Sulfur Isotope Study on Hg and Sb Deposits in Japan

Abstract. Sulfur isotope ratios of cinnabar from Hg deposits and stibnite, jamesonite and berthierite from Sb deposits in Japan are examined in order to understand metallogeneses of Hg and Sb deposits in Japanese island arcs. The studied Hg and Sb deposits include the Hg deposit at Yamato‐suigin (Honshu) and the Sb deposit at Ichinokawa (Shikoku) in the Southwest Japan arc. In addition, Hg deposits including Itomuka and Ryushoden in central Hokkaido and Hg and Sb mineralizations in Northeast Japan arc are examined. The δ³⁴S values of cinnabar from the Hidaka‐Kitami district, central Hokkaido, including the Itomuka and Ryushoden deposits range widely, from ‐10 to +16 %o, the highest values encountered at the Samani deposit. The δ³⁴S values of cinnabar from other areas in Japan range from ‐12 to +5 %o, having δ³⁴S values higher than +2 %o from southwestern Hokkaido (Meiji deposit), Shikoku (Suii deposit) and Kyushu (Hasami and Yamagano deposits). On the other hand, the δ³⁴S values of stibnite from all areas in Japan range from ‐14 to +5 %o, having positive δ³⁴S values higher than +2 %o up to +5 %o from southwestern Hokkaido (Yakumo, Toyotomi and Teine deposits) and eastern‐central Honshu (Hachiman and Daikoku deposits). The variation in δ³⁴S values of Hg and Sb deposits may reflect the variation in δ³⁴S values of country rocks or variation in mixing ratio of sulfur extracted from the country rocks, sulfur derived from seawater sulfate, and sulfur derived from magmatic emanations. The relatively high δ³⁴S values of cinnabar and stibnite higher than +2 %o from southwestern Hokkaido, eastern‐central Honshu and Kyushu are probably caused by contribution of volcanic emanation from arc magmas having positive σδ³⁴S values, whereas the positive δ³⁴S values of cinnabar higher than +2 %o from Suii deposit in Shikoku may be attributed to structurally substituted sulfate in limestone country rocks and/or sulfur derived from seawater sulfate. However, the wide range of the δ³⁴S values of cinnabar from the Hidaka‐Kitami district, central Hokkaido, is difficult to explain at this moment. Other relatively low, negative δ³⁴S values of cinnabar and stibnite, berthierite from other areas in Japan may be attributed to 1) incorporation of isotopically light sedimentary sulfur or sulfur derived from ilmenite‐series silicic magma, or 2) less contribution of volcanic emanation from arc magmas having positive σδ³⁴S values.     

Relationships between Kuroko volcanogenic massive sulfide (VMS) deposits, felsic volcanism, and island arc development in the northeast Honshu arc, Japan

The northeast (NE) Honshu arc was formed by three major volcano-tectonic events resulting from Late Cenozoic orogenic movement: continental margin volcanism (before 21?Ma), seafloor basaltic lava flows and subsequent bimodal volcanism accompanied by back-arc rifting (21 to 14?Ma), and felsic volcanism related to island arc uplift (12 to 2?Ma). Eight petrotectonic domains, parallel to the NE Honshu arc, were formed as a result of the eastward migration of volcanic activity with time. Major Kuroko volcanogenic massive sulfide (VMS) deposits are located within the eastern marginal rift zone (Kuroko rift) that formed in the final period of back-arc rifting (16 to 14?Ma). Volcanic activity in the NE Honshu arc is divided into six volcanic stages. The eruption volumes of volcanic rocks have gradually decreased from 4,600?km³ (per 1?my for a 200-km-long section along the arc) of basaltic lava flows in the back-arc spreading stage to 1,000?C2,000?km³ of bimodal hyaloclastites in the back-arc rift stage, and about 200?km³ of felsic pumice eruptions in the island arc stage. The Kuroko VMS deposits were formed at the time of abrupt decrease in the eruption volume and change in the mode of occurrence of the volcanic rocks during the final period of back-arc rifting. In the area of the Kuroko rift, felsic volcanism changed from aphyric or weakly plagioclase phyric (before 14?Ma), to quartz and plagioclase phyric with minor clinopyroxene (12 to 8?Ma), to hornblende phyric (after 8?Ma), and hornblende and biotite phyric (after 4?Ma). The Kuroko VMS deposits are closely related to the aphyric rhyolitic activity before 14?Ma. The rhyolite was generated at a relatively high temperature from a highly differentiated part of felsic magma seated at a relatively great depth and contains higher Nb, Ce, and Y contents than the post-Kuroko felsic volcanism. The Kuroko VMS deposits were formed within a specific tectonic setting, at a specific period, and associated with a particular volcanism of the arc evolution process. Therefore, detailed study of the evolutional process from rift opening to island arc tectonics is very important for the exploration of Kuroko-type VMS deposits.     

