of the Central Alps.     

Circular moraine features on the Varanger Peninsula, northern Norway, and their possible relation to polythermal ice sheet coverage

This paper introduces a new hypothesis about the formation of circular moraine features (CMFs) on felsenmeer-covered plateaux of the Varanger Peninsula, northern Norway. CMFs and glacial lineations in the northwestern part of the Varanger Peninsula were mapped from aerial photographs. In two CMF-rich areas, Base œrro-Plateau and Båtsfjordfjellet, the CMFs were investigated during fieldwork. The aim was to investigate possible entrainment, transport and deposition mechanisms of the CMFs in connection to ice sheet properties.The CMFs were deposited in connection with a polythermal ice cover. During glaciations, the ice sheet was cold-based on the boulder field plateaux and warm-based in valleys, especially in ice drainage pathways towards fjords. The CMF material was probably entrained en masse, on the Varanger Peninsula, in transition zones between warm- and cold-based ice. The debris transport took place close to the ice base. During deglaciation, the debris formed dirt cones, slowing down the melting of underlying dead-ice blocks. As material slid down the margins of the cones, the typical CMF shape was formed.     

Deglaciation history and post-glacial mass movements in Balsfjord, northern Norway

The deglaciation history of Balsfjord, northern Norway, and post-glacial mass movement events were investigated. Radiocarbon dates indicate that the Balsfjord glacier retreated from the Tromsø–Lyngen moraines about 10.4 ¹⁴C Ky BP. Between ca. 10.3 ¹⁴C Ky BP and 9.9 ¹⁴C Ky BP, deposition of a distinct end moraine–the Skjevelnes moraine–in the central part of Balsfjord occurred. The transition from glacimarine to open marine sedimentary environment took place before 9.6 ¹⁴C Ky BP. Between ca. 9.5 ¹⁴C Ky BP and 8.4 ¹⁴C Ky BP, at least one local and three regional mass movement events occurred. After this period, no gravity flow activity is preserved in the cores. The high frequency of mass movements in the early post-glacial period is presumed to be due to fast sea level changes and/or tectonic activity induced by rapid isostatic uplift.     

Late Miocene – Recent exhumation of the central Himalaya and recycling in the foreland basin assessed by apatite fission-track thermochronology of Siwalik sediments, Nepal

Thermochronological analysis of detrital sediments derived from the erosion of mountain belts and contained in the sedimentary basins surrounding them allows reconstructing the long-term exhumation history of the sediment source areas. The effective closure temperature of the thermochronological system analysed determines the spatial and temporal resolution of the analysis through the duration of the lag time between closure of the system during exhumation and its deposition in the sedimentary basin. Here, we report apatite fission-track (AFT) data from 31 detrital samples collected from Miocene to Pliocene stratigraphic sections of the Siwalik Group in western and central Nepal, as well as three samples from modern river sediments from the same area, that complement detrital zircon fission-track (ZFT) and U–Pb data from the same samples presented in a companion paper. Samples from the upper part of the stratigraphic sections are unreset and retain a signal of source-area exhumation; they show spatial variations in source-area exhumation rates that are not picked up by the higher-temperature systems. More deeply buried samples have been partially reset within the Siwalik basin and provide constraints on the thermal and kinematic history of the fold-and-thrust belt itself. The results suggest that peak source-area exhumation rates have been constant at ∼1.8 km Myr⁻¹ over the last ∼7 Ma in central Nepal, whereas they ranged between 1 and ∼1.5 km Myr⁻¹ in western Nepal over the same time interval; these spatial variations may be explained by either a tectonic or climatic control on exhumation rates, or possibly a combination of the two. Increasing lag times within the uppermost part of the sections suggest an increasing component of apatites that have been recycled within the Siwalik belt and are corroborated by AFT ages of modern river sediment downstream as well as the record of the distal Bengal Fan. The most deeply buried and most strongly annealed samples record onset of exhumation of the frontal Siwaliks along the Himalayan frontal thrust at ∼2 Ma and continuous shortening at rates comparable with the present-day shortening rates from at least 0.3 Ma onward.     

The Maximum Ice Age Glaciation between the Karakorum Main Ridge （K2） and the Tarim Basin and its Influence on Global Energy Balance

