全文获取类型
收费全文 | 3400篇 |
免费 | 153篇 |
国内免费 | 46篇 |
专业分类
测绘学 | 104篇 |
大气科学 | 272篇 |
地球物理 | 726篇 |
地质学 | 1314篇 |
海洋学 | 241篇 |
天文学 | 606篇 |
综合类 | 12篇 |
自然地理 | 324篇 |
出版年
2023年 | 14篇 |
2021年 | 40篇 |
2020年 | 62篇 |
2019年 | 81篇 |
2018年 | 88篇 |
2017年 | 100篇 |
2016年 | 117篇 |
2015年 | 101篇 |
2014年 | 122篇 |
2013年 | 176篇 |
2012年 | 117篇 |
2011年 | 171篇 |
2010年 | 150篇 |
2009年 | 202篇 |
2008年 | 174篇 |
2007年 | 169篇 |
2006年 | 157篇 |
2005年 | 137篇 |
2004年 | 133篇 |
2003年 | 101篇 |
2002年 | 95篇 |
2001年 | 67篇 |
2000年 | 68篇 |
1999年 | 59篇 |
1998年 | 53篇 |
1997年 | 56篇 |
1996年 | 54篇 |
1995年 | 42篇 |
1994年 | 28篇 |
1993年 | 31篇 |
1992年 | 27篇 |
1991年 | 41篇 |
1990年 | 23篇 |
1989年 | 26篇 |
1988年 | 31篇 |
1987年 | 37篇 |
1986年 | 23篇 |
1985年 | 30篇 |
1984年 | 27篇 |
1983年 | 18篇 |
1982年 | 27篇 |
1981年 | 31篇 |
1980年 | 28篇 |
1979年 | 17篇 |
1978年 | 15篇 |
1977年 | 20篇 |
1976年 | 18篇 |
1974年 | 26篇 |
1973年 | 21篇 |
1971年 | 14篇 |
排序方式: 共有3599条查询结果,搜索用时 15 毫秒
41.
Martin R. Lee Mark E. Hodson Maureen MacKenzie Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975
Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction. 相似文献
42.
The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2 总被引:2,自引:1,他引:1
Josep M. Soler Marco Boi Jos Luis Mogolln Jordi Cama Carlos Ayora Peter S. Nico Nobumichi Tamura Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions. 相似文献
43.
Mineralogical sources of the buffer capacity in a granite catchment determined by strontium isotopes
Christina Weyer Gunnar Lischeid Luc Aquilina Anne-Catherine Pierson-Wickmann Charlotte Martin 《Applied Geochemistry》2008
The role of different minerals in base cation release and thus the increase of buffering capacity of groundwater against acid deposition is controversially discussed in the literature. The 87Sr/86Sr ratios and base cation concentration were investigated in whole rock leachates, mineral separates, precipitation, soil solution, groundwater and stream water samples in the Lehstenbach catchment (Germany) to identify the weathering sequence of the granite bedrock. Three different approaches were followed in parallel. It was assumed that the contribution of different minerals to base cation supply of the groundwater with increasing weathering intensity would be observed by investigating (1) unweathered rock leachates, deep groundwater and shallow groundwater, (2) groundwater samples from new groundwater wells, reflecting the initial weathering of the drilled bedrock, and groundwater from wells that were drilled in 1988, (3) stream water during baseflow, dominated by deep groundwater, and stream water during high flow, being predominantly shallow groundwater. Whereas the first approach yielded consistent patterns, there was some evidence that groundwater from the new wells initially reflected contamination by the filter gravel rather than cation release in an initial stage of weathering. Time series samples of stream water and groundwater solute concentrations and isotope ratios turned out to reflect varying fractions of soil water and precipitation water at baseflow and high flow conditions rather than varying contributions of different minerals that prevail at different stages of granite weathering. 相似文献
44.
G. Diego Gatta Nicola Rotiroti Martin Fisch Milen Kadiyski Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes. 相似文献
45.
Control strategies for the Clam Wave Energy Device 总被引:1,自引:0,他引:1
A promising wave energy device being currently investigated is the ‘clam’. The clam extracts energy by pumping air through a specially designed (Wells) turbine. Although operation of the Wells turbine does not require a rectified air flow, some additional control will be necessary to optimize the phase of the clam motion for good efficiencies. An examination of the equation of motion in the time domain suggests the possibility of phase control by mechanical, power take-off, or pneumatic latching. Latching can be shown to increase the efficiency of the device in the longer wavelengths of the wave spectrum, i.e. those of high incident wave power. Equivalently latching could be used to keep the device efficiency high while reducing its size, possibly resulting in cheaper power extraction. 相似文献
46.
47.
A coding error in the s-Coordinate Primitive Equation Model (SPEM) has led to misleading statements about the behaviour of the Mellor–Yamada level 2 parameterization of vertical mixing. It has been claimed that the scheme removes static instability only very slowly and preserves statically unstable stratifications for an unrealistic long time. This note corrects this statement by demonstrating that the Mellor–Yamada mixing scheme, if implemented correctly, tends to overestimate rather than underestimate vertical mixing in seasonally ice-covered seas. Similar to other mixing schemes with the same behaviour, this leads to spurious open ocean deep convection, an unrealistic homogenization of the water column, and a significant reduction of sea ice volume. 相似文献
48.
Despite the severity of tropical cyclone ‘Winifred’, which crossed the Great Barrier Reef on 1 February 1986, there were little long-term effects on lagoon surface sediments from reefs in its path. Short-term effects were apparent only at one particularly exposed area. These were: an increase in proportion of the coarse fraction, the establishment of sand ripples, and the destruction of the mounds produced by callianassid shrimps (normally the dominant topographic feature). Within six weeks this area was indistinguishable from a typical reef lagoon. This is probably the result of sediment reworking by callianassid shrimp, involving selective burial of the coarse fragments and transport to the surface of finer particles. Sediment turnover rates by callianassids are commensurate with change to the sediment within the relatively short period observed. The sediment fauna responded quickly to the changes in sediment type. Immediately after the cyclone the disturbed area supported a fauna typical of the coarse sediments on the shallow reef flat, as the sediment reverted to a more normal type so the fauna changed back to that typical of a reef lagoon. 相似文献
49.
The Central Trough of the North Sea is not a simple rift graben. It is an elongated area of regional subsidence which was initiated in mid Cretaceous times and continued to subside through to the late Tertiary. Its form is not representative of pre-mid Cretaceous tectonics.In Late Permian times the North Sea was divided into a northern and southern Zechstein basin by the E-W trending Mid North Sea-Ringkøbing-Fyn High. The latter was dissected by a narrow graben trending NNW through the Tail End Graben and the Søgne Basin. The Feda Graben was a minor basin on the northern flank of the Mid North Sea High at this time. This structural configuration persisted until end Middle Jurassic times when a new WNW trend separated the Tail End Graben from the Søgne Basin. Right lateral wrench movement on this new trend caused excessive subsudence in the Tail End and Feda Grabens while the Søgne Basin became inactive.Upper Jurassic subsidence trends continued during the Early Cretaceous causing the deposition of large thicknesses of sediments in local areas along the trend. From mid Cretaceous times the regional subsidence of the Central Trough was dominant but significant structural inversions occurred in those areas of maximum Early Cretaceous and Late Jurassic subsidence. 相似文献
50.