Iron release in aqueous environment by fresh volcanic ash from Mount Etna (Italy) and Popocatépetl (Mexico) volcanoes

In this study, we performed leaching experiments for timescales of hours-to-months in deionized water on fresh volcanic ash from Mt. Etna (Italy) and Popocatépetl (Mexico) volcanos to monitor Fe release as a function of ash mineral chemistry and size, with the aim of clarifying Fe release mechanisms and eventually evaluating the impact of volcanic ash on marine and lacustrine environments. To define sample mineralogy and Fe speciation, inclusive characterization was obtained by means of XRF, SEM, XRPD, EELS and Mössbauer spectroscopies. For Etna and Popocatépetl samples, glass proportions were quantified at 73 and 40%, Fe₂O₃ total contents at 11.6–13.2 and 5.8 wt%, and Fe³⁺/Fe_Tot ratios at 0.33 and 0.23, respectively. Leaching experiments showed that significant amounts of iron, ~?30 to 150 and ~?750 nmol g^?1 l^?1 for pristine Etna and Popocatépetl samples, respectively, are released within the first 30 min as a function of decreasing particle size (from 1 to 0.125 mm). The Popocatépetl sample showed a very sustained Fe release (up to 10 times Etna samples) all along the first week, with lowest values never below 400 nmol g^?1 l^?1 and a maximum of 1672 nmol g^?1 l^?1 recorded after 5 days. This sample, being composed of very small particles (average particle size 0.125 mm) with large surface area, likely accumulated large quantities of Fe-bearing sublimates that quickly dissolved during leaching tests, determining high Fe release and local pH decrease (that contributed to release more Fe from the glass) at short timescale (hours-to-days). The fractional Fe solubility (Fe_S) was 0.004–0.011 and 0.23% for Etna and Popocatépetl samples, respectively, but no correlation was found between Fe released in solution and either ash Fe content, glass/mineral ratio or mineral assemblage. Results obtained suggest that volcanic ash chemistry, mineralogy and particle size assume a relevant role on Fe release mostly in the medium-to-long timescale, while Fe release in the short timescale is dominated by dissolution of surface sublimates (formed by physicochemical processes occurring within the eruption plume and volcanic cloud) and the effects of such a dissolution on the local pH conditions. For all samples, a moderate to sustained Fe release occurred for leaching times comparable with their residence time within the euphotic zone of marine and lacustrine environments (variable from few minutes to few hours), revealing their possible contribution to increase Fe bioavailability.     

Harmonization vs. fragmentation: overview of climate policy scenarios in EMF27

This paper synthesizes results of the multi-model Energy Modeling Forum 27 (EMF27) with a focus on climate policy scenarios. The study included two harmonized long-term climate targets of 450 ppm CO₂-e (enforced in 2100) and 550 pm CO₂-e (not-to-exceed) as well as two more fragmented policies based on national and regional emissions targets. Stabilizing atmospheric GHG concentrations at 450 and 550 ppm CO₂-e requires a dramatic reduction of carbon emissions compared to baseline levels. Mitigation pathways for the 450 CO₂-e target are largely overlapping with the 550 CO₂-e pathways in the first half of the century, and the lower level is achieved through rapid reductions in atmospheric concentrations in the second half of the century aided by negative anthropogenic carbon flows. A fragmented scenario designed to extrapolate current levels of ambition into the future falls short of the emissions reductions required under the harmonized targets. In a more aggressive scenario intended to capture a break from observed levels of stringency, emissions are still somewhat higher in the second half due to unabated emissions from non-participating countries, emphasizing that a phase-out of global emissions in the long term can only be reached with full global participation. A key finding is that a large range of energy-related CO₂ emissions can be compatible with a given long-term target, depending on assumptions about carbon cycle response, non-CO₂ and land use CO₂ emissions abatement, partly explaining the spread in mitigation costs.     

