Assessment of the acid drainage neutralization capacity and the toxic metals lixiviation of tailing from Guanajuato mining district,Mexico

In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.     

Mapping groundwater recharge potential using GIS approach in Darwha block

Groundwater is the most important source of water in meeting irrigation, drinking, and other needs in India. The assessment of the potential zone for its recharge is critical for sustainable usage, quality management, and food security. This study reports alternative mapping of the groundwater recharge potential of a selected block by including large-scale soil data. Thematic layers of soil, geomorphology, slope, land use land cover, topographical wetness index, and drainage density of Darwha block (District Yavatmal, Maharashtra, India) were generated and integrated in a geographic information system environment. The topographic maps, thematic maps, field data, and satellite image were processed, classified, and weighted using analytical hierarchical process for their contribution to groundwater recharge. The layers were integrated by weighted linear combination method in the GIS environment to generate four groundwater potential zones viz., “poor,” “poor to moderate,” “moderate to high,” and “high.” Based on the generated groundwater potential map, about 9830 ha (12%) of the study area was categorized as high potential for recharge, 25,558 ha (31%) as poor to moderate, 33,398 ha (40%) as moderate to high, and 12,565 ha (15%) as poor potential zone. The zonation corresponds well with the field data on greater well density (0.22/ha) and irrigated crop area (27%) in the high potential zone as against 0.02 wells/ha and only 6% irrigated area in the poor zone. The map is recommended for use in regulating groundwater development decisions and judicious expenditure on drilling new wells by farmers and the state authorities.     

Bi-cylindrical conformal map projection

Novel map projections can be derived by solving one of the two primary problems in mathematical cartography: direct and inverse. The combination of the equations of existing projections is a method that belongs to the direct problem category in mathematical cartography. As projections of different types, different classes, and different aspects can be combined, a considerable number of projections can be obtained by using this method. This paper aims to develop a novel projection by combining two conformal cylindrical projections with different aspects, namely normal and transverse, to reduce the distortions in map projection. It is observed that the resulting projection exhibits less distortion than those in normal and transverse cylindrical projections. Furthermore, the developed projection preserves conformality.     

Accuracy assessment of noise mapping on the main street

Among the sounds constituting a part of our daily lives, the undesired and disturbing ones are named noise. The noises can be defined as the acoustic energy that affects the physiological and psychological welfare of humans due to its direct or indirect effects on the human health. But, the traffic noise, which is one of the disturbing noises having wide dispersion in urban areas, affects the health of a gradually increasing number of people. The number of studies on measurement, dispersion, and mapping of traffic noise in developed and developing countries is gradually increasing. It can be seen that the studies concentrate on mapping based on the city centers and neighborhoods, where the traffic is intense. In this article, unlike the regional noise measurement studies, the transversal cross sections were established with a certain interval according to the land status along the main street, and the noise measurement points were determined using the global navigation satellite system (GNSS). The daily mean noise levels (L_den) were calculated by performing the measurements at daytime, evening, and nighttime. Using ArcGIS 10.4 software, the accuracy of noise maps created via inverse distance weighting (IDW), radial basis function (RBF), and ordinary kriging (OK) geostatistical analysis interpolation methods and the dispersion effect of traffic noise were compared. According to the visual method and error corrections, it was found that the best noise map was obtained using the RBF method. It is believed that the map provides accurate and reliable results because of the flat land surface, higher noise values measured on the road region, decrease in the noise at the points farther from the road region, and soft transitions between the noise values depending on the distance from the road. In order to take measures in order to decrease or eliminate noise on the main street, the local administrators and decision-makers can make use of these maps, the accuracy of which has been confirmed.     

Hydrochemical,isotopic, and reservoir characterization of the Pasinler (Erzurum) geothermal field,eastern Turkey