Throughfall partitioning by trees

Although we know that rainfall interception (the rain caught, stored, and evaporated from aboveground vegetative surfaces and ground litter) is affected by rain and throughfall drop size, what was unknown until now is the relative proportion of each throughfall type (free throughfall, splash throughfall, canopy drip) beneath coniferous and broadleaved trees. Based on a multinational data set of >120 million throughfall drops, we found that the type, number, and volume of throughfall drops are different between coniferous and broadleaved tree species, leaf states, and timing within rain events. Compared with leafed broadleaved trees, conifers had a lower percentage of canopy drip (51% vs. 69% with respect to total throughfall volume) and slightly smaller diameter splash throughfall and canopy drip. Canopy drip from leafless broadleaved trees consisted of fewer and smaller diameter drops (D_{50_DR}, 50th cumulative drop volume percentile for canopy drip, of 2.24 mm) than leafed broadleaved trees (D_{50_DR} of 4.32 mm). Canopy drip was much larger in diameter under woody drip points (D_{50_DR} of 5.92 mm) than leafed broadleaved trees. Based on throughfall volume, the percentage of canopy drip was significantly different between conifers, leafed broadleaved trees, leafless broadleaved trees, and woody surface drip points (p ranged from <0.001 to 0.005). These findings are partly attributable to differences in canopy structure and plant surface characteristics between plant functional types and canopy state (leaf, leafless), among other factors. Hence, our results demonstrating the importance of drop‐size‐dependent partitioning between coniferous and broadleaved tree species could be useful to those requiring more detailed information on throughfall fluxes to the forest floor.     

Spiral mode of standing accretion shock instability in core-collapse supernovae

The study of standing accretion shock instability (SASI) in core-collapse supernova cores has been done with three-dimensional (3D) computer simulations. Rotations with various perturbations were introduced from outer boundary of an initial steady accreting flow. We found that one or two armed spiral accreting flow onto the proto-neutron star (PNS) is formed inside the shock wave depending on perturbations. The linear growth of spiral modes are clearly diagnosed by the mode analysis of the shock surface, and the lower m modes grow quickly in the linear regime.     

Evaluation of plastic energy dissipation capacity of steel beams suffering ductile fracture under various loading histories

The energy dissipation capacity of a structure is a very important index that indicates the structural performance in energy‐based seismic design. This index depends greatly on the structural components that form the whole system. Owing to the wide use of the strong‐column weak‐beam strength hierarchy where steel beams dissipate the majority of earthquake input energy to the structures, it is necessary to evaluate the energy dissipation capacity of the beams. Under cyclic loadings such as seismic effects, the damage of the beams accumulates. Therefore, loading history is known to be the most pivotal factor influencing the deformation capacity and energy dissipation capacity of the beams. Seismic loadings with significantly different characteristics are applied to structural beams during different types of earthquakes and there is no unique appropriate loading protocol that can represent all types of seismic loadings. This paper focuses on the effects of various loading histories on the deformation capacity and energy dissipation capacity of the beams. Cyclic loading tests of steel beams were performed. In addition, some experimental results from published tests were also collected to form a database. This database was used to evaluate the energy dissipation capacity of steel beams suffering from ductile fracture under various loading histories. Copyright © 2011 John Wiley & Sons, Ltd.     

Topotaxic relationships between spinel and pyroxene in kelyphite after garnet in mantle-derived peridotites and their implications to reaction mechanism and kinetics

Kelyphite is a reaction product between garnet and olivine, which was formed by subsolidus reactions upon decompression during the ascent of mantle peridotite. We studied crystallographic relationships among constituent (product) phases of kelyphite ?C orthopyroxene, clinopyroxene, spinel and reactant phases, garnet and olivine, using EBSD and found that, for a relatively high temperature sample (from Czech Moldanubian), spinel and pyroxenes are in a topotaxic relationship in such a way that spinel {111} coincides with pyroxene (100) and spinel {110} coincides with pyroxene (010); while the topotaxy is incomplete or non for a lower-temperature sample (from western Norway). On the basis of the observed microstructural and crystallographic relationships, we propose a hypothesis that the topotaxic relationship may be established at nucleation stages of the onset of the kelyphitization and that the degree of topotaxy may be related to the transformation temperature and the degree of supersaturation of the reaction. The lower the temperature, the higher the supersaturation and, therefore, more rapid the nucleation becomes, resulting in a more disordered state in topotaxic relationship.     

A case study of the application of a microcomputer-based favorability evaluation system: Uranium exploration in the Alligator Rivers Uranium Field, Northern Territory, Australia

We have attempted to develop an expert system to evaluate the favorability of uranium exploration projects using the Data-directed Numerical Method (DdM). We developed the system for the Macintosh personal computer, so as to facilitate the iterative processes of trial and error inherent in the DdM. In a detailed case study, we use the above system to evaluate the favorability of the Alligator Rivers Uranium Field, Northern Territory, Australia. The favorability of the target area is evaluated by considering several exploration parameters related to the geological factors controlling ore formation. The selection of appropriate exploration parameters is important to the success of the method. We then selected 15 model cells to validate each exploration parameter and also to design the exploration model by the application of the chi-square test. The result of the favorability evaluation, as displayed by the developed system, indicates that our designed exploration model is acceptable. By employing the above processes we conclude that the system using the DdM is applicable as an exploration tool and is useful in establishing an exploration model.     

Seismic-response-controlled structure with active mass driver system. Part 1: Design

An Active Mass Driver (AMD) system is proposed to suppress actively the response of a building to irregular external excitations such as earthquakes and typhoons. This system has been introduced to an actual ten-storey office building for the first time in the world. The system controls the motions of a structure by means of an external energy supply. It consists of an auxiliary mass installed in a building and an actuator that operates the mass and produces a control force which counters disturbances to the building. The design method of the AMD system, including the location of the installation and the capacity and stability of the system, is proposed. Simplification of the control algorithm is also described.