Thermal alteration experiments on organic matter in recent marine sediment—III. Aliphatic and steroidal alcohols

Recent sediments from Tanner Basin (off southern California) and Bandaras Bay (in Gulf of California) have been analyzed for normal, isoprenoid and steroidal alcohols using chromatographic (column, GLC, TLC), and spectroscopic (u.v., i.r., MS) methods, prior to and after heat-treatment (from 65 to 150°C). Normal saturated alcohols (C₁₄-C₂₄) and monounsaturated alcohols (C₂₂-C₂₄) were identified, as well as the isoprenoid alcohols, phytol and dihydrophytol.Two series of sterols (Δ⁵ and Δ⁷) were found in Tanner Basin, and Δ⁵-sterols and triterpenes, in Bandaras Bay sediment. Sterols from both sediments contained the corresponding stanols.     

Some thermodynamical and microphysical aspects of monsoon clouds

The thermodynamical and microphysical characteristics of monsoon clouds in the Poona, Bombay and Rihand regions were investigated using extensive aircraft in-cloud observations. The number of clouds sampled at Poona, Bombay and Rihand is 2199, 169 and 104 respectively. The temperatures inside the cloud are colder than its environment at Poona and Rihand. The maximum difference is about 3°C at the cloud base level and the difference decreased with height. At Bombay the difference is less than 1°C and at some levels the temperatures inside the cloud are warmer than its environment. The lapse rates of temperatures inside the cloud are slightly less than those in the immediate environment of the cloud. The environmental lapse rates are nearly equal to the saturated adiabatic value. The positive increments in liquid water content (LWC) are associated with the increments in temperature inside the cloud. Similarly positive increments in temperatures inside the cloud are associated with the increments in temperature of its immediate environment at the same level or the layer immediately above. The maximum cloud lengths observed at Poona and Bombay respectively are 14 and 3 km. The horizontal cross-section of LWC showed a maximum number of 13 peaks in clouds at Poona while only 7 peaks were observed at Bombay. The location of maximum LWC in the horizontal cross-section is more or less at the centre of the cloud. The LWC profile showed an increase with height from the base of the cloud at Poona and Bombay. There is no marked variation of LWC with height at Rihand. The total droplet concentration at different altitudes at Poona and Bombay is in the range 28–82 cm^?3. The size distribution of cloud droplets experienced a broadening effect with increase in height from the cloud base at Poona. The broadening effect at Bombay is not as marked as that at Poona.     

Submergence avoidance behavior in the periwinkleLittorina irrorata is not due to threat of drowning

An attempt to establish an LD₅₀ for submergence onLittorina irrorata casts strong doubt on the hypothesis that submergence avoidance behavior is due to the threat of drowning. Predator avoidance is offered as a more plausable hypothesis. Respiration rates of 2.73×10^?3 ml O₂/g body wt./min. for submerged snails and 2.70×10^?2 ml O₂/g body wt./min. for controls were determined.     

Archaeomagnetic investigations in Bulgaria: Field-intensity determinations

Geomagnetic paleointensity determination have been made by the Thellier method using samples from 27 sites in Bulgaria. The samples include bricks, specimens taken from historic kilns, from prehistoric hearths and the sites of ancient fires. The ages of the samples, which range from about 4500 B.C. to the 19th century A.D., have been determined partly by the ¹⁴C method and partly from archaeological evidence. The (residual NMR)-(induced TRM) diagrams tend to be less linear for the prehistoric samples either due to weathering or because the NRM is not a total TRM.     

FT-IR measurements of cold C3H8 cross sections at 7–15 μm for Titan atmosphere

We present absorption cross sections of propane (C₃H₈) at temperatures from 145 K to 297 K in the 690–1550 cm⁻¹ region. Pure and N₂-broadened spectra were measured at pressures from 3 Torr to 742 Torr using a Bruker IFS125 FT-IR spectrometer at JPL. The gas absorption cell, developed at Connecticut College, was cooled by a closed-cycle helium refrigerator. The cross sections were measured and compiled for individual spectra recorded at various experimental conditions covering the planetary atmosphere and Titan. In addition to the cross sections, a propane pseudoline list with a frequency grid of 0.005 cm⁻¹, was fitted to the 34 laboratory spectra. Line intensities and lower state energies were retrieved for each line, assuming a constant width. Validation tests showed that the pseudoline list reproduces discrete absorption features and continuum, the latter contributed by numerous weak and hot band features, in most of the observed spectra within 3%. Based on the pseudoline list, the total intensity in the 690–1550 cm⁻¹ region was determined to be 52.93 (±3%) × 10⁻¹⁹ cm⁻¹/(molecule cm⁻²) at 296 K; this value is within 3% of the average from four earlier studies. Finally, the merit of the pseudoline approach is addressed for heavy polyatomic molecules in support of spectroscopic observation of atmospheres of Titan and other planets. The cold cross sections will be submitted to the HITRAN database (hitran.harvard.edu), and the list of C₃H₈ pseudolines will be available from a MK-IV website of JPL (http://mark4sun.jpl.nasa.gov/data/spec/Pseudo).     