A modern research approach and working techniques in hitherto unexamined areas, produced the following results: 1). The tongues of decakilometre long Karakorum glaciers belong to temperate ice-streams with an annual meltwateroutput. The short Aghil glaciers on the contrary are continental, arid and cold. 2). The present-day oscillations of the Karakorum glaciers are related to their own mass, and are contrary to and independent of the actual climate. Only the short glaciers, with steep tongue fronts, show a present-day positive balance. 3). ^14C- dated Late Glacial moraines indicate a 400-800 m thick valley glacier at the former confluence point of the K2-, Sarpo Laggo- and Skamri glaciers. 4). From the evidence of transfluence passes with roches moutonn6es, striae and the limits of glacial polishing, as well as moraines and erratics, a High Glacial at least 12oo m thick ice-stream network between the Karakorums and the Kuen Lun north slopes was reconstructed. The Shaksgam and Yarkand valleys were occupied by glaciers coming from west Tibet. The lowest-lying moraines are to be found in the foreland down to 2000 m, indicating a depression of the High Glacial (LGM) snowline (ELA) by 13oo m.5). The approximately 10,000 measurements of the radiation balance at up to heights of 5500 m on K2 indicate that with incoming energy near the solar constant the reflection from snow- covered ice is up to 70% greater than from rock and rock waste surfaces.6).These results confirm for the very dry western margins of Tibet an almost complete ice sheet cover in an area with subtropical energy balance, conforming with the Ice Age hypothesis of the author which is based upon the presence of a 2.4 million km^2 Tibetan inland ice sheet. This inland ice developed for the first time when Tibet was uplifted over the snowline during the early Pleistocene. As the measured subtropical radiation balance shows, it was able to trigger the Quaternary Ice Ages.     

Altitudinal levels and altitudinal limits in high mountains

In lowlands climate-specific processes due to weathering and erosion are dominant, whilst the geomorphology of mountains is dependent on the geologic-tectonic structure, i.e., the energy of erosion that increases according to the vertical. The expression "extremely high mountains" has been established as the extreme of a continuous mountain classification. It has to be understood in terms of geomorphology, glaciology and vegetation. Correspondence of the planetary and hypsometric change of forms is of great value as synthetic explanation. It is confirmed with regard to vegetation, periglacial geomorphology and glaciology. Due to the world-wide reconstruction of the snowline its paleoclimatic importance increases, too. Apart from lower limits the periglacial and glacial altitudinal levels also show zones of optimum development and climatic upper limits in the highest mountains of the earth. According to the proportion of the altitudinal levels a classification as to arid, temperate and humid high mountains has been carried out.     

Reconstruction of the Ice Age glaciation in the southern slopes of Mt. Everest, Cho Oyu, Lhotse and Makalu (Himalaya) (Part 1)

In the Khumbu-and Khumbakarna Himalaya an ice stream network and valley glacier system has been reconstructed for the last glacial period (Würmian, Last Ice Age, Isotope stage 4–2, 60–18 Ka BP, Stage 0) with glaciogeomorphological and sedimentological methods. It was a part of the glacier system of the Himalaya and has communicated across transfluence passes with the neighbouring ice stream networks toward the W and E. The ice stream network has also received inflow from the N, from a Tibetan ice stream network, by the Kyetrak-Nangpa-Bote Koshi Drangka (Valley) in the W, by the W-Rongbuk glacier valley into the Ngozumpa Drangka (Valley), by the Central Rongbuk glacier valley into the Khumbu Drangka (Valley) and by the antecedent Arun Nadi transverse-valley in the E of the investigation area. The ice thickness of the valley glacier sections, the surface of which was situated above the snow-line, amounted to 1000–1450 m. The most extended parent valley glaciers have been measured approx. 70 km in length (Dudh Koshi glacier), 67 km (Barun-Arun glacier) and 80 km (Arun glacier). The tongue end of the Arun glacier has flowed down to c. 500 m and that of the Dudh Koshi glacier to c. 900 m asl. At heights of the catchment areas of 8481 (or 8475) m (Makalu), i.e., 8848 (or 8872) m (Mt. Everest, Sagarmatha, Chogolungma) this is a vertical distance of the Ice Age glaciation of c. 8000 m. The steep faces towering up to 2000 m above the névé areas of the 6000–7000 m-high surfaces of the ice stream network were located 2000–5000 m above the ELA. Accordingly, their temperatures were so low, that their rock surfaces were free of flank ice and ice balconies. From the maximum past glacier extension up to the current glacier margins, 13 (altogether 14) glacier stages have been differentiated and in part 14C-dated. They were four glacier stages of the late glacial period, three of the neoglacial period and six of the historical period. By means of 130 medium-sized valley glaciers the corresponding ELA-depressions have been calculated in comparison with the current courses of the orographic snow-line. The number of the glacier stages since the maximum glaciation approx. agrees with that e.g. in the Alps and the Rocky Mountains since the last glacial period. Accordingly, it is interpreted as an indication of the Würmian age (last glacial period) of the lowest ice margin positions. The current climatic, average glacier snow-line in the research area runs about 5500 m asl. The snow-line depression (ELA) of the last glacial period (Würm) calculated by four methods has run about 3870 m asl, so that an ELA-depression of c. 1630 m has been determined. This corresponds to a lowering of the annual temperature by c. 8, i.e., 10°C according to the specific humid conditions at that time.