Hydraulics and Hydrology in Mountain Areas

<正>The 35th IAHR World Congress was held in Chengdu,China from September 8 to September 132013.The title of the conference was:"The Wise Finds Pleasure in Water:Meandering through Water Science and Engineering".During the congress,1239 papers were presented in 139sessions for oral presentations and 7 sessions for poster presentations.After the Congress,a Committee was appointed to select some of the best papers presented at the Congress for publication,after a     

Application and validation of bivariate GIS-based landslide susceptibility assessment for the Vitravo river catchment (Calabria,south Italy)

The Calabria (Southern Italy) region is characterized by many geological hazards among which landslides, due to the geological, geomorphological, and climatic characteristics, constitute one of the major cause of significant and widespread damage. The present work aims to exploit a bivariate statistics-based approach for drafting a landslide susceptibility map in a specific scenario of the region (the Vitravo River catchment) to provide a useful and easy tool for future land planning. Landslides have been detected through air-photo interpretation and field surveys, by identifying both the landslide detachment zones (LDZ) and landslide bodies; a geospatial database of predisposing factors has been constructed using the ESRI ArcView 3.2 GIS. The landslide susceptibility has been assessed by computing the weighting values (Wi) for each class of the predisposing factors (lithology, proximity to fault and drainage line, land use, slope angle, aspect, plan curvature), thus evaluating the distribution of the landslide detachment zones within each class. The extracted predisposing factors maps have then been re-classified on the basis of the calculated weighting values (Wi) and by means of overlay processes. Finally, the landslide susceptibility map has been considered by five classes. It has been determined that a high percentage (61%) of the study area is characterized by a high to very high degree of susceptibility; clay and marly lithologies, and slope exceeding 20° in inclination would be much prone to landsliding. Furthermore, in order to ascertain the proposed landslide susceptibility estimate, a validation procedure has been carried out, by splitting the landslide detachment zones into two groups: a training and a validation set. By means of the training set, the susceptibility map has first been produced; then, it has been compared with the validation set. As a result, a great majority of LDZ-validation set (85%) would be located in highly and very highly susceptible areas. The predictive power of the model is considered reliable, since more than 50% of the LDZ fall into 20% of the most susceptible areas. The reliability of the susceptibility map is also suggested by computing the SCAI index, true positive and false positive rates; nevertheless, the most susceptible areas are overestimated. As a whole, the results indicate that landslide susceptibility assessment based on a bivariate statistics-based method in a GIS environment may be useful for land planning policy, especially when considering its cost/benefit ratio and the need of using an easy tool.     

Coexistence of abyssal and ultra-depleted SSZ type mantle peridotites in a Neo-Tethyan Ophiolite in SW Turkey: Constraints from mineral composition,whole-rock geochemistry (major–trace–REE–PGE), and Re–Os isotope systematics

We present new, whole-rock major and trace element chemistry, including rare earth elements (REE), platinum-group elements (PGE), and Re–Os isotope data from the upper mantle peridotites of a Cretaceous Neo-Tethyan ophiolite in the Mu?la area in SW Turkey. We also report extensive mineral chemistry data for these peridotites in order to better constrain their petrogenesis and tectonic environment of formation. The Mu?la peridotites consist mainly of cpx-harzburgite, depleted harzburgite, and dunite. Cpx-harzburgites are characterized by their higher average CaO (2.27 wt.%), Al₂O₃ (2.07 wt.%), REE (53 ppb), and ¹⁸⁷Os/¹⁸⁸Os_(i) ratios varying between 0.12497 and 0.12858. They contain Al-rich pyroxene with lower Cr content of coexisting spinel (Cr# = 13–22). In contrast, the depleted harzburgites and dunites are characterized by their lower average CaO (0.58 wt.%), Al₂O₃ (0.42 wt.%), and REE (1.24 ppb) values. Their clinopyroxenes are Al-poor and coexist with high-Cr spinel (Cr# = 33–83). The ¹⁸⁷Os/¹⁸⁸Os_(i) ratios are in the range of 0.12078–0.12588 and are more unradiogenic compared to those of the cpx-harzburgites.Mineral chemistry and whole rock trace and PGE data indicate that formation of the Mu?la peridotites cannot be explained by a single stage melting event; at least two-stages of melting and refertilization processes are needed to explain their geochemical characteristics. Trace element compositions of the cpx-harzburgites can be modeled by up to ~ 10–16% closed-system dynamic melting of a primitive mantle source, whereas those of the depleted harzburgites and dunites can be reproduced by ~ 10–16% open-system melting of an already depleted (~ 16%) mantle. These models indicate that the cpx-harzburgites are the products of first-stage melting and low-degrees of melt–rock interaction that occurred in a mid-ocean ridge (MOR) environment. However, the depleted harzburgites and dunites are the product of second-stage melting and related refertilization which took place in a supra subduction zone (SSZ) environment. The Re–Os isotope systematics of the Mu?la peridotites gives model age clusters of ~ 250 Ma, ~ 400 Ma and ~ 750 Ma that may record major tectonic events associated with the geodynamic evolution of the Neo-Tethyan, Rheic, and Proto-Tethyan oceans, respectively. Furthermore, > 1000 Ma model ages can be interpreted as a result of an ancient melting event before the Proto-Tethys evolution.     

