Petrophysical and geochemical constraints on alteration processes in granites

The hydrothermal alteration of granites has large influence on their petrophysical properties. To reveal the impact of alteration on magnetic and porosity properties of granites we have conducted a complex study of effects of two largely independent alteration processes, related to chemically different fluids, in granites of the Vysoký Kámen stock (the Krudum granite body, Czech Republic). It includes the whole-rock geochemical, magnetic and pore-space characterization. The alkali feldspathization resulted in decomposition of Li-mica, quartz removal, depletion in mafic cations and growth of new alkali feldspars (albite, K-feldspar), decreasing the overall magnetic susceptibility and disrupting the pore space by its discontinuation. The preservation of the orientation of the principal susceptibility axes is likely related to insignificant influence of the feldspathization process on the paramagnetic and diamagnetic phases orientation acquired during the magma emplacement. The greisenization, on the other hand had considerably more significant effects on microstructure and physical properties of the granite. The microstructure was modified by the growth of large amounts of new phases (Li-mica, quartz and topaz). This changed the mineral density of the rock, the porosity, size and character of pores to larger, flatter and probably more connected. This led also to the complete reworking of the original anisotropy of magnetic susceptibility during the greisenization.     

Effects of CO2 on benthic biota: An in situ benthic chamber experiment in Storfjorden (Norway)

Carbon capture and storage (CCS) methods, either sub-seabed or in ocean depths, introduces risk of CO₂ leakage and subsequent interaction with the ecosystem. It is therefore important to obtain information on possible effects of CO₂. In situ CO₂ exposure experiments were carried out twice for 10 days during 2005 using a Benthic Chamber system at 400 m depth in Storfjorden, Norway. pCO₂ in the water above the sediment in the chambers was controlled at approximately 500, 5000 and 20,000 μatm, respectively. This article describes the experiment and the results from measured the biological responses within the chamber sediments. The results show effects of elevated CO₂ concentrations on biological processes such as increased nanobenthos density. Methane production and sulphate reduction was enhanced in the approximately 5000 μatm chamber.     

SLOPE EVOLUTION ON ABANDONED SPOIL BANKS IN EASTERN OKLAHOMA

Unreclaimed strip mine dumps near Henryetta, Oklahoma were employed as a natural laboratory for the study of slope evolution. These dumps were created by similar technologies and from similar materials but at different times. Modern, 30-year-old and 60-year-old slopes were compared through morphometric analysis and by the direct measurement of current rates of denudation. Slope evolution may be generalized as slope decline. This was effected through reduction of the slope crest, burial of the slope foot, and extension of the upper convexity and lower concavity at the expense of the rectilinear main slope of the original mine dump. There was a progressive reduction in rates of surface erosion, and the balance between weathering and suffosion became skewed towards the latter on the oldest dumps.     

Direct dating of thick‐ and thin‐skin thrusts in the Peruvian Subandean zone through apatite (U–Th)/He and fission track thermochronometry

Although the structure of the central Peruvian Subandean zone is well defined, the timing of thrust‐related exhumation and Cenozoic sedimentation remain poorly constrained. In this study, we report new apatite (U–Th)/He (AHe) and fission track (AFT) ages from thrust‐belt and foreland strata along three published balanced cross sections. AHe data from the northern, thick‐skinned domain (i.e. Shira Mountain, Otishi Cordillera and Ucayali Basin) show young AHe ages (ranging from 2.6 ± 0.2 to 13.1 ± 0.8 Ma) compared with AFT ages (ranging from 101 ± 5 to 133 ± 11 Ma). In the southern Camisea Basin, where deformation is mainly thin‐skinned, AHe and AFT ages have been both reset and show young cooling ages (3.7 ± 0.8 Ma and 8 ± 2 Ma respectively). Using low‐temperature thermochronology data and the latest fission track annealing and He diffusion codes, the thermal history of the study area has been reconstructed using inverse modelling. This history includes two steps of erosion: Early Cretaceous and late Neogene, but only Neogene sedimentation and exhumation varies in the different sectors of the study area. From a methodological point of view, large AHe data dispersion point to the need for refinement of AHe damage and annealing models. The influence of grain chemistry on damage annealing, multiple age components and the possibility of fission tracks as traps for He need further consideration. For the central Peruvian Subandes, AHe and AFT ages combined with balanced cross sections emphasize the dominant control of Paleozoic inheritance rather than climate on Cenozoic infilling and exhumation histories. Finally, our data provide the first field example of how thick‐skinned thrust‐related deformation and exhumation in the Subandes can be directly dated through AHe thermochronology.     

