Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.     

Formation of chlorite rims and the impact of pore-lining chlorite on reservoir quality: a case study from Shiqianfeng sandstones in upper Permian of Dongpu Depression,Bohai Bay Basin,eastern China

The source material, precursor and formation processes of chlorite rims, and impact of pore-lining chlorite on reservoir quality of the Shiqianfeng sandstones, Dongpu Depression, Bohai Bay Basin, China, are studied using an integrated approach, including core observation, point-count analysis of thin-sections, scanning electron microscopy, electron microprobe analysis and cathode luminescence. The petrographic analysis shows that chlorite rims consist of grain-coating chlorite, poorly crystalline pore-lining chlorite and euhedral-crystallised pore-lining chlorite. The chemical composition shows that pore-lining chlorite is mainly Fe-rich with an average of 0.785 for Fe/(Fe+Mg) ratio. Petrographic analysis shows a large amount of volcanic dust (3.0～16.0 vol%, average of 7.93 vol%) in Shiqianfeng sandstones, which determines the formation of poorly crystalline pore-lining chlorite. Transformation of volcanic dust to smectite rims started with shallow burial depth at an early diagenetic stage, followed by in situ alteration of the smectite rims to poorly crystalline chlorite rims. Euhedral-crystallised chlorite mainly develops in sandstones with high porosity, high permeability and open flow systems. Pore-lining chlorite can inhibit quartz overgrowth but cannot effectively prevent pore-filling of authigenic quartz, carbonate and kaolinite cements, and therefore cannot prevent porosity destruction. However, the occurrence of pore-lining chlorite is a barometer of good reservoir quality and intense hydrodynamic conditions.     

WORLD ATLAS OF THEMATIC MAPS OF DESERTIFICATION

The author describes the contents and participation of former Soviet republics in the compilation of a global atlas of desertification, published under the auspices of the United Nations. Translated by H. L. Haslett, Leamington Spa, UK, from: Izvestiya Akademii Nauk SSSR, seriya geograficheskaya, 1991, No. 6, p. 130.     

ON LOPINITE,A NEW TYPE OF COAL IN CHINA

To the east of Nanchang,the capital of Kiangsi Province,there cropsout a continuous belt of Permian coal series~1 trending approximately in thedirection from N.E.to S.W.Broadly speaking,this coal belt forms a synclinal     

Prediction of surface horizontal displacements, and gravity and tilt changes caused by filling the Three Gorges Reservoir

 Horizontal displacements, and gravity and tilt changes induced by filling the Three Gorges Reservoir are modeled using elastic loading Green functions. When the water surface reaches its highest level, the effects become maximum on the reservoir banks. The longitudinal and latitudinal components of the horizontal displacements reach −8.2 and 7.7 mm respectively, gravity is increased by up to 3.4 mGal, and the prime vertical and meridian components of the tilt changes are −7.8 and −17.5 arcseconds respectively. Accordingly, the filling of the reservoir will influence values observed from global positioning system (GPS), gravimetry and tilt measurements in the area. The results given can be used to provide important corrections for extracting earthquake-related signals from observed data. Received: 19 January 2001 / Accepted: 3 September 2001     

Alteration in CM carbonaceous chondrites inferred from modal and chemical variations in matrix

The modal abundance of matrix in CM chondrites appears to vary from 57–85 vol%. The concentrations of volatile elements that should occur in matrix remain approximately constant despite differences in the proportions of matrix, suggesting that the differing matrix contents may not be real primary variations but are optical effects due to aqueous alteration processes that make other petrologic components unrecognizable. Apparent matrix content can be used as a qualitative measure of the degree of alteration experienced by each CM chondrite. Fe/Si ratios in matrices decrease progressively with increasing alteration due to the formation of new phyllosilicate phases with higher Mg/Fe ratios and optically recognizable opaque minerals that are not counted as matrix. The aqueous alteration process in CM chondrites appears to have been largely isochemical if the bulk meteorites are considered as the reacting systems, although depletion patterns and isotopic anomalies indicate open-system behavior for a few highly mobile components.     

哈萨克斯坦共和国地震学数据库简介

建立哈萨克斯坦共和国地震学数据库是CASIN国际项目的一部分,应由中亚各国来共同完成。项目主要目的旨在建立地震学数据库,以作为今后减小哈萨克斯坦共和国地震危险性的工作基础。哈萨克斯坦共和国地震学数据库由下列子系统构成:1)文件输入子系统;2)信息检索和提交子系统;3)信息元数据存储子系统;4)档案库运行控制子系统;5)信息安全子系统。哈萨克斯坦共和国地震学数据库有以下功能:1)永久存储综合信息并上报和收集(记录)其他资料;2)存储数据和资料计算;3)电子文档的长期存储和管理;4)规定序号进行信息查询和文件的联机保证;5)信息统计和…     

Intersexes in Mississippi River shovelnose sturgeon sampled below Saint Louis, Missouri, USA.

The Missouri Department of Conservation detected high organochlorine levels in tissues of fish from the Mississippi River south of Saint Louis. Chlordane, which is both a carcinogen and an endocrine disrupter, reached 2960 micrograms/kg in fillets of shovelnose sturgeon, Scaphirhynchus platyorynchus, and 1926 micrograms/kg in their roe, wet weight basis. Polychlorinated biphenyls (PCBs) and p,p'-dichlorodiphenyldichloroethylene (DDE) in roe have reached 5810 and 780 micrograms/kg, respectively. The purpose of this study was to determine if endocrine disrupters and carcinogens are a potential cause of the significantly diminished reproduction capacity and population declines in the endangered pallid sturgeon, Scaphirhynchus albus. Twenty-four surrogate shovelnose sturgeons were sampled north of Saint Louis where contaminant levels were lower compared with 17 sampled south of Saint Louis where contaminant levels were high. Liver and gonad tissues were formalin-fixed, histologically processed and examined. Neoplasms were not found. The principal finding was that the testes of two of the seven downstream male fish contained ovigerous lamellae, in addition to mature sperm. Since sturgeons are gonochoristic and intersexes are rare and unusual, the occurrence of intersex in 29% of the male Mississippi River shovelnose sturgeon examined from a population contaminated with chlordane and other chemicals raise concern for human health, species biodiversity and preservation of waterway quality. These findings, however, need to be corroborated by expanded studies with a higher sample size.     

Parhelia in the planetary boundary layer at newmarket,Ontario: Note

Abstract

Observations of parhelia at Newmarket, Ontario on December 10, 1977 support an earlier suggestion regarding observations made in Toronto on January 22 of the same year. Parhelia were found to occur in the planetary boundary layer (PBL), particularly during the morning hours under blowing snow conditions on clear, cold (ca —17°C) winter days. Thus parhelia which occur in southern Ontario during the winter months can develop in the PBL without the presence of cirrostratus‐type clouds.