Are opinions expressed in land-use planning documents?

A great deal of research on information extraction from textual datasets has been performed in specific data contexts, such as movie reviews, commercial product evaluations, campaign speeches, etc. In this paper, we raise the question on how appropriate these methods are for documents related to land-use planning. The kind of information sought concerns the stakeholders, sentiments, geographic information, and everything else related to the territory. However, it is extremely challenging to link sentiments to the three dimensions that constitute geographic information (location, time, and theme). After highlighting the limitations of existing proposals and discussing issues related to textual data, we present a method called OPILAND (OPinion mIning from LAND-use planning documents) designed to semi-automatically mine opinions related to named-entities in specialized contexts. Experiments are conducted on a Thau lagoon dataset (France), and then applied on three datasets that are related to different areas in order to highlight the relevance and the broader applications of our proposal.     

On the limits of using combined U-series/ESR method to date fossil teeth from two Early Pleistocene archaeological sites of the Orce area (Guadix-Baza basin,Spain)

The combined U-series/electron spin resonance (ESR) dating method was applied to nine teeth from two Early Pleistocene archaeological sites located in the Orce area (Guadix-Baza Basin, Southern Spain): Fuente Nueva-3 (FN-3) and Barranco León (BL). The combination of biostratigraphy and magnetostratigraphy places both sites between the Olduvai and Jaramillo subchrons (1.78–1.07 Ma).Our results highlight the difficulty of dating such old sites and point out the limits of the combined U-series/ESR dating method based on the US model. We identified several sources of uncertainties that may lead to inaccurate age estimates. Seven samples could not be dated because the dental tissues had (²³⁰Th/²³⁴U) activity ratios higher than equilibrium, indicating that uranium had probably leached from these tissues. It was however possible to calculate numerical estimates for two of the teeth, both from FN-3. One yielded a Middle Pleistocene age that seems to be strongly underestimated; the other provided an age of 1.19 ± 0.21 Ma, in agreement with data obtained from independent methods. The latter result gives encouragement that there are samples that can be used for routine dating of old sites.     

Assessing physical vulnerability in large cities exposed to flash floods and debris flows: the case of Arequipa (Peru)

Understanding the physical vulnerability of buildings and infrastructure to natural hazards is an essential step in risk assessment for large cities. We have interpreted high spatial resolution images, conducted field surveys, and utilized numerical simulations, in order to assess vulnerability across Arequipa, south Peru, close to the active El Misti volcano. The emphasis of this study was on flash floods and volcanic or non-volcanic hyperconcentrated flows, which recur on average every 3.5 years across the city. We utilized a geographic information system to embed vulnerability and hazard maps as a step to calculate risk for buildings and bridges along the Río Chili valley and two tributaries. A survey of ~1,000 buildings from 46 city blocks, different in age, construction materials, and land usage, provided architectural and structural characteristics. A similar survey of twenty bridges across the three valleys was based on structural, hydraulic, and strategic parameters. Interpretation of high spatial resolution (HSR) satellite images, which allows for quick identification of approximately 69 % of the structural building types, effectively supplemented field data collection. Mapping vulnerability has led us to pinpoint strategic areas in case of future destructive floods or flows. Calculated vulnerability is high if we examine structural criteria alone. We further consider physical setting with the most vulnerable city blocks located on the lowermost terraces, perpendicular or oblique to the flow path. Statistical analysis conducted on 3,015 city blocks, considering nine criteria identified from HSR images, indicated that building-type heterogeneity and the shape of the city blocks, along with building and street network density, are the most discriminant parameters for assessing vulnerability.     

The Corossol structure: A possible impact crater on the seafloor of the northwestern Gulf of St. Lawrence,Eastern Canada

We report on a 4.1 (±0.2) km diameter and 185 m deep circular submarine structure exposed on the seabed in >40 m water depths in the northwestern Gulf of St. Lawrence (Eastern Canada) from the analysis of high‐resolution multibeam bathymetric and seismic data. The presence of a circular form characterized by a central uplift and concentric rings resembles the morphology and geometry of complex meteorite impact structures. Also, other origins, such as kimberlites, intrusions, karsts, or diapirs, can be eliminated on geological criteria. A single 4 cm long breccia fragment recovered from the central uplift has numerous glassy droplets of fluorapatite composition, assumed to be impact melts, and a single quartz grain with planar intersection features thought to be shock‐induced planar deformation features (PDFs). The absolute age of this possible impact structure is unknown, but its geological setting indicates that it was formed long after the Mid‐Ordovician and before regional pre‐Quaternary sea‐level lowstands. Present results outline the need for further examination to confirm an impact origin and to precisely date the formation of the structure.     