A hybrid artificial neural network-numerical model for ground water problems

Numerical models constitute the most advanced physical-based methods for modeling complex ground water systems. Spatial and/or temporal variability of aquifer parameters, boundary conditions, and initial conditions (for transient simulations) can be assigned across the numerical model domain. While this constitutes a powerful modeling advantage, it also presents the formidable challenge of overcoming parameter uncertainty, which, to date, has not been satisfactorily resolved, inevitably producing model prediction errors. In previous research, artificial neural networks (ANNs), developed with more accessible field data, have achieved excellent predictive accuracy over discrete stress periods at site-specific field locations in complex ground water systems. In an effort to combine the relative advantages of numerical models and ANNs, a new modeling paradigm is presented. The ANN models generate accurate predictions for a limited number of field locations. Appending them to a numerical model produces an overdetermined system of equations, which can be solved using a variety of mathematical techniques, potentially yielding more accurate numerical predictions. Mathematical theory and a simple two-dimensional example are presented to overview relevant mathematical and modeling issues. Two of the three methods for solving the overdetermined system achieved an overall improvement in numerical model accuracy for various levels of synthetic ANN errors using relatively few constrained head values (i.e., cells), which, while demonstrating promise, requires further research. This hybrid approach is not limited to ANN technology; it can be used with other approaches for improving numerical model predictions, such as regression or support vector machines (SVMs).     

Interannual and synoptic-scale features of two types of cold-air outbreaks over the East China Sea during 1988�C2006

For the 1988?C2006 cold seasons, we investigated the characteristic structures of two types of cold-air outbreaks over the East China Sea: Type N, for which a thick layer of northerly meridional wind was formed during the cold-air outbreak; and Type S, for which an initially thin layer of northerly meridional wind was gradually thickened as the cold-air outbreak developed. The emergence frequencies of Type N and Type S outbreaks are sensitive to winter monsoon intensity at the 500-hectopascal (hPa) level. Type S outbreaks are dominant during strong El Ni?o events, leading to enhanced southerly meridional flow at 500?hPa over the East China Sea. The development of the 500-hPa Pacific High strongly influences the synoptic-scale structures of the two different types of outbreaks over the East China Sea.     

Potential protostars in cloud cores

We present H₂CO observations of young protostar candidates in the Serpens Cloud Core. We find evidence for dense molecular gas in the cores of these objects that is warmer than the surrounding dust. The strong emission and gas properties support the premise that many of these sources may be very young protostars.     

Selection and quality assessment of Landsat data for the North American forest dynamics forest history maps of the US

Using the NASA Earth Exchange platform, the North American Forest Dynamics (NAFD) project mapped forest history wall-to-wall, annually for the contiguous US (1986–2010) using the Vegetation Change Tracker algorithm. As with any effort to identify real changes in remotely sensed time-series, data gaps, shifts in seasonality, misregistration, inconsistent radiometry and cloud contamination can be sources of error. We discuss the NAFD image selection and processing stream (NISPS) that was designed to minimize these sources of error. The NISPS image quality assessments highlighted issues with the Landsat archive and metadata including inadequate georegistration, unreliability of the pre-2009 L5 cloud cover assessments algorithm, missing growing-season imagery and paucity of clear views. Assessment maps of Landsat 5–7 image quantities and qualities are presented that offer novel perspectives on the growing-season archive considered for this study. Over 150,000+ Landsat images were considered for the NAFD project. Optimally, one high quality cloud-free image in each year or a total of 12,152 images would be used. However, to accommodate data gaps and cloud/shadow contamination 23,338 images were needed. In 220 specific path-row image years no acceptable images were found resulting in data gaps in the annual national map products.     

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.