Spheroidal pyroxenite aggregates in the Bushveld Complex — a special case of silicate liquid immiscibility

Spherical aggregates of orthopyroxene are reported from some parts of the Bushveld Complex in a variety of host rocks.Detailed mapping has shown that these spherical aggregates, comprising pyroxenite spheroids in a quartz-norite matrix, are contact phenomena and not stratigraphic markers. Orthopyroxene, biotite and amphibole are enriched in spheroids relative to matrix; their mineral chemistry showing a fairly constant orthopyroxene and plagioclase composition through the spheroids and into the matrix, indicating in-situ formation.Bulk chemistry shows spheroid to matrix tie-lines orthogonal to those generally accepted for silicate liquid immiscibility, but other chemical information is consistent with the occurrence of immiscibility.The formation of the aggregates may be related to the industrial process of spherical agglomeration, by which spheroids are formed by the introduction of an immiscible “bridging liquid” to the melt — probably derived from the floor rocks in this case. The mechanism accounts for the field relationships, petrography and chemistry of the aggregate-matrix system. The petrology of the process equates with a special case of silicate liquid immiscibility induced by local contamination and ageing of the original magma.A similar “bridging liquid” mechanism could also account for the formation of the so-called “boulder bed” beneath the Merensky Reef.     

Rockfall susceptibility and runout in the Valley of the Kings

Natural Hazards - The UNESCO world heritage site Valley of the Kings or Wadi el-Moluk (???? ??????) near Luxor, Egypt, hosts unique...     

Behaviour of radiogenic Pb in zircon during ultrahigh-temperature metamorphism: an ion imaging and ion tomography case study from the Kerala Khondalite Belt,southern India

Zircon crystals from a locally charnockitized Paleoproterozoic high-K metagranite from the Kerala Khondalite Belt (KKB) of southern India have been investigated by high-spatial resolution secondary ion mass spectrometry analysis of U–Th–Pb and rare earth elements (REE), together with scanning ion imaging and scanning ion tomography (depth-profiled ion imaging). The spot analyses constrain the magmatic crystallization age of the metagranite to ca. 1,850 Ma, with ultrahigh-temperature (UHT) metamorphism occurring at ca. 570 Ma and superimposed charnockite formation at ca. 520–510 Ma, while the ion imaging reveals a patchy distribution of radiogenic Pb throughout the zircon cores. Middle- to heavy-REE depletion in ca. 570 Ma zircon rims suggests that these grew in equilibrium with garnet and therefore date the UHT metamorphism in the KKB. The maximum apparent ²⁰⁷Pb/²⁰⁶Pb age obtained from the unsupported radiogenic Pb concentrations is also consistent with formation of the Pb patches during this event. The superimposed charnockitization event appears to have caused additional Pb-loss in the cores and recrystallization of the rims. The results of depth-profiling of the scanning ion tomography image stack show that the Pb-rich domains range in size from <5 nm to several 10 nm (diameter if assumed to be spherical). The occurrence of such patchy Pb has previously been documented only from UHT metamorphic zircon, where it likely results from annealing of radiation-damaged zircon. The formation of a discrete, heterogeneously distributed and subsequently immobile Pb phase effectively arrests the normal Pb-loss process seen at lower grades of metamorphism.     

Street-scale storm surge load impact assessment using fine-resolution numerical modelling: a case study from Nemuro,Japan

Natural Hazards - Due to gradual sea level rise and changes in the climate system, coastal vulnerability to storm surge hazards is expected to increase in some areas. Studies regarding the effect...     

Deep-sea hydrocarbon seep gastropod Bathynerita naticoidea responds to cues from the habitat-providing mussel Bathymodiolus childressi

Bathynerita naticoidea (Gastropoda: Neritidae) is a numerically dominant heterotrophic gastropod found at hydrocarbon seep sites on the upper Louisiana slope of the Gulf of Mexico. Snails of this species are commonly associated with beds of the methanotrophic mussel Bathymodiolus childressi (Bivalvia: Mytilidae), and their population structure mirrors that of the mussels they are found among. Previous studies have shown that these snails feed on bacteria and decomposing periostracum on the B. childressi shell. We predicted that B. naticoidea might be attracted to cues specific to its preferred habitat, such as dissolved methane, mucus from conspecific snails, or metabolites produced by B. childressi mussels. To examine this, we used a flow‐through Y‐maze system to investigate the behavior of B. naticoidea exposed to these potential cues. We found that the nerite is not attracted to methane, but is strongly attracted to seawater conditioned with B. childressi. The attractant appears to be specific to this type of mussel, and is not a soluble cue produced by conspecific snails.     

Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran

In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential.     

Evidence for microbiological manganese oxidation in the river Tamar Estuary, South West England

Water samples from the Tamar Estuary oxidized manganese when supplemented with Mn²⁺ (2 mgl⁻¹). The rates of oxidation were depressed in the presence of various metabolic inhibitors. The effect of Mn²⁺ and temperature on the rate of manganese oxidation suggested that a biological process was largely responsible for converting Mn²⁺ to Mn⁴⁺. Rates of manganese oxidation were much higher in freshwater (3·32 μgl⁻¹ h⁻¹ in water containing 30 mgl⁻¹ of suspended matter) than in saline water (0·7 μgl⁻¹ h⁻¹ in water of salinity 32‰) containing the same amount of particulate matter. The rate of manganese oxidation was proportional to the particulate load (up to 100 mgl⁻¹ particulates).