Nonuniform cratering of the Moon and a revised crater chronology of the inner Solar System

We model the cratering of the Moon and terrestrial planets from the present knowledge of the orbital and size distribution of asteroids and comets in the inner Solar System, in order to refine the crater chronology method. Impact occurrences, locations, velocities and incidence angles are calculated semi-analytically, and scaling laws are used to convert impactor sizes into crater sizes. Our approach is generalizable to other moons or planets. The lunar cratering rate varies with both latitude and longitude: with respect to the global average, it is about 25% lower at (±65°N, 90°E) and larger by the same amount at the apex of motion (0°N, 90°W) for the present Earth-Moon separation. The measured size-frequency distributions of lunar craters are reconciled with the observed population of near-Earth objects under the assumption that craters smaller than a few kilometers in diameter form in a porous megaregolith. Varying depths of this megaregolith between the mare and highlands is a plausible partial explanation for differences in previously reported measured size-frequency distributions. We give a revised analytical relationship between the number of craters and the age of a lunar surface. For the inner planets, expected size-frequency crater distributions are calculated that account for differences in impact conditions, and the age of a few key geologic units is given. We estimate the Orientale and Caloris basins to be 3.73 Ga old, and the surface of Venus to be 240 Ma old. The terrestrial cratering record is consistent with the revised chronology and a constant impact rate over the last 400 Ma. Better knowledge of the orbital dynamics, crater scaling laws and megaregolith properties are needed to confidently assess the net uncertainty of the model ages that result from the combination of numerous steps, from the observation of asteroids to the formation of craters. Our model may be inaccurate for periods prior to 3.5 Ga because of a different impactor population, or for craters smaller than a few kilometers on Mars and Mercury, due to the presence of subsurface ice and to the abundance of large secondaries, respectively. Standard parameter values allow for the first time to naturally reproduce both the size distribution and absolute number of lunar craters up to 3.5 Ga ago, and give self-consistent estimates of the planetary cratering rates relative to the Moon.     

Determination of Trace Element Mass Fractions in Ultramafic Rocks by HR‐ICP‐MS: A Combined Approach Using a Direct Digestion/Dilution Method and Preconcentration by Coprecipitation

A procedure is described for the determination of thirty‐seven minor and trace elements (LILE, REE, HFSE, U, Th, Pb, transition elements and Ga) in ultramafic rocks. After Tm addition and acid sample digestion, compositions were determined both following a direct digestion/dilution method (without element separation) and after a preconcentration procedure using a double coprecipitation process. Four ultramafic reference materials were investigated to test and validate our procedure (UB‐N, MGL‐GAS [GeoPT12], JP‐1 and DTS‐2B). Results obtained following the preconcentration procedure are in good agreement with previously published work on REE, HFSE, U, Th, Pb and some of the transition elements (Sc, Ti, V). This procedure has two major advantages: (a) it avoids any matrix effect resulting from the high Mg content of peridotite, and (b) it allows the preconcentration of a larger trace element set than with previous methods. Other elements (LILE, other transition elements Cr, Mn, Co, Ni, Cu, Zn, as well as Ga) were not fully coprecipitated with the preconcentration method and could only be accurately determined through the direct digestion/dilution method.     

