Redistribution and export of contaminated sediment within eastern Fukushima Prefecture due to typhoon flooding

Tropical cyclones expose river basins to heavy rainfall and flooding, and cause substantial soil erosion and sediment transport. There is heightened interest in the effects of typhoon floods on river basins in northeast Japan, as the migration of radiocaesium‐bearing soils contaminated by the Fukushima Daiichi Nuclear Power Plant (FDNPP) accident will affect future radiation levels. The five main catchments surrounding FDNPP are the Odaka, Ukedo, Maeda, Kuma and Tomioka basins, but little quantitative modelling has been undertaken to identify the sediment redistribution patterns and controlling processes across these basins. Here we address this issue and report catchment‐scale modelling of the five basins using the GETFLOWS simulation code. The three‐dimensional (3D) models of the basins incorporated details of the geology, soil type, land cover, and used data from meteorological records as inputs. The simulation results were checked against field monitoring data for water flow rates, suspended sediment concentrations and accumulated sediment erosion and deposition. The results show that the majority of annual sediment migration in the basins occurs over storm periods, thus making typhoons the main vectors for redistribution. The Ukedo and Tomioka basins are the most important basins in the region in terms of overall sediment transport, followed by the other three basins each with similar discharge amounts. Erosion is strongly correlated with the underlying geology and the surface topography in the study area. A low permeability Pliocene Dainenji formation in the coastal area causes high surface water flow rates and soil erosion. Conversely, erosion is lower in an area with high permeability granite basement rocks between the Hatagawa and Futaba faults in the centre of the study area. Land cover is also a factor controlling differences in erosion and transport rates between forested areas in the west of the study area and predominantly agricultural areas towards the east. The largest sediment depositions occur in the Ogaki and Takigawa Dams, at the confluence of the Takase and Ukedo Rivers, and at the Ukedo River mouth. Having clarified the sediment redistribution patterns and controlling processes, these results can assist the ongoing task of monitoring radioactive caesium redistribution within Fukushima Prefecture, and contribute to the design and implementation of measures to protect health and the environment. Copyright © 2016 John Wiley & Sons, Ltd.     

Particle Size Distribution and Gas-Particle Partition of Polycyclic Aromatic Hydrocarbons in Helsinki Urban Area

Ambient concentrations of polycyclic aromatic hydrocarbons (PAHs) were measured in Helsinki (Finland). Particle mass size distributions were obtained with a cascade impactor (12 stages) with glass fibre filters as substrates. Simultaneously with the impactor measurements, particulate and gaseous PAHs were collected on a quartz filter and XAD-2 adsorbent, respectively, for evaluation of gas-partition coefficients. Samples were analysed for PAHs by on-line coupled supercritical fluid extraction — liquid chromatography — gas chromatography — mass spectrometry. The impactor results showed that most of the PAHs in Helsinki urban area were concentrated in fine particles (<2.5 μm diameter) with unimode peak at about 1 μm. The results were comparable with the number distribution measured with a differential mobility particle sizer. Total amounts of PAHs (gas + particle) varied from 15 (acenaphthylene) to 1990 (fluorene) pg/m³. The PAHs lighter than 202 amu (pyrene and fluoranthene) were exclusively in gas phase, whereas those heavier than 202 amu were mostly associated with particles. A plot of the partition coefficients (logKp) versus the temperature dependent sub-cooled vapour pressures (logp _L ⁰ ) showed a gradient of −0.66, which deviated from equilibrium state (gradient = −1).     

High‐pressure polymorphs in Yamato‐790729 L6 chondrite and their significance for collisional conditions

Shock pressure recorded in Yamato (Y)‐790729, classified as L6 type ordinary chondrite, was evaluated based on high‐pressure polymorph assemblages and cathodoluminescence (CL) spectra of maskelynite. The host‐rock of Y‐790729 consists mainly of olivine, low‐Ca pyroxene, plagioclase, metallic Fe‐Ni, and iron‐sulfide with minor amounts of phosphate and chromite. A shock‐melt vein was observed in the hostrock. Ringwoodite, majorite, akimotoite, lingunite, tuite, and xieite occurred in and around the shock‐melt vein. The shock pressure in the shock‐melt vein is about 14–23 GPa based on the phase equilibrium diagrams of high‐pressure polymorphs. Some plagioclase portions in the host‐rock occurred as maskelynite. Sixteen different CL spectra of maskelynite portions were deconvolved using three assigned emission components (centered at 2.95, 3.26, and 3.88 eV). The intensity of emission component at 2.95 eV was selected as a calibrated barometer to estimate shock pressure, and the results indicate pressures of about 11–19 GPa. The difference in pressure between the shock‐melt vein and host‐rock might suggest heterogeneous shock conditions. Assuming an average shock pressure of 18 GPa, the impact velocity of the parent‐body of Y‐790729 is calculated to be ~1.90 km s^?1. The parent‐body would be at least ~10 km in size based on the incoherent formation mechanism of ringwoodite in Y‐790729.     