Apparent diameters of 172 B5V-A5V stars of the Catalogue of Geneva Observatory

The spectrophotometric method for computing the apparent stellar diameters, proposed by Chalonge and Divan (1950) and modified by Fracassini and Pasinetti (1967) has been applied to 172 B5V-A5V stars (single and belonging to galactic clusters) of the Catalogue of Geneva Observatory (Rufener, 1971). In the straight line diagrams log vsm, drawn for the stars of the same spectral type, it is possible to identify some peculiar stars (with peculiarities in the diameter or monochromatic brightness). The agreement with the values of the apparent diameters of Leo, Ori, Lyr and CMa, obtained by Hanbury Brownet al. (1967), is very good. The comparison with the diagramss _v vs (B-V)₀,R vs (B-V)₀ deduced by Wesselink (1969), seems satisfactory. The comparison with the results obtained by other authors and the great number of stars which will be observed in the photometric system in seven colors of Geneva, demonstrate the wide possibilities of this spectrophotometric method for determining the apparent stellar diameters.

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Sommario Il metodo spettrofotometrico di Chalonge e Divan (1950) per il calcolo dei diametri stellari apparenti, modificato da Fracassini e Pasinetti (1967), è stato applicato a 172 stelle B5V-A5V (isolate e in ammassi galattici) del Catalogo dell'Osservatorio di Ginevra (Rufener, 1971). Costruiti i diagrammi lineari log -m _v per i vari gruppi di stelle dello stesso tipo spettrale, è possibile identificare alcune stelle peculiari con diametri e brillanze monochromatiche anomale. Il confronto con i diametti apparenti di Leo, Ori, Lyr e CMa determinati da Hanbury Brownet al. (1967) mostra un accordo molto buono. Il confronto con le relazionis _v -(B-V)₀eR-(B-V) ₀ ottenute da Wesselink (1969) appare soddisfacente. Il confronto con i risultati ottenuti da altri autori e il grande numero di stelle che saranno osservate nel sistema fotometrico in sette colori di Ginevra, dimostrano le ampie possibilità di questo metodo spettrofotometrico per la determinazione dei diametri stellari apparenti.

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Thesis for the degree on Applied Physics.     

Gebel Kamil: The iron meteorite that formed the Kamil crater (Egypt)

Abstract– The 45 m in diameter Kamil impact crater was formed <5000 yr ago in the eastern Sahara, close to the southern border of modern Egypt. The original features of this structure, including thousands of fragments of the meteorite impactor, are extremely well preserved. With the exception of a single 83 kg regmaglypted individual, all specimens of Gebel Kamil (the iron meteorite that formed the Kamil crater) are explosion fragments weighing from <1 g to 34 kg. Gebel Kamil is an ungrouped Ni‐rich (about 20 wt% Ni) ataxite characterized by high Ge and Ga contents (approximately 120 μg g^?1 and approximately 50 μg g^?1, respectively) and by a very fine‐grained duplex plessite metal matrix. Accessory mineral phases in Gebel Kamil are schreibersite, troilite, daubréelite, and native copper. Meteorite fragments are cross‐cut by curvilinear shear bands formed during the explosive terrestrial impact. A systematic search around the crater revealed that meteorite fragments have a highly asymmetric distribution, with greater concentrations in the southeast sector and a broad maximum in meteorite concentration in the 125–160° N sector at about 200 m from the crater rim. The total mass of shrapnel specimens >10 g, inferred from the density map compiled in this study is 3400 kg. Field data indicate that the iron bolide approached the Earth’s crust from the northwest (305–340° N), travelling along a moderately oblique trajectory. Upon hypervelocity impact, the projectile was disrupted into thousands of fragments. Shattering was accompanied by some melting of the projectile and of the quartz‐arenite target rocks, which also suffered shock metamorphism.     

