Seasonal variations of exposure biomarkers, oxidative stress responses and cell damage in the clams, Tapes philippinarum, and mussels, Mytilus galloprovincialis, from Adriatic sea

This work investigated the natural variability of several biomarkers in Tapes philippinarum and Mytilus galloprovincialis, sampled from Northern Adriatic where these organisms are important sentinel species for future environmental impact assessment. Levels of metallothioneins, peroxisomal enzymes and acetylcholinesterase, showed a significant seasonality and marked differences between clams and mussels. Among antioxidant enzymes, catalase and GST decreased during the warmer period, the latter enzyme activity resulting particularly high in clams. The total oxyradical scavenging capacity toward peroxyl radicals decreased in mussels from winter to summer, indicating a prooxidant challenge due to higher seawater temperature and intensity of light irradiance. Lysosomal membrane stability did not exhibit significant seasonal variations, while some variations were observed for DNA damages. Overall results indicated a significant influence of seasonal variability on several biomarkers and species-specific differences which should be considered to discriminate the appearance of anthropogenic disturbance.     

The value of technology and of its evolution towards a low carbon economy

This paper assesses the economic value associated with the development of various low-carbon technologies in the context of climate stabilization. We analyze the impact of restrictions on the development of specific mitigation technologies, comparing three integrated assessment models used in the RECIPE comparison exercise. Our results indicate that the diversification of the carbon mitigation portfolio is an important determinant of the feasibility of climate policy. Foregoing specific low carbon technologies raises the cost of achieving the climate policy, though at different rates. CCS and renewables are shown to have the highest value, given their flexibility and wide coverage. The costs associated with technology failure are shown to be related to the role that each technology plays in the stabilization scenario, but also to the expectations about their technological progress. In particular, the costs of restriction of mature technologies can be partly compensated by more innovation and technological advancement.     

Innovation benefits from nuclear phase-out: can they compensate the costs?

This paper investigates whether an inefficient allocation of abatement due to constraints on the use of currently available low carbon mitigation options can promote innovation in new technologies and have a positive impact on welfare. We focus on the case of a nuclear power phase-out and endogenous technical change in energy efficiency and alternative low carbon technologies. The research is inspired by the re-thinking about nuclear power deployment which took place in some countries, especially in Western Europe, after the Fukushima accident in March 2011. The analysis uses an Integrated Assessment Model, WITCH, which features multiple externalities related to greenhouse gas emissions and innovation market failures. Our results show that phasing out nuclear power stimulates R&D investments and deployment of technologies with large learning potential. The resulting technology benefits that would not otherwise occur due to intertemporal and international externalities almost completely offset the economic costs of foregoing nuclear power. The extent of technology benefits depends on the stringency of the climate policy and is distributed unevenly across countries.     

卫星遥感藏北高原非均匀陆表地表特征参数和植被参数

卫星遥感在研究青藏高原北部地区(藏北高原地区)非均匀陆表地表特征参数和植被参数时有其独到的作用.作者提出了基于NOAA-14 AVHRR资料推算藏北高原地区地表特征参数和植被参数的方案,并把其用于全球能量水循环之亚洲季风青藏高原试验(GAME/Tibet)试验区.同时利用3个景的NOAA-14 AVHRR资料进行了分析研究,得到了一些有关藏北地区非均匀地表的区域地表特征参数(地表反射率、地表温度)和植被参数(INDV、植被覆盖度和叶面指数ILA).     

Re–Os and Pb–Pb geochronology of the Archean Salobo iron oxide copper–gold deposit, Carajás mineral province, northern Brazil

Rhenium–osmium ages were determined for two molybdenite samples and a Pb–Pb age was derived from bornite–chalcopyrite–magnetite at the Salobo iron oxide copper–gold deposit to determine the timing of mineralization and its relation to the nearby Old Salobo Granite. Rhenium–osmium dating of molybdenite spatially associated with copper sulfide minerals yields ages with weighted means of 2576±8 and 2562±8 Ma. Removing the error multiplier introduced by the decay constant uncertainty, appropriate for comparing ages from the same isotopic system, these data convincingly argue for two temporally separated pulses of molybdenite deposition at 2576.1±1.4 Ma (n=2) and 2561.7±3.1 Ma (n=3). The 2576±8 Ma age coincides with a previously published U–Pb age of 2573±2 Ma for the Old Salobo Granite, suggesting that main stage ore formation may have been contemporaneous with granite magmatism. The slightly younger 2562 Ma age most likely represents new molybdenite precipitation associated with the development or reactivation of local shear zones. Lead–lead stepwise leaching of copper sulfide minerals yields a less precise isochron age of 2579±71 Ma, and supports an Archean age for the Salobo ores. This is the first documentation of an Archean iron oxide copper–gold deposit, and the Re–Os and Pb–Pb geochronology herein support 2580–2550 Ma estimates for basement reactivation and regional granite magmatism associated with the development of brittle–ductile shear zones.     

