Distribution of trace elements in filtered and non filtered aqueous fractions: Insights from rivers and streams of Sardinia (Italy)

The distribution of several trace elements in different aqueous fractions has been studied in running waters from Sardinia (Italy). Trace elements and major components were determined in water samples collected at high- and low-discharge from rivers (90 samples) and streams (70 samples). At selected sites, total (non filtered samples) and dissolved (0.4 μm and 0.015 μm pore-size filtered samples) amounts of trace elements were determined, and the composition of the solid matter retained on the filters was investigated for estimating the eventual interrelationship. The elements B, Li, Rb, Sr, Ba, As, Sb, Mo, Tl and U in the studied waters showed small differences between total and dissolved amounts; dissolved concentrations were higher under low flow conditions, when the contribution of rainwater to the rivers was minimum; their concentrations were often correlated with total dissolved solids (TDS), and appeared to be related to the intensity of water-rock interaction processes. The elements Al, Fe, Mn, Pb, Zn, Cd, Cu, Co, Ni, Cs, Y, REE and Th were not related to TDS and/or major ions; they showed higher concentrations under high flow conditions; marked differences occurred between total and dissolved amounts; much lower concentrations were generally observed in the water filtered through 0.015 μm than in the water filtered through 0.4 μm, especially when sampling was carried out after heavy rain events that enhanced the load of solid matter in the water. These observations indicate an aqueous transport via sorption processes on very fine particles, such as Fe-oxide/hydroxide and clay mineral particles, which have been inferred by SEM-EDX analyses of the matter retained on the filters.     

Phenomenology of the Lense-Thirring effect in the solar system

Recent years have seen increasing efforts to directly measure some aspects of the general relativistic gravitomagnetic interaction in several astronomical scenarios in the solar system. After briefly overviewing the concept of gravitomagnetism from a theoretical point of view, we review the performed or proposed attempts to detect the Lense-Thirring effect affecting the orbital motions of natural and artificial bodies in the gravitational fields of the Sun, Earth, Mars and Jupiter. In particular, we will focus on the evaluation of the impact of several sources of systematic uncertainties of dynamical origin to realistically elucidate the present and future perspectives in directly measuring such an elusive relativistic effect.     

Effects of limestone petrography and calcite microstructure on OPC clinker raw meals burnability

Mineralogy and Petrology - Limestone represents the main raw material for ordinary Portland cement clinker production. In this study eight natural limestones from different geological environments...     

Models of interacting pairs of thin,quasi-geostrophic vortices: steady-state solutions and nonlinear stability

We study pairwise interactions of elliptical quasi-geostrophic (QG) vortices as the limiting case of vanishingly thin uniform potential vorticity ellipsoids. In this limit, the product of the vertical extent of the ellipsoid and the potential vorticity within it is held fixed to a finite non-zero constant. Such elliptical “lenses” inherit the property that, in isolation, they steadily rotate without changing shape. Here, we use this property to extend both standard moment models and Hamiltonian ellipsoidal models to approximate the dynamical interaction of such elliptical lenses. By neglecting non-elliptical deformations, the simplified models reduce the dynamics to just four degrees of freedom per vortex. For simplicity, we focus on pairwise interactions between identical elliptical vortices initially separated in both the horizontal and vertical directions. The dynamics of the simplified models are compared with the full QG dynamics of the system, and show good agreement as expected for sufficiently distant lenses. The results reveal the existence of families of steadily rotating equilibria in the initial horizontal and vertical separation parameter space. For sufficiently large vertical separations, equilibria with varying shape exist for all horizontal separations. Below a critical vertical separation (stretched by the constant ratio of buoyancy to Coriolis frequencies N / f), comparable to the mean radius of either vortex, a gap opens in horizontal separation where no equilibria are possible. Solutions near the edge of this gap are unstable. In the full QG system, equilibria at the edge of the gap exhibit corners (infinite curvature) along their boundaries. Comparisons of the model results with the full nonlinear QG evolution show that the early stages of the instability are captured by the Hamiltonian elliptical model but not by the moment model that inaccurately estimates shorter-range interactions.     

The Burren: a glacial,karstic and biokarstic expression of a limestone plateau in western Ireland

The term glaciokarst describes a landscape where both glacial and karstic processes have contributed to geomorphological evolution and has been applied to a range of environments from the high arctic to the alpine Mediterranean. Nevertheless, glaciokarstic environments globally often exhibit significant variation in geomorphological processes and landforms due to these geographical differences. The Burren, County Clare, Republic of Ireland, is often quoted as a quintessential glaciokarstic landscape. However, the Burren and other similar environments would appear to lean towards one end of the glaciokarst spectrum, where solutional and biological processes have been dominant throughout the Holocene, in contrast to ice‐dominated glaciokarsts where karstic and biokarstic processes are temperature‐limited and cryospheric processes remain the principal geomorphological agents. Holocene landscape evolution and the development of a range of meso‐, micro‐ and nano‐scale karren features on limestone surfaces appears to be largely biokarstic in origin. Karstification of many glacially scoured limestone pavements would have begun under acidic soil cover, with biological soil processes contributing to smooth, rounded cryptokarstic surface forms. Holocene soil erosion is attributed to anthropogenic activity, climatic fluctuations and the evolution of the karstic groundwater system leading to vertical soil loss through widening grikes. Exposed limestone pavements subject to subaerial conditions often exhibit extensive lichen colonization which has been shown to influence the overall rate of karstification and contribute to the development of micro‐ and meso‐scale bioweathering features. Where cryptokarstic features have been exhumed from beneath soil cover, their evolution under subaerial conditions leads to intermediate, polygenetic karren features. In light of our current understanding of the Burren landscape, it is proposed that the term glaciobiokarstic may be a better expression to encompass the biological processes that have played a fundamental role in the evolution of the Burren and similar landscapes, without neglecting the contribution of glacial and inorganic karstic processes. Copyright © 2016 John Wiley & Sons, Ltd.     