Impact of fire on long-term vegetation dynamics of ombrotrophic peatlands in northwestern Québec,Canada

A 7000-year record of local fire history was reconstructed from three ombrotrophic peatlands in the James Bay lowlands (northwestern Québec, Canada) using a high-resolution analysis of macroscopic charcoal (long axis ≥ 0.5 mm). The impact of fire on vegetation changes was evaluated using detailed analysis of plant macrofossils. Compared to upland boreal forest, fire incidence in these Sphagnum-dominated bogs is rather low. Past fire occurrence seems to have been controlled primarily by internal processes associated with local hydroseral succession. Size of the peatland basin and distance from the well-drained forest soils also appear to be factors controlling fire occurrence. The impact of peatland fires on long-term vegetation succession appears negligible except in a forested bog, where it initiated the replacement of Sphagnum by mosses. In some circumstances, fire caused marked changes in the bryophyte assemblages over many decades. However, ombrotrophic peatland vegetation is generally resilient to surface fire.     

A protoceratopsid skeleton with an associated track from the Upper Cretaceous of Mongolia

The Djadokhta Formation of the Gobi Desert is known for the number and diversity of dinosaur and other vertebrate bones and skeletons found there, but only theropod, hadrosaur and supposed ankylosaurid footprints have been reported from this stratum. Dinosaur footprints are also noted from the Nemegt Formation, and occur as typical dinosaur track accumulations (tracksites). An articulated protoceratopsid skeleton - specimen ZPAL Mg D-II/3 - was collected by the Polish-Mongolian Expedition of 1965 from the Djadokhta Formation of Flaming Cliffs in Mongolia. Recently, the natural cast of a tetradactyl digitigrade footprint was found underneath the pelvic girdle while the skeleton and matrix were being prepared. This is possibly the first find of a dinosaur track in close association with an articulated skeleton. Although Protoceratops is an extremely common dinosaur in Mongolia, its footprints have never previously been reported from the Late Cretaceous of the Gobi Desert.     

Arsenic and antimony contamination of waters,stream sediments and soils in the vicinity of abandoned antimony mines in the Western Carpathians,Slovakia

Environmental contamination with As and Sb caused by past mining activities at Sb mines is a significant problem in Slovakia. This study is focused on the environmental effects of the 5 abandoned Sb mines on water, stream sediment and soil since the mines are situated in the close vicinity of residential areas. Samples of mine wastes, various types of waters, stream sediments, soils, and leachates of the mine wastes, stream sediments and selected soils were analyzed for As and Sb to evaluate their geochemical dispersion from the mines. Mine wastes collected at the mine sites contained up to 5166 mg/kg As and 9861 mg/kg Sb. Arsenic in mine wastes was associated mostly with Fe oxides, whereas Sb was present frequently in the form of individual Sb, Sb(Fe) and Fe(Sb) oxides. Waters of different types such as groundwater, surface waters and mine waters, all contained elevated concentrations of As and Sb, reaching up to 2150 μg/L As and 9300 μg/L Sb, and had circum-neutral pH values because of the buffering capacity of abundant Ca- and Mg-carbonates. The concentrations of Sb in several household wells are a cause for concern, exceeding the Sb drinking water limit of 5 μg/L by as much as 25 times. Some attenuation of the As and Sb concentrations in mine and impoundment waters was expected because of the deposition of metalloids onto hydrous ferric oxides built up below adit entrances and impoundment discharges. These HFOs contained >20 wt.% As and 1.5 wt.% Sb. Stream sediments and soils have also been contaminated by As and Sb with the peak concentrations generally found near open adits and mine wastes. In addition to the discharged waters from open adits, the significant source of As and Sb contamination are waste-rock dumps and tailings impoundments. Leachates from mine wastes contained as much as 8400 μg/L As and 4060 μg/L Sb, suggesting that the mine wastes would have a great potential to contaminate the downstream environment. Moreover, the results of water leaching tests showed that Sb was released from the solids more efficiently than As under oxidizing conditions. This might partly explain the predominance of Sb over As in most water samples.     

