Geochemistry and Petrogenesis of Siwana Peralkaline Granites, West of Barmer, Rajasthan, India

The bimodal Malani suite, West of Barmer, Rajasthan is characterized by discontinuous, ring shaped outcrops of Siwana peralkaline granite with minor outcrops of basalt. The peralkaline, within- plate and A-type nature of granite are evident by its chemical characteristics. The granite is characterized by high Na₂O+K₂O, Fe/Mg, Zr, Nb, Y, Zn; low Al₂O₃, CaO and Sr and is significantly low in absolute abundance of trace and REE elements compared to type area Siwana granite. The granite is correlated to the “Pan-African” event and its petrogenesis and tectonic significance are discussed.     

Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.     

Estimating the contribution of the authigenic mineral component to the long-term reactive silica accumulation on the western shelf of the Mississippi River Delta

Previous studies have shown how biogenic silica particles undergo conversion to aluminosilicate phases in large tropical deltaic systems, thus affecting the world ocean budget of major seawater cations. This study tackles the important question of the silica budget in the coastal zone of the Mississippi River Delta, providing evidence for the role of biogenic silica diagenesis in this subtropical system from direct examination of individual diatom particles, sediment leachates and pore-water composition. The estimated reactive silica stored in the study area (5990 km²) is based on operational leaches that account for altered biogenic silica particles and other authigenic aluminosilicate phases in addition to fresh biogenic silica. Early diagenesis of silica in the delta front occurs mainly where more siliceous material is deposited. An inner-shelf area, where hypoxic conditions are found, significantly contributes to the formation of authigenic products of Si alteration. Data suggest that the limiting factor of silica alteration processes is the availability of detrital phases such as Al and Fe. The estimated total reactive silica accumulation in the study area is 1.45×10¹⁰ mol Si year⁻¹, representing ∼2.2% of the long-term bulk sediment accumulation. On the basis of a conservative appraisal, the authigenic mineral components account for ∼40% of the long-term reactive silica storage. This study shows that non-tropical deltaic systems are significantly more important sinks of silica than previously thought and that, where conditions are favourable, a consistent portion of reactive silica not leaving the shelf is stored within the delta in the form of authigenic components.     

The Holocene Secche di Lazzaro phreatomagmatic succession (Stromboli,Italy): evidence of pyroclastic density current origin deduced by facies analysis and AMS flow directions

The edifice of Stromboli volcano gravitationally collapsed several times during its volcanic history (>100 ka–present). The largest Holocene event occurred during the final stage of the Neostromboli activity (∼13–5 ka), and was accompanied by the emplacement of phreatomagmatic and lahar deposits, known as the Secche di Lazzaro succession. A stratigraphic and paleomagnetic study of the Secche di Lazzaro deposits allows the interpretation of the emplacement and the eruptive processes. We identify three main units within the succession that correspond to changing eruption conditions. The lower unit (UA) consists of accretionary lapilli-rich, thinly bedded, parallel- to cross-stratified ash deposits, interpreted to indicate the early stages of the eruption and emplacement of dilute pyroclastic density currents. Upward, the second unit (UB) of the deposit is more massive and the beds thicker, indicating an increase in the sedimentation rate from pyroclastic density currents. The upper unit (UC) caps the succession with thick, immediately post-eruptive lahars, which reworked ash deposited on the volcano’s slope. Flow directions obtained by Anisotropy of Magnetic Susceptibility (AMS) analysis of the basal bed of UA at the type locality suggest a provenance of pyroclastic currents from the sea. This is interpreted to be related to the initial base-surges associated with water–magma interaction that occurred immediately after the lateral collapse, which wrapped around the shoulder of the sector collapse scar. Upward in the stratigraphy (upper beds of UA and UB) paleoflow directions change and show a provenance from the summit vent, probably related to the multiple collapses of a vertical, pulsatory eruptive column.     