A low temperature X-ray single-crystal diffraction and polarised infra-red study of epidote

The effects of low-temperature on the crystal structure of a natural epidote [Ca_1.925Fe_0.745Al_2.265Ti_0.004Si_3.037O₁₂(OH), a = 8.8924(7), b = 5.6214(3), c = 10.1547(6)? and β = 115.396(8)° at room conditions, Sp. Gr. P2₁ /m] have been investigated with a series of structure refinements down to 100 K on the basis of X-ray single-crystal diffraction data. The reflection conditions confirm that the space group is maintained within the T-range investigated. Structural refinements at all temperatures show the presence of Fe³⁺ at the octahedral M(3) site only [%Fe(M3) = 70.6(4)% at 295 K]. Only one independent proton site was located and two possible H-bonds occur, with O(10) as donor and O(4) and O(2) as acceptors. The H-bonding scheme is maintained down to 100 K and is supported by single crystal room-T polarised FTIR data. FTIR Spectra over the region 4,000–2,500 cm⁻¹ are dominated by the presence of a strongly pleochroic absorption feature which can be assigned to protonation of O(10)–O(4). Previously unobserved splitting of this absorption features is consistent with a NNN influence due to the presence of Al and Fe³⁺ on the nearby M(3) site. An additional relatively minor absorption feature in FTIR spectra can be tentatively assigned to protonation of O(10)–O(2). Low-T does not affect significantly the tetrahedral and octahedral bond distances and angles, even when distances are corrected for “rigid body motions”. A more significant effect is observed for the bond distances of the distorted Ca(1)- and Ca(2)-polyhedra, especially when corrected for “non-correlated motion”. The main low-T effect is observed on the vibrational regime of the atomic sites, and in particular for the two Ca-sites. A significant reduction of the magnitude of the thermal displacement ellipsoids, with a variation of U _eq (defined as one-third of the trace of the orthogonalised U _ij tensor) by ~40% is observed for the Ca-sites between 295 and 100 K. Within the same T-range, the U _eq of the octahedral and oxygen sites decrease similarly by ~35%, whereas those of the tetrahedral cations by ~22%.     

Reconstruction of annual winter rainfall since A.D.1579 in central-eastern Spain based on calcite laminated sediment from Lake La Cruz

We present the first winter (December to March) rainfall reconstruction based in a novel proxy, the thickness of annual calcite laminations preserved in Lake La Cruz (central–eastern Spain). A previous calibration analysis between laminae thickness and the instrumental data series (1950 to present) indicated a highly significant correlation with winter rainfall. Therefore this study attempts the winter rainfall reconstruction since the onset of laminations (1579 a.d.) by means of the calibration function previously developed. The verification analysis between inferred annual values and earlier instrumental data (1859–1949) confirms the suitability of this novel proxy and the reliability of the series reconstructed. The reconstructed series show the fluctuating character of winter rainfall in the western Mediterranean area; interdecadal dry periods alternated with wetter periods following, in a board sense, the pattern recorded by documentary sources in other regions of the Iberian Peninsula. At present times regional winter rainfall anomalies are highly correlated with the phase of the North Atlantic Oscillation (NAO). However the time series analysis showed the dominance of nonstationary components at high frequencies of the climate signal over the last four centuries suggesting that the connection between winter rainfall and the NAO has not been stable over time and also other modes of variability, not only NAO, may have conditioned winter rainfall variability.     

Sun–earth relationship inferred by tree growth rings in conifers from Severiano De Almeida,Southern Brazil

This study of Sun–Earth relationships is based on tree growth rings analysis of araucarias (Araucaria angustifolia) collected at Severiano de Almeida (RS) Brazil. A chronology of 359 years was obtained, and the classical method of spectral analysis by iterative regression and wavelet method was applied to find periodicities and trends contained in the tree growth. The analysis of the dendrochronological series indicates representative periods of solar activity of 11 (Schwabe cycle), 22 (Hale cycle), and 80 (Gleissberg cycle) years. The result shows the possible influence of the solar activity on tree growth in the last 350 years. Periods of 2–7 years were also found and could represent a response of the trees to local climatic conditions. Good agreement between the time series of tree growth rings and the 11 year solar cycle was found during the maximum solar activity periods.