Are we going to live in a post-NATO world? A critical perspective on trends,obstacles and possibilities

The main research question investigated in this paper is the following: will a post-NATO world emerge during the next decades? The relevance of such a question is a consequence of the political and economic changes that have seen the light as a result of the power shift of international relations after the end of the Cold War. In spite of this, some contradictory tendencies, such as the weakening of the European pole within the NATO block, the US-NATO enlargement and its military aggressiveness, are generating a number of significant obstacles to the emergence of a post-NATO world. We will argue that the existence of these obstacles could be interpreted as some steps toward the historical downsizing of the US-EU-NATO hegemony. A “post-NATO” world does not necessarily imply the end of NATO, but rather the end of its hegemonic military presence on the global stage. Firstly, we will put the question into context mentioning the debates around NATO’s future and underlining the path undertaken by the Alliance in the frame of the redefinition of the aims of its “strategic concepts”. In this perspective, we will underline the direct link which exists between US strategic needs and NATO’s evolution in the post-Cold war era. Secondly, we will argue that the recent process of military expansionism led by NATO is remarkably de-legitimizing its actions on the global stage. Such a process, along with the current world system shift toward the end of unipolarity, is likely to provoke dramatic consequences in terms of international insecurity and the spreading of war. Thirdly, we will briefly compare the US and Chinese foreign actions, arguing that the space of international legitimacy is radically changing. This fact represents another brick supporting the idea of the emergence of a post-NATO world system in the future of international relations.     

Timing of juvenile arc crust formation and evolution in the Sapat Complex (Kohistan–Pakistan)

The combination of age determination and geochemical tracers allows understanding the source evolution during magmatism. We studied the Sapat Complex, in the exhumed Cretaceous Kohistan Paleo-Island Arc, to reconstruct the formation of the juvenile lower arc crust and the evolution of the mantle source during arc magmatism. High precision ID-TIMS U/Pb dating on zircon, shows that a protracted period of magmatic accretion formed the Sapat Complex between 105 and 99 Ma. Since continued melt percolation processes that formed the lower crust obscured the original bulk rock Nd–Pb–Sr isotopic composition, we rely on the Hf isotopic composition of zircons of different ages to unravel the source evolution. Nd and Pb bulk isotopic compositions coupled with Hf isotopic composition on zircons allow reconstructing a geodynamical scenario for the Sapat Complex, and the Cretaceous history of the Arc. We suggest that trenchward migration of the hot mantle source at 105 Ma explains the small heterogeneous εHf signal between + 14 and + 16. This heterogeneity vanished within ca. 2 million years, and the εHf of the source evolved from + 16 to + 14 at 99 Ma. Integrated to the Kohistan Cretaceous history, which has a baseline of εHf ≈ 14, these data pinpoint two geodynamical events, with slab retreat and the formation of the Sapat Complex followed by splitting of the Kohistan island arc at 85 Ma.     

Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.     

New constraints on the origin and age of Variscan eclogitic rocks (Ligurian Alps,Italy)

Gabbro and eclogite boudins are preserved within the amphibolites of the composite para- and ortho-gneiss Variscan basement of the Savona Crystalline Massif (Ligurian Briançonnais, Italy). Whole rock trace element patterns, low initial εNd (+5.4 to +8.8) data and trace element analyses on relict igneous clinopyroxene revealed that the mafic rocks were derived from depleted mantle melts, which most likely underwent crustal contamination during emplacement. Gabbros have a cumulus origin controlled by clinopyroxene and plagioclase segregation, whereas the eclogites represent evolved melts. U-Pb and trace element micro-analyses on zircons separated from one amphibolitised gabbro and one eclogite help to constrain coeval ages at ~468 Ma for their igneous protoliths. The occurrence of a few inherited zircons confirms the involvement of a crustal component in the petrogenesis of the mafic rocks. In the eclogite, concordant zircon ages younger than the protolith age testify to metamorphic re-crystallisation (or new growth) from about 420 to 305 Ma. Zircon textures and trace element compositions indicate that eclogite facies metamorphism occurred 392–376 Ma ago. The younger zircon portions yielding a mean Concordia age of 333 ± 7 Ma are related to equilibration or new growth during the post-eclogite, amphibolite-facies equilibration.