The reservoir temperature and conceptual model of the Pasinler geothermal area, which is one of the most important geothermal areas in Eastern Anatolia, are determined by considering its hydrogeochemical and isotope properties. The geothermal waters have a temperature of 51 °C in the geothermal wells and are of Na–Cl–HCO₃ type. The isotope contents of geothermal waters indicate that they are of meteoric origin and that they recharge on higher elevations than cold waters. The geothermal waters are of immature water class and their reservoir temperatures are calculated as 122–155 °C, and their cold water mixture rate is calculated as 32%. According to the δ¹³C_VPDB values, the carbon in the geothermal waters originated from the dissolved carbon in the groundwaters and mantle-based CO₂ gases. According to the δ³⁴S_CDT values, the sources of sulfur in the geothermal waters are volcanic sulfur, oil and coal, and limestones. The sources of the major ions (Na⁺, Ca²⁺, Mg²⁺, Cl^?, and HCO₃ ^?) in the geothermal waters are ion exchange and plagioclase and silicate weathering. It is determined that the volcanic rocks in the area have effects on the water chemistry and elements like Zn, Rb, Sr, and Ba originated from the rhyolite, rhyolitic tuff, and basalts. The rare earth element (REE) content of the geothermal waters is low, and according to the normalized REE diagrams, the light REE are getting depleted and heavy REE are getting enriched. The positive Eu and negative Ce anomalies of waters indicate oxygen-rich environments.     

The Starzach site in Southern Germany: a site with naturally occurring CO<Subscript>2</Subscript> emissions recovering from century-long gas mining as a natural analog for a leaking CCS reservoir

In this paper, we present the Starzach site, a region featuring numerous natural CO₂ emission spots, such as mofettes, that reappeared after a longer period of extensive industrial CO₂ mining. We discuss the results of a detailed literature study on the geological setting and the activities related to the gas mining in combination with own measurements to introduce the site as an example on how gas leakage from an insecure CCS reservoir could manifest at the surface. The site is in particular interesting for such investigations as the CO₂ emissions started to replenish after the end of the CO₂ mining and offers the unique possibility to investigate an increase in degassing activity as it might be expected for an active CCS site where leakage is suspected. Based on the geological setting and soil, gas emission, and isotope investigations, we further discuss the source of the CO₂ emission and the gas ascent to the ground surface via deep-reaching faults, latter being so far excluded by previous work. The combination of our extensive literature review and recent field investigations allowed us to draw new geological conclusions for the site that were under discussion for a long time and to give insight into the site’s potential for CCS-related analog studies in the future.     

Porosity and wave velocity evolution of granite after high-temperature treatment: a review

The evolution of porosity and changes in wave velocity in granite after high-temperature treatment has been experimentally investigated in different studies. Statistical analysis of the test results shows that there is a temperature threshold value that leads to variations in porosity and wave velocity. At a temperature that is less than 200 °C, the porosity of granite slowly increases with increases in temperature, while the wave velocity decreases. When the temperature is greater than 200 °C (especially between 400 and 600 °C), the porosity quickly increases, while the wave velocity substantially decreases. The temperature ranges of room temperature to 200 and 200–400 °C correspond to the undamaged state and the micro-damage state, respectively. The results confirm that there is an important link between the variations of physical and mechanical properties in response to thermal treatment. By studying the relationships among rock porosity, wave velocity and temperature, this provides the basis for solving multi-variable coupling problems under high temperatures for the thermal exploitation of petroleum and safe disposal of nuclear waste.     

Biosorption with autochthonous and allochthonous fungal biomasses for bioremediation and detoxification of landfill leachate

Landfill leachates are not adequately treated in traditional wastewater treatment plants, on account of their problematic peculiarities: i.e., dark colour, high concentration of recalcitrant pollutants and COD, and high toxicity. In this work, 19 biomasses (15 autochthonous and 4 allochthonous) were exploited in biosorption treatment for the remediation of a leachate (influent) and the effluent coming from the biological oxidation with activated sludge and nitrification–denitrification treatment. The effects of the initial pH, the biomass amount, and the medium for the biomass pre-culture were considered. The best configuration was: pH 5, 5 g L^??1 biomass cultivated on STY medium. Eventually, the two most effective biomasses, Cunninghamella bertholletiae MUT 2861 and Aspergillus fumigatus MUT 4050, were used in consecutive 2 h cycles in a batch biosorption experiment. The effectiveness of the treatment decreased in subsequent cycles in terms of decolourisation (31–15%). COD, Cl^?, SO₄^2?, total N, and toxicity were removed mainly in the second cycle of treatment (up to ??36, ??12, ??15, ??17 and ??49%, respectively). The results suggest that the effluent toxicity was basically due to uncoloured substances, which were mainly removed after coloured molecules.     

Hydrothermal alteration and evolution of Zr-Th-U-REE mineralization in the microgranite of Wadi Ras Abda,North Eastern Desert,Egypt

Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.