Mixing of magmatic CO2 into volcano groundwater flow at Aso volcano assessed combining carbon and water stable isotopes

To understand deep groundwater flow systems and their interaction with CO₂ emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ¹³C_DIC) and DIC concentrations of the sampled waters show that magma-derived CO₂ mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ¹³C_DIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ¹⁸O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ¹³C_DIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO₂ is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO₂ mixes into deeper groundwater flowing nearer the magma conduit or chamber.     

Empirical ocean-color algorithms to retrieve chlorophyll-a, total suspended matter, and colored dissolved organic matter absorption coefficient in the Yellow and East China Seas

A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag₄₄₀). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for T_Chl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (T_Chl2i in case-2 waters), T_TSM (regionally tuned Tassan??s TSM algorithm), and T_ag440 or C_ag440 (regionally tuned Tassan??s or Carder??s ag₄₄₀ algorithm) were able to retrieve Chl-a, TSM, and ag₄₄₀ with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, T_Chl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. T_Chl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified T_Chl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw₅₅₅) > 2 mW cm^?2 ??m^?1 sr^?1 (T_Chl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from T_Chl2s (for case-2 waters) to MOC_Chl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag₄₄₀ using SeaWiFS Rrs, we recommend empirical algorithms for T_TSM (pre-SeaWiFS-modified form) and MT_ag440 or MC_ag440 (SeaWiFS Rrs-modified forms of T_ag440 or C_ag440). These could retrieve with uncertainties as high as 82 and 52%, respectively.     

Is there any seasonal variation in marine nematodes within the sediments of the intertidal zone?

The sediment parameters and nematode assemblages in the intertidal zone of the Hichirippu shallow lagoon, Hokkaido, Japan, were investigated. The objectives of this study were to observe the seasonal variation in the nematodes in the sediment, and to investigate the relationships between the nematodes and environmental factors. Samples were collected bi-monthly from five stations on the tidal flat from April 2003 to February 2004. It was found that the sediment parameters (Chl a concentration, AVS, TOC and TN contents) varied throughout the 10-month study. Fifty-four species of nematodes were found in the study area. The density and biomass of the nematodes varied in accordance with the sediment temperature during the sampling period. In this study, there was a seasonal variation in the nematode assemblage found in the intertidal zone of this shallow lagoon. The important factors affecting this variation were sediment temperature, and food competition among the nematodes themselves. The seasonal variation of the nematode also showed a relationship with the Chl a concentration in the sediment during the sampling period.     

Permo–Triassic Barrovian-type metamorphism in the ultrahigh-temperature Kontum Massif, central Vietnam: Constraints on continental collision tectonics in Southeast Asia

The Kontum Massif in central Vietnam is composed of various metamorphic complexes including a high-temperature southern part (Kannak and Ngoc Linh complexes) and a low- to medium-temperature northern part (Kham Duc complex). The Kham Duc complex exhibits Barrovian-type medium-pressure metamorphism evidenced by kyanite- and/or staurolite-bearing metapelites. The garnet–gedrite–kyanite gneiss, which is the focus of the present study, preserves several mineral parageneses formed during a prograde and retrograde metamorphic history: staurolite + quartz in gedrite, garnet + gedrite + kyanite in the matrix, and spinel + cordierite symplectite between gedrite and sillimanite. The calculated semiquantitative petrogenetic grid reveals peak pressure conditions of 620–650°C at 1.1–1.2 GPa and peak temperature conditions of 730–750°C at 0.7–0.8 GPa. The monazite U–Th–Pb electron microprobe ages of the garnet–gedrite–kyanite gneiss and associated gneisses yield 246 ± 3 Ma for the Kham Duc complex, which is similar to the age of the high- to ultrahigh-temperature metamorphism in the adjacent Kannak and Ngoc Linh complexes of the southern Kontum Massif. The present results indicate that both the Barrovian-type and ultrahigh-temperature metamorphism occurred simultaneously in the Kontum Massif during an event strongly related to Permo–Triassic microcontinental collision tectonics in Asia.     

利用地幔内反射波探测日本列岛下660 km不连续面的深度变化（英文）

通过分析发生在日本周边深源地震的宽频带波形资料,估计了日本列岛下的660km不连续面(d660)的深度变化。许多宽频带波形记录到了在d660顶部发生反射的sScS的后续波。sScS后续波与sScS间的到时差包含了震中与台站下方的d660深度变化的信息。我们成功地检测到这两种震相并将其分离,到目前为止还没有这方面研究的报道。我们由sScS与其后续波的到时差来求每个震中与记录台站下的d660的深度变化。研究结果显示,西部日本下的d660较深(大于660km),这可能是滞留在地幔转换带中的冷的太平洋板块造成的。在日本中部,d660变深,显然这不是太平洋板块本身造成的,因为日本中部已经位于该滞留板片的东部。日本东北部下的d660变得较浅,这可能是太平洋板片形状变化或下地幔热物质上涌形成局部热异常造成的。     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.     

南海大气季节内振荡特征及其与ENSO循环的关系

采用1979—2009年NCEP/NCAR再分析资料、NOAA向外长波辐射(outgoing long-wave radiation,简称OLR)及扩展重建海表面温度资料,对南海大气季节内振荡(Intra-seasonal Oscillation,简称ISO)特征及其与ENSO循环的关系进行了诊断分析。结果表明:1)南海大气ISO的30~60 d周期在5—10月均显著。一般年南海大气ISO的对流传播在纬向上存在东传和西传,在经向上具有南北半球季节性摆动的特征。以低频动能表征的南海大气ISO强度年代际变化特征明显,近31 a来趋势增强,年变化呈单峰结构,峰值在7—8月。2)南海大气ISO的对流与ENSO循环显著相关,其强度在El Nio(La Nia)年减弱(增强)。与一般年对比,南海大气ISO对流在El Nio和La Nia年均表现为西传减弱、北传显著。北传特征表现为强对流活跃带于春季(4—5月)北跳至北半球(在La Nia年最北可至35°N),但在北半球的传播方向与一般年相比存在显著差异。3)南海大气ISO强度与ENSO循环关系密切,在El Nio(La Nia)年减弱(增强),两者表现为约半年(6~8个月)的滞后相关。Nio3区海表面温度异常序列与南海大气ISO强度的相关在中西太平洋地区和El Nio成熟前的春、秋季最显著,同时相关中心伴随低频动能高值区东移。     

与季节内振荡-超级云团系统相关的赤道波的识别

文中重点研究与热带季节内振荡－超级云团系统相关联的赤道波的识别。考虑到赤道波的本质为截获在赤道地区的一般的气候平衡场附近的线性动力过程的固有模态,首先从原理上阐明了ＰＯＰｓ分析技术对于分离各类赤道波动的有效性,以后利用这种分析方法对日本静止气象卫星所观测到的黑体红外辐射温度资料进行了ＰＯＰｓ分析。结果表明,在热带季节内振荡－超级云团系统中,对应于４０ｄ振荡的模态基本表现为Ｋｅｌｖｉｎ波的结构;对应于１０ｄ左右的模态,亦为Ｋｅｌｖｉｎ波,而在２ｄ尺度上,则分别存在经向模态序号ｎ＝１和ｎ＝２的西进和东进惯性重力波。分析中还发现了西进的混合Ｒｏｓｓｂｙ重力波的存在。