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441.
Toshihiro Suzuki Syun-iti Akimoto Yuh Fukai 《Physics of the Earth and Planetary Interiors》1984,36(2):135-144
The system iron-enstatite-water was investigated at pressures around 5 GPa and at temperatures ranging from 1000 to 1200°C, using several different kinds of starting materials. Quenched samples showed the coexistence of iron, olivine and pyroxene. Synthesis of the Fe-containing olivine in the run products proves that a series of reactions, Fe + H2O → FeHx + FeO and FeO + MgSiO3 → (Mg, Fe)2SiO4, have taken place. Spherical “balls of iron” were observed in the 1200°C run. This strongly indicates that the melting temperature of iron decreased by ~ 500 K by the possible dissolution of hydrogen. Following geophysical implications are derived from these experimental results. If water was retained in the hydrous minerals in the primordial material, the iron-water reaction is expected to occur throughout the core-formation process. The reaction product FeHx will melt and then sink to form a proto-core and iron oxide will be dissolved in the Earth's mantle. The dissolution of hydrogen in the Earth's core is a natural consequence of the core-formation process. 相似文献
442.
The effects of intra-seasonal wind forcing on the mean field of the tropical Pacific Ocean has been studied using an ocean general circulation model (GCM). Idealized intra-seasonal zonal wind forcing with zero mean, which propagates eastward, induces net eastward jets at the equator that shift the warm water pool to the east. The mean temperature of the upper 200 m of the ocean increases off the equator and decreases at the equator. The change is independent of the propagation speed of the intra-seasonal wind forcing. The magnitude of the change depends on the amplitude and the period of the forcing, and the ocean structure, while the spatial pattern is independent of these parameters. A simple shallow water model is used to explain these changes. It is found that the term responsible for the enhanced eastward Equatorial jet is the Reynolds stress term, which arises from a phase shift of the zonal current due to friction. The resultant convergence of eastward momentum on the equator and geostrophic adjustment of the interface to the change of zonal current brings about the thermal redistribution of the upper ocean seen in the GCM. 相似文献
443.
The temperature dependence of carbon isotopic fractionations between calcite and graphite, and between dolomite and graphite are calibrated by the calcite-dolomite solvus geothermometry using marbles collected from the contact metamorphic aureole in the Kasuga area, central Japan. The carbon isotopic fractionations (Δ13CCc-Gr and Δ13CDoGr) systematically decrease with increasing metamorphic temperature. The concordant relationships between the fractionations and solvus temperatures are approximately linear with T?2 over the temperature range. 400° to 680°C: Δ13CCcGr (%.) = 5.6 × 106 × T?2 (K) ? 2.4 Δ13CDoGr (%.) = 5.9 × 106 × T?2 (K) ? 1.9 These systematic relationships between fractionation and temperature suggest that carbon isotopic equilibria between carbonates and graphite were attained in many cases. The equation for the calcite-graphite system has a slope steeper than Bottinga's (1969) results. It is, however, in good agreement with that of Valley and O'Neil (1981) in the temperature range from 600° to 800°C.Because of the relatively high sensitivity to temperature, these isotopic geothermometers are useful for determining the temperatures in moderate- to high-grade metamorphosed carbonate rocks. 相似文献