Application of Continuous 222Rn Monitor with Dual Loop System in a Small Lake

To estimate the spatial distribution of groundwater discharge from the bottom of a small lake of Kumamoto in Japan, we applied continuous radon measurements with a dual loop system and verified the results obtained using the radon method by visual diving surveys. Time‐shifting correction in the dual‐loop system is reasonable to obtain the true radon activity in water. Distributions of radon activity and water temperature in the study area reveal the effects on groundwater discharge and mixing situation of lake water. The estimated discharge zone ascertained using the radon method agrees with the groundwater discharge distribution observed through diving surveys. Although the data resolution of the radon method is much greater than the width of observed discharge zones, the general distribution of groundwater discharge is recognizable. The dual loop system of radon measurement is useful for smaller areas.     

CaPtO3 as a novel post-perovskite oxide

Structural, morphological, magnetic, and thermal properties have been investigated for a novel post-perovskite oxide CaPtO₃ synthesized under high pressure. By comparing obtained structural parameters with those for known post-perovskite compounds, we argue that the chemical bond has a strong covalent character. Precise measurements of the Langevin susceptibility χ ₀ = −9.6 × 10⁻⁵ emu/mol and Debye temperature θ ∼ 470 K provide a good opportunity to confirm the reliability of first-principle calculations on predicting physical properties of the Earth’s D” layer.     

Rate-dependent strength of porous ice–silica mixtures and its implications for the shape of small to middle-sized icy satellites

Porosity is one of the most important physical properties in the rheology of small icy satellites composed of ice–silicate mixtures. Deformation experiments involving ice and 1 μm silica bead mixtures were conducted to clarify the effect of porosity on the flow law of ice–silica mixtures. Mixtures with silica mass contents of 0, 30, and 50 wt.% were used for the experiments, and the porosity was changed from 0% to 25% in each mixture. The temperature ranged from −10 to −20 °C, and the strain rate was changed from 1.2 × 10⁻⁶ to 4.2 × 10⁻⁴ s⁻¹. As a result, it was found that the ice–silica mixtures deformed plastically, and that the relationship between the maximum stress, σ_max, on the stress–strain curve and the applied strain rate, , could be described by the following flow law: . The mixture became softer as the porosity or silica mass content increased, and the stress exponent n and activation energy Q were independent of porosity, depending only on the silica mass content. Furthermore, the parameter A₀ could be written as A₀ = B(1 − ?)^−α, where ? is the porosity. The constants B and α also depended only on the silica mass content, and they increased with the increase in this content. The Maxwell relaxation time was calculated in order to estimate the conditions for topographic relaxation of icy satellites, and it was found that topographic relaxation occurred at temperatures higher than 160 K in the case of icy satellites with mean radii of 200 km.     

Fe–Mg partitioning between post-perovskite and ferropericlase in the lowermost mantle

Fe–Mg partitioning between post-perovskite and ferropericlase has been studied using a laser-heated diamond anvil cell at pressures up to 154 GPa and 2,010 K which corresponds to the conditions in the lowermost mantle. The composition of the phases in the recovered samples was determined using analytical transmission electron microscopy. Our results reveal that the Fe–Mg partition coefficient between post-perovskite and ferropericlase (K _D^PPv/Fp) increases with decreasing bulk iron content. The compositional dependence of K _D^PPv/Fp on the bulk iron content explains the inconsistency in previous studies, and the effect of the bulk iron content is the most dominant factor compared to other factors, such as temperature and aluminum content. Iron prefers ferropericlase compared to post-perovskite over a wide compositional range, whereas the iron content of post-perovskite (X _Fe^PPv, the mole fraction) does not exceed a value of 0.10. The iron-rich ferropericlase phase may have significant influence on the physical properties, such as the seismic velocity and electrical conductivity at the core–mantle boundary region.     

Experimental study on the collisional disruption of porous gypsum spheres

Abstract— In order to study the catastrophic disruption of porous bodies such as asteroids and planetesimals, we conducted several impact experiments using porous gypsum spheres (porosity: 50%). We investigated the fragment mass and velocity of disrupted gypsum spheres over a wide range of specific energies from 3 times 10³ J/kg to 5 times 10⁴ J/kg. We compared the largest fragment mass (m₁/M_t) and the antipodal velocity (V_a) of gypsum with those of non‐porous materials such as basalt and ice. The results showed that the impact strength of gypsum was notably higher than that of the non‐porous bodies; however, the fragment velocity of gypsum was slower than that of the non‐porous bodies. This was because the micro‐pores dispersed in the gypsum spheres caused a rapid attenuation of shock pressure in them. From these results, we expect that the collisional disruption of porous bodies could be significantly different from that of non‐porous bodies.