Geomorphic controls on mercury accumulation in soils from a historically mined watershed, Central California Coast Range, USA

Historic Hg mining in the Cache Creek watershed in the Central California Coast Range has contributed to the downstream transport of Hg to the San Francisco Bay-Delta. Different aspects of Hg mobilization in soils, including pedogenesis, fluvial redistribution of sediment, volatilization and eolian transport were considered. The greatest soil concentrations (>30 mg Hg kg⁻¹) in Cache Creek are associated with mineralized serpentinite, the host rock for Hg deposits. Upland soils with non-mineralized serpentine and sedimentary parent material also had elevated concentrations (0.9–3.7 mg Hg kg⁻¹) relative to the average concentration in the region and throughout the conterminous United States (0.06 mg kg⁻¹). Erosion of soil and destabilized rock and mobilization of tailings and calcines into surrounding streams have contributed to Hg-rich alluvial soil forming in wetlands and floodplains. The concentration of Hg in floodplain sediment shows sediment dispersion from low-order catchments (5.6–9.6 mg Hg kg⁻¹ in Sulphur Creek; 0.5–61 mg Hg kg⁻¹ in Davis Creek) to Cache Creek (0.1–0.4 mg Hg kg⁻¹). These sediments, deposited onto the floodplain during high-flow storm events, yield elevated Hg concentrations (0.2–55 mg Hg kg⁻¹) in alluvial soils in upland watersheds. Alluvial soils within the Cache Creek watershed accumulate Hg from upstream mining areas, with concentrations between 0.06 and 0.22 mg Hg kg⁻¹ measured in soils 90 km downstream from Hg mining areas. Alluvial soils have accumulated Hg released through historic mining activities