Origin of Carboniferous sandstones fringing the northern margin of the Wales‐Brabant Massif: insights from detrital zircon ages

A study of detrital zircon age populations in Namurian–Westphalian (Carboniferous) sandstones in the southern Central Pennine Basin of the UK has revealed considerable complexity in their provenance history. The Pendleian–Marsdenian Morridge Formation, which is known to have been derived from the Wales‐Brabant Massif to the south on the basis of palaeocurrent and petrographic information, is dominated by zircons ultimately derived from the Caledonian belt to the north. These zircons were recycled from sandstones of northern origin that had been previously deposited over the massif during Middle to Late Devonian times. The Morridge Formation also includes Late Neoproterozoic zircons of local Wales‐Brabant Massif origin. The south lobe of the Yeadonian Rough Rock has been previously interpreted as having a complex provenance including sediment of northern origin interbedded with sediment ascribed to a Wales‐Brabant Massif source. However, the zircon spectrum lacks a Late Neoproterozoic component that would have been diagnostic of input from the Wales‐Brabant Massif, and the provenance history of the Rough Rock south lobe therefore remains enigmatic. The Langsettian Ludgbridge Conglomerate is dominated by Late Neoproterozoic zircons of Wales‐Brabant Massif origin, but even in this evidently proximal deposit, the provenance is complex since the main zircon group (ca. 640 Ma) cannot be matched with known local Neoproterozoic basement sources. The data either indicate the presence of hitherto‐unknown magmatic rocks of this age adjacent to the South Staffordshire coalfield or indicate that the zircons were recycled from sediment with a more distal origin. Finally, the Duckmantian Top Hard Rock contains zircons that can be reconciled with a source in the Irish Caledonides, consistent with the palaeocurrent evidence, supplemented by zircons derived from the Wales‐Brabant Massif, possibly including the Monian Composite Terrane of Anglesey. The study reinforces the important message that failure to recognize the presence of recycled zircon could lead to erroneous reconstructions of sediment provenance and transport history. Copyright © 2014 John Wiley & Sons, Ltd.     

Mining candidate causal relationships in movement patterns

In many applications, the environmental context for and drivers of movement patterns are just as important as the patterns themselves. This article adapts standard data mining techniques, combined with a foundational ontology of causation, with the objective of helping domain experts identify candidate causal relationships between movement patterns and their environmental context. In addition to data about movement and its dynamic environmental context, our approach requires as input definitions of the states and events of interest. The technique outputs causal and causal-like relationships of potential interest, along with associated measures of support and confidence. As a validation of our approach, the analysis is applied to real data about fish movement in the Murray River in Australia. The results demonstrate that the technique is capable of identifying statistically significant patterns of movement indicative of causal and causal-like relationships.     

Detecting trends that are nonlinear and asymmetric on diurnal and seasonal time scales

Trends in climate time series are often nonlinear and temporally-asymmetric, i.e. the trend is different for different seasons and/or hours of the day. Here a method is developed that allows the nonlinearity and temporal asymmetry of a trend to be investigated simultaneously. First, nonlinear trend components are extracted from a univariate time series, by adapting a nonparametric dimension-reduction method. Then, the nonlinear trend components are substituted into a regression model in which the periodic mean component and the periodic variation in the amplitude of the nonlinear trend are modeled using harmonic functions of the seasonal and diurnal periods. Third, trend patterns in the positive and negative anomalies are investigated, by extending the nonlinear trend model using indicator variables. Fourth, a non-local inferential test is developed to test the statistical significance of the trend patterns. The nonlinear trend model is applied to a simulated time series, as well as to long-term high-resolution temperature records from five Southern Hemisphere sites: Lucas Heights, Sydney Airport, Cape Grim, Macquarie Island and Law Dome. Our method should be generally useful for identifying the effect of both climate-related factors and observation/site-related factors on seasonal and diurnal trends in meteorological data series.     

GPS-derived orbits for the GOCE satellite

The first ESA (European Space Agency) Earth explorer core mission GOCE (Gravity field and steady-state Ocean Circulation Explorer) was launched on 17 March 2009 into a sun-synchronous dusk–dawn orbit with an exceptionally low initial altitude of about 280 km. The onboard 12-channel dual-frequency GPS (Global Positioning System) receiver delivers 1 Hz data, which provides the basis for precise orbit determination (POD) for such a very low orbiting satellite. As part of the European GOCE Gravity Consortium the Astronomical Institute of the University of Bern and the Department of Earth Observation and Space Systems are responsible for the orbit determination of the GOCE satellite within the GOCE High-level Processing Facility. Both quick-look (rapid) and very precise orbit solutions are produced with typical latencies of 1 day and 2 weeks, respectively. This article summarizes the special characteristics of the GOCE GPS data, presents POD results for about 2 months of data, and shows that both latency and accuracy requirements are met. Satellite Laser Ranging validation shows that an accuracy of 4 and 7 cm is achieved for the reduced-dynamic and kinematic Rapid Science Orbit solutions, respectively. The validation of the reduced-dynamic and kinematic Precise Science Orbit solutions is at a level of about 2 cm.     