Evaluation of Methods for Determining Crack Initiation in Compression Tests on Low-Porosity Rocks

Laboratory testing of rocks is traditionally carried out to determine the peak strength using the ISRM Suggested Methods or other suitable standards. However, it is well known that in low-porosity crystalline rocks there are at least three distinct stages of compressive loading that can be readily identified if the stress–strain response is monitored during the loading process: (1) crack initiation, (2) unstable crack growth, i.e., crack coalescence and (3) peak strength. Crack initiation is noted as the first stage of stress-induced damage in low-porosity rocks, yet the suggested guidelines of the ISRM for compression tests make no mention of crack initiation. In addition, recent research suggests that crack initiation can be used as an estimate for the in situ spalling strength, commonly observed around underground excavations in massive to moderately jointed brittle rocks. Various methods have been proposed for identifying crack initiation in laboratory tests. These methods are evaluated using ten samples of ?sp? Diorite and the results are compared with a simplified method, lateral strain response. Statistically, all methods give acceptable crack-initiation values. It is proposed that the ISRM Suggested Methods be revised to include procedures suitable for establishing the crack-initiation stress.     

Pharmaceuticals as indictors of sewage-influenced groundwater

A set of human pharmaceuticals enables identification of groundwater that is influenced by sewage and provides information on the time of recharge. As the consumption rates of the investigated pharmaceuticals have changed over time, so too has the composition of the sewage. At the study area, south of Berlin (Germany), irrigation was performed as a method of wastewater clean-up at sewage irrigation farms until the early 1990s. Today, treated wastewater is discharged into the surface-water-stream Nuthegraben. Groundwater and surface-water samples were analyzed for the pharmaceutical substances clofibric acid, bezafibrate, diclofenac, carbamazepine and primidone, the main ions and organic carbon. The pharmaceutical substances were detected at concentrations up to microgram-per-liter level in groundwater and surface-water samples from the Nuthegraben Lowland area and from the former irrigation farms. Concentrations detected in groundwater are generally much lower than in surface water and there is significant variation in the distribution of pharmaceutical concentrations in groundwater. Groundwater influenced by the irrigation of sewage water shows higher primidone and clofibric-acid concentrations. Groundwater influenced by recent discharge of treated sewage water into the surface water shows high carbamazepine concentrations while concentrations of primidone and clofibric acid are low.     

Deciphering the Variscan tectonothermal overprint and deformation partitioning in the Cadomian basement of the Teplá–Barrandian unit, Bohemian Massif

The Teplá–Barrandian unit (TBU) has long been considered as a simply bivergent supracrustal ‘median massif’ above the Saxothuringian subduction zone in the Variscan orogenic belt. This contribution reveals a much more complex style of the Variscan tectonometamorphic overprint and resulting architecture of the Neoproterozoic basement of the TBU. For the first time, we describe the crustal-scale NE–SW-trending dextral transpressional Krakovec shear zone (KSZ) that intersects the TBU and thrusts its higher grade northwestern portion severely reworked by Variscan deformation over a southeastern very low grade portion with well-preserved Cadomian structures and only brittle Variscan deformation. The age of movements along the KSZ is inferred as Late Devonian (~380–370?Ma). On the basis of structural, microstructural, and anisotropy of magnetic susceptibility data from the KSZ, we propose a new synthetic model for the deformation partitioning in the Teplá–Barrandian upper crust in response to the Late Devonian to early Carboniferous subduction and underthrusting of the Saxothuringan lithosphere. We conclude that the Saxothuringian/Teplá–Barrandian convergence was nearly frontal during ~380–346?Ma and was partitioned into pure shear dominated domains that accommodated orogen-perpendicular shortening alternating with orogen-parallel high-strain domains that accommodated dextral transpression or bilateral extrusion. The synconvergent shortening of the TBU was terminated by a rapid gravity-driven collapse of the thickened lithosphere at ~346–337?Ma followed by, or partly simultaneous with, dextral strike-slip along the Baltica margin-parallel zones, driven by the westward movement of Gondwana from approximately 345?Ma onwards.