Toward a global coal mining moratorium? A comparative analysis of coal mining policies in the USA,China, India and Australia

To stop global warming at well below 2° C, the bulk of the world’s fossil fuel reserves will have to be left in the ground. Coal is the fossil fuel with the greatest proportion that cannot be used, and various advocacy groups are campaigning for a ban on the opening of new coal mines. Recently, both China and the USA implemented temporary moratoria on the approval of new coal mining leases. This article examines whether these coal mining bans reflect the emergence of a global norm to keep coal under the ground. To that end, we review recent coal mining policies in the four largest coal producers and explain them comparatively with a framework based on interests, ideas and institutions. We find that the norm of keeping coal in the ground remains essentially contested. Even in those countries that have introduced some form of a coal mining moratorium, the ban can easily be, or has already been, reversed. To the extent that the norm of keeping coal in the ground has momentum, it is primarily due to non-climate reasons: the Chinese moratorium was mostly an instance of industrial policy (aiming to protect Chinese coal companies and their workers from the overcapacity and low prices that are hitting the industry), while the USA’s lease restrictions were mainly motivated by concerns over fiscal justice. We do not find evidence of norm internalisation, which means that the emerging norm fails to gain much traction amid relevant national actors and other (large) coal producing states. If proponents of a moratorium succeed in framing the issue in non-climate terms, they should have a greater chance of building domestic political coalitions in favour of the norm.     

Behaviour of Fe-oxides relevant to contaminant uptake in the environment

The behaviour of Fe-oxides was investigated during precipitation and co-precipitation, phase transformation and dissolution, while their ability to adsorb and incorporate trace components was examined. Some samples were synthesised and studied under controlled laboratory conditions and other samples were taken from experiments designed to test the effectiveness of waste treatment strategies using iron. Surface-sensitive and high-resolution techniques were used to complement information gathered from classical, macroscopic methods.

Adsorption isotherms for Ni²⁺ uptake on synthetic ferrihydrite (Fe₅HO₈·4H₂O, often written simply Fe(OH)₃), goethite (-FeOOH), hematite (-Fe₂O₃) and magnetite (Fe₃O₄) were all similar, increasing as expected at higher pH. Desorption behaviour was also similar, but one third or more of the Ni²⁺ failed to return to solution. In the past, “irreversible sorption” has been blamed on uptake into micro-fractures or pores, but during examination (using Atomic force microscopy, AFM) of hundreds of Fe-oxide particles, no evidence for such features could be found, leading to the conclusion that Ni²⁺ must become incorporated onto or into the solids. When solutions of Fe(II) are oxidised in controlled laboratory conditions or during treatment of ash from municipal waste incinerators, two-line ferrihydrite forms rapidly and on never-dried samples, AFM shows abundant individual particles with diameter ranging from 0.5 to several tens of nanometers. Aging in solution at 70°C promotes growth of the particles into hematite and goethite and their identification (by X-ray powder diffraction, XRPD, with Rietveld refinement) becomes possible at the same aging stage as mineral morphology becomes recognisable by AFM. In other experiments that were designed to mimic natural attack by organic acids, colloidal lepidocrocite (γ-FeOOH) was observed in situ by AFM, while reductive dissolution removed material on specific crystal faces. Lath ends are eroded fastest while basal planes are more stable.

In order to help elucidate mechanisms of contaminant immobilisation by Fe-oxides, we examined samples from a reactive barrier made with 90% quartz sand, 5% bentonite and 5% zero-valent iron filings that had reacted with a solution typical of leachate from coal-burning fly ash using time-of-flight secondary ion mass spectroscopy (TOF-SIMS). Fe(0) oxidised to Fe(III), while soluble and toxic Cr(VI) was reduced to insoluble Cr(III). Chemical maps show Fe-oxide coatings on bentonite; Cr is associated with Fe-oxides to some extent but its association with Ca in a previously undescribed phase is much stronger. Other samples taken from municipal waste incinerator ash that had been treated by aeration in Fe(II) solutions were examined with transmission electron microscopy (TEM), selected area electron diffraction (SAED) and energy dispersive X-ray spectroscopy (EDS). Pb and some Zn are seen to be dispersed throughout two-line ferrihydrite aggregates, whereas Sn and some Zn are incorporated simply as a result of entrainment of individual ZnSn-oxide crystallites.

Geochemical speciation models that fail to account for contaminant uptake in solid solutions within major phases or as thin coatings or entrained crystals of uncommon phases such as those described here risk to underestimate contaminant retardation or immobilisation.