Modeling the Transient Response of Saline Intrusion to Rising Sea‐Levels

Sea levels are expected to rise as a result of global temperature increases, one implication of which is the potential exacerbation of sea water intrusion into coastal aquifers. Given that approximately 70% of the world's population resides in coastal regions, it is imperative to understand the interaction between fresh groundwater and sea water intrusion in order to best manage available resources. For this study, controlled investigation has been carried out concerning the temporal variation in sea water intrusion as a result of rising sea levels. A series of fixed inland head two‐dimensional sea water intrusion models were developed with SEAWAT in order to assess the impact of rising sea levels on the transient migration of saline intrusion in coastal aquifers under a range of hydrogeological property conditions. A wide range of responses were observed for typical hydrogeological parameter values. Systems with a high ratio of hydraulic conductivity to recharge and high effective porosity lagged behind the equilibrium sea water toe positions during sea‐level rise, often by many hundreds of meters, and frequently taking several centuries to equilibrate following a cease in sea‐level rise. Systems with a low ratio of hydraulic conductivity to recharge and low effective porosity did not develop such a large degree of disequilibrium and generally stabilized within decades following a cease in sea‐level rise. This study provides qualitative initial estimates for the expected rate of intrusion and predicted degree of disequilibrium generated by sea‐level rise for a range of hydrogeological parameter values.     

A Review of Higher Order Ionospheric Refraction Effects on Dual Frequency GPS

Higher order ionospheric effects are increasingly relevant as precision requirements on GPS data and products increase. The refractive index of the ionosphere is affected by its electron content and the magnetic field of the Earth, so the carrier phase of the GPS L1 and L2 signals is advanced and the modulated code delayed. Due to system design the polarisation is unaffected. Most of the effect is removed by expanding the refractive index as a series and eliminating the first term with a linear combination of the two signals. However, the higher order terms remain. Furthermore, transiting gradients in refractive index at a non-perpendicular angle causes signal bending. In addition to the initial geometric bending term, another term allows for the difference that the curvature makes in electron content along each signal. Varying approximations have been made for practical implementation, mainly to avoid the need for a vertical profile of electron density. The magnetic field may be modelled as a tilted co-centric dipole, or using more realistic models such as the International Geomagnetic Reference Field. The largest effect is from the second term in the expansion of the refractive index. Up to several cm on L2, it particularly affects z-translation, and satellite orbits and clocks in a global network of GPS stations. The third term is at the level of the errors in modelling the second order term, while the bending terms appear to be absorbed by tropospheric parameters. Modelling improvements are possible, and three frequency transmissions will allow new possibilities.     

Thallium isotopes in early diagenetic pyrite - A paleoredox proxy?

This paper presents the first study of Tl isotopes in early diagenetic pyrite. Measurements from two sections deposited during the Toarcian Ocean Anoxic Event (T-OAE, ∼183 Ma) are compared with data from Late Neogene (<10 Ma) pyrite samples from ODP legs 165 and 167 that were deposited in relatively oxic marine environments. The Tl isotope compositions of Late Neogene pyrites are all significantly heavier than seawater, which most likely indicates that Tl in diagenetic pyrite is partially sourced from ferromanganese oxy-hydroxides that are known to display relatively heavy Tl isotope signatures. One of the T-OAE sections from Peniche in Portugal displays pyrite thallium isotope compositions indistinguishable from Late Neogene samples, whereas samples from Yorkshire in the UK are depleted in the heavy isotope of Tl. These lighter compositions are best explained by the lack of ferromanganese precipitation at the sediment-water interface due to the sulfidic (euxinic) conditions thought to be prevalent in the Cleveland Basin where the Yorkshire section was deposited. The heavier signatures in the Peniche samples appear to result from an oxic water column that enabled precipitation of ferromanganese oxy-hydroxides at the sediment-water interface.The Tl isotope profile from Yorkshire is also compared with previously published molybdenum isotope ratios determined on the same sedimentary succession. There is a suggestion of an anti-correlation between these two isotope systems, which is consistent with the expected isotope shifts that occur in seawater when marine oxic (ferromanganese minerals) fluxes fluctuate.The results outlined here represent the first evidence that Tl isotopes in early diagenetic pyrite have potential to reveal variations in past ocean oxygenation on a local scale and potentially also for global oceans. However, much more information about Tl isotopes in different marine environments, especially in anoxic/euxinic basins, is needed before Tl isotopes can be confidently utilized as a paleo-redox tracer.     

Syndepositional volcanism in the Rietgat and arenaceous Bothaville Formations,Ventersdorp Supergroup (late Archaean—early Proterozoic), in South Africa

The volcanic-sedimentary succession of the Ventersdorp Supergroup which is virtually undisturbed tectonically and of low-grade (greenschist facies) metamorphism, affords a unique opportunity for studying the interplay between volcanic and sedimentary processes. The transitional sequence between the Rietgat and Bothaville Formations consists of a number of lithofacies. These are a basal breccia representing pyroclastic and laharic deposits, an overlying breccia—arenite—conglomerate (BAC) which formed by debris flow and fluvial processes, an arenite deposited offshore during a transgression, and an upper conglomerate laid down on a beach. In the volcaniclastic BAC and arenite lithofacies the presence of thin tuff beds, deformed acid lava fragments (bombs?) and glass shards in the arenaceous matrix suggest syndepositional volcanism.Sedimentation took place along the flanks of an asymmetrical, actively volcanic, domal structure which consisted partly of unstable pyroclastic deposits in the east. Resedimentation of the pyroclastic debris by subaerial debris flows and braided streams built a volcaniclastic fan lobe at the foot of the domal structure. As volcanic activity subsided, sands derived from a granitic terrain, mixed with minor air-fall debris to subsequently cover the fan lobe during a regional transgression.