Degassing, crystallization and eruption dynamics at Stromboli: trace element and lithium isotopic evidence from 2003 ashes

During its 1800-year-long persistent activity the Stromboli volcano has erupted a highly porphyritic (HP) volatile-poor scoriaceous magma and a low porphyritic (LP) volatile-rich pumiceous magma. The HP magma is erupted during normal Strombolian explosions and lava effusions, while the LP one is related to more energetic paroxysms. During the March–April 2003 explosive activity, Stromboli ejected two typologies of juvenile glassy ashes, namely highly vesicular LP shards and volatile-poor HP shards. Their textural and in situ chemical characteristics are used to unravel mutual relationships between HP and LP magmas, as well as magma dynamics within the shallow plumbing system. The mantle-normalized trace element patterns of both ash types show the typical arc-lava pattern; however, HP glasses possess incompatible element concentrations higher than LP glasses, along with Sr and Eu negative anomalies. HP shards are generally characterized by higher Li contents (to ~20 ppm) and lower δ⁷Li values (+1.2 to −3.8‰) with respect to LP shards (Li contents of 7–14 ppm and δ⁷Li ranging between +4.6 and +0.9‰). Fractional crystallization models based on major and trace element compositions, combined with a degassing model based on open-system Rayleigh distillation and on the assumption that ^melt/fluidD_Li > 1, show that abundant (~30%) plagioclase precipitation and variable degrees of degassing can lead the more primitive LP magma to evolve toward a differentiated (isotopically lighter) HP magma ponding in the upper conduit and undergoing slow continuous degassing-induced crystallization. This study also evidences that in March 2003 Stromboli volcano poured out a small early volume of LP magma that traveled slower within the conduit with respect to later and larger volumes of fast ascending LP magma erupted during the April 5 paroxysm. The different ascent rates and cooling rates of the two LP magma batches (i.e., pre- and post-paroxysm) resulted in small, but detectable, differences in their chemical signatures. Finally, this study highlights the high potential of in situ investigations of juvenile glassy ashes in petrologic and geochemical monitoring the volcanic activity and of Li isotopes as tracers of degassing processes within the shallow plumbing system.     

Anatomy of a late Pleistocene clinoformal sedimentary body (Le Castella,Calabria, southern Italy): A case of prograding spit system?

The Le Castella marine terrace is the smallest and youngest terrace of the Crotone area (southern Italy), and formed after a rapid marine ingression due to a glacio-eustatic rise outpacing the regional uplift of the area. The most prominent feature of the terrace deposits is a seaward-accreting clinoform about 10 m thick, inferred to be formed during forced regressive conditions. This prograding body is mostly composed of bioclastic material, and shows an internal complexity consisting of alternating oblique and sigmoid elementary units inferred to be produced mainly by changes of accommodation development. Foreset avalancing was due to sediment accumulation by gravity-flow processes, while topsets were characterized by the migration of medium- to large-scale dunes showing a unimodal palaeocurrent pattern, oblique with respect to the dip direction of the large-scale clinoform foresets. The Le Castella clinoform starts to develop from a topographic step on the basement due to tectonics, which also controlled the palaeoshoreline trend.The recognized stratigraphic and facies architectures, the palaeocurrent pattern, and the inferred palaeogeographic setting during deposition, all suggest that the Le Castella clinoform is an example of spit system attached to the mainland and accreted due to longshore transport. The present example contributes to establish criteria allowing the recognition of ancient spit systems, which still are poorly known and rarely documented in the pre-Quaternary geological record.     

Constraints on metasomatized mantle under Central South America: evidence from Jurassic alkaline lamprophyre dykes from the Eastern Cordillera, NM Argentina

In the Río Grande Valley, NW Argentina, several porphyritic panidiomorphic, ocelli-bearing dykes and sills intrude the Neoproterozoic to lower Paleozoic basement of the Eastern Cordillera. New petrographical and geochemical data permit us to classify these rocks as ocellar-analcime monchiquites, a feldspar-free variety of alkaline lamprophyre composed of Ti-rich-diopside/augite, Ti-rich biotite/phlogopite, forsteritic olivine, titanian-pargasite and analcime, with abundant ocelli filled with analcime/carbonate. In terms of geochemical compositions they are characterized by LILE and LREE enrichment and lack of Nb-Ta and Eu anomalies. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd initial ratios range between 0.70377 to 0.70781 and 0.512506 and 0.512716 respectively, and T_DM model ages vary between 0.25–0.64 Ga. A K-Ar age of 163?±?9 Ma suggests that these rocks are related to the pre-rifting stage of the Mesozoic-Cenozoic continental Salta Rift in NW Argentina. Partial melting of a heterogeneous enriched metasomatized lithospheric mantle, magma mixing and fractionation are envisaged to explain the petrographic, geochemical and isotope characteristics of these magmas.