Land use and disturbance effects on the dynamics of natural ecosystems of the Monte Desert: Implications for their management

The complex interactions between human activity and natural processes determine non-linear dynamics in ecosystems that can difficult their management. Human settlements in arid lands contribute to the modification of disturbance regimes, including the introduction of new disturbances and the elimination of others. In consequence, they can alter the functional mechanisms that allow systems to overcome limiting factors, leading to desertification. In this revision, we evaluated the effects of the changes on disturbance regimes produced by the different forms of land transformation on the structure and function of ecosystems of the Monte Biogeographical Province, in Argentinean arid west. Two approaches were used: the analysis of land use history and the analysis of the effects of the main disturbances on the dynamics of different communities. We concluded that throughout the history of the Monte Desert, the joint action of natural and anthropic agents has resulted in complex dynamics that lead most area of the Monte to a moderate to severe status of desertification. The modification of the disturbance regime had strong consequences for several aspects of the dynamics of communities, such as species composition and diversity, water dynamics, soil conditions, trophic structure and productivity of Monte Desert ecosystems. However, disturbance regimes could be managed to promote favorable transitions in ecosystems and, therefore, could be a tool for optimizing productivity of agro-ecosystems, and recovering and conserving natural ecosystems.     

Effects of waterborne nitrite on phase I-II biotransformation in channel catfish (Ictalurus punctatus).

The effects of waterborne nitrite (3 mg/l NO2) on channel catfish were studied to evaluate changes in hematological parameters and phase I-II biotransformation in liver slices. Nitrite-exposed fish had significantly higher methemoglobin, blood and liver nitrite, and significantly lower pO2 than control fish. Total phase I-mediated metabolism of 7-ethoxycoumarin (EC) was not altered in nitrite-exposed fish compared with control fish (291 +/- 43 and 312 +/- 20 pmol/mg/h, respectively). However, phase II glucuronosyltransferase-mediated metabolism of 7-hydroxycoumarin (HC), both as a phase I metabolite of EC and as a parent substrate, was elevated in nitrite-exposed fish (204 +/- 17 and 1007 +/- 103 pmol/mg/h, respectively) as compared to control fish (149 +/- 14 and 735 +/- 87 pmol/mg/h) (P < 0.05). Sulfotransferase-mediated metabolism of HC (as a metabolite of EC and as a parent substrate) was not notably altered in nitrite-exposed fish (95 +/- 16 and 617 +/- 33 pmol/mg protein/h, respectively) as compared with control fish (118 +/- 24 and 575 +/- 55 pmol/mg/h, respectively). These studies indicate that in vivo nitrite exposure and associated changes in hematological parameters do not appear to affect hepatic phase I EC biotransformation in channel catfish. However, subtle but significant changes in phase II glucuronidation, but not sulfation activity, were observed. The mechanism of these alterations is unclear. However, the data suggest that environmentally realistic concentrations of nitrite may affect the dynamics of conjugative metabolism in exposed fish.     

Bacterial response to seasonal changes in labile organic matter composition on the continental shelf and bathyal sediments of the Cretan Sea

Bacterial abundance, biomass and cell size were studied in the oligotrophic sediments of the Cretan Sea (Eastern Mediterranean), in order to investigate their response to the seasonal varying organic matter (OM) inputs. Sediment samples were collected on a seasonal basis along a transect of seven stations (ranging from 40 to 1570 m depth) using a multiple-corer. Bacterial parameters were related to changes in chloroplastic pigment equivalents (CPE), the biochemical composition (proteins, lipids, carbohydrates) of the sedimentary organic matter and the OM flux measured at a fixed station over the deep basin (1570 m depth). The sediments of the Cretan Sea represent a nutrient depleted ecosystem characterised by a poor quality organic matter. All sedimentary organic compounds were found to vary seasonally, and changes were more evident on the continental shelf than in deeper sediments. Bacterial abundance and biomass in the sediments of the Cretan Sea (ranging from 1.02 to 4.59 × 10⁸ cells g⁻¹ equivalent to 8.7 and 38.7 μgC g⁻¹) were quite high and their distribution appeared to be closely related to the input of fresh organic material. Bacterial abundance and biomass were sensitive to changes in nutrient availability, which also controls the average cell size and the frequency of dividing cells. Bacterial abundance increased up to 3-fold between August '94 and February '95 in response to the increased amount of sedimentary proteins and CPE, indicating that benthic bacteria were constrained more by changes in quality rather than the quantity of the sedimentary organic material. Bacterial responses to the food inputs were clearly detectable down to 10 cm depth. The distribution of labile organic compounds in the sediments appeared to influence the vertical patterns of bacterial abundance and biomass. Cell size decreased significantly with water depth. Bacterial abundance and biomass were characterised by clear seasonal changes in response to seasonal OM pulses. The strong coupling between protein flux and bacterial biomass together with the strong bacterial dominance over the total biomass suggest that the major part of the carbon flow was channelled through the bacteria and the benthic microbial loop.     

Origin of fluids in iron oxide–copper–gold deposits: constraints from δ 37Cl, 87Sr/86Sri and Cl/Br

The origin of the hypersaline fluids (magmatic or basinal brine?), associated with iron oxide (Cu–U–Au–REE) deposits, is controversial. We report the first chlorine and strontium isotope data combined with Cl/Br ratios of fluid inclusions from selected iron oxide–copper–gold (IOCG) deposits (Candelaria, Raúl–Condestable, Sossego), a deposit considered to represent a magmatic end member of the IOCG class of deposit (Gameleira), and a magnetite–apatite deposit (El Romeral) from South America. Our data indicate mixing of a high δ ³⁷Cl magmatic fluid with near 0‰ δ ³⁷Cl basinal brines in the Candelaria, Raúl–Condestable, and Sossego IOCG deposits and leaching of a few weight percent of evaporites by magmatic-hydrothermal (?) fluids at Gameleira and El Romeral. The Sr isotopic composition of the inclusion fluids of Candelaria, Raúl–Condestable, and El Romeral confirms the presence of a non-magmatic fluid component in these deposits. The heavy chlorine isotope signatures of fluids from the IOCG deposits (Candelaria, Raúl–Condestable, Sossego), reflecting the magmatic-hydrothermal component of these fluids, contrast with the near 0‰ δ ³⁷Cl values of porphyry copper fluids known from the literature. The heavy chlorine isotope compositions of fluids of the investigated IOCG deposits may indicate a prevailing mantle Cl component in contrast to porphyry copper fluids, an argument also supported by Os isotopes, or could result from differential Cl isotope fractionation processes (e.g. phase separation) in fluids of IOCG and porphyry Cu deposits.     

Geochemistry and zircon U-Pb geochronology of Aligoodarz granitoid complex, Sanandaj-Sirjan Zone, Iran

The Aligoodarz granitoid complex (AGC) is located in the Sanandaj-Sirjan Zone (SSZ), western Iran and consists of quartz-diorites, granodiorites and subordinate granites. Whole rock major and trace element data mostly define linear trends on Harker diagrams suggesting a cogenetic origin of the different rock types. (⁸⁷Sr/⁸⁶Sr)_i and εNd_t ratios are in the ranges 0.7074-0.7110 and −3.56 to −5.50, respectively. The trace elements and Sr-Nd isotopic composition suggest that the granitoids from the AGC are similar to crustal derived I-type granitoids of continental arcs. The whole rock suite was produced by assimilation and fractional crystallization starting from a melt with intermediate composition likely possessing a mantle component. In situ zircon U-Pb data on the granites with LA-ICP-MS yield a crystallization age of ∼165 Ma. Inherited grains spanning in age from ∼180 Ma up to 2027 Ma were also found and confirm that assimilation of country rock has occurred.Chemical and chronological data on the AGC were compared with those available for other granitoid complexes of the central SSZ (e.g., Dehno, Boroujerd and Alvand). The comparison reveals that in spite of the different origins that have been proposed, all these granitoid complexes are likely genetically related. They share many chemical features and are derived from crustal melts with minor differences. Alvand granites have the most peculiar compositions most likely related to the presence of abundant pelitic component. All these intrusions are coeval and reveal the presence of an extensive magmatic activity in the central sector of the SSZ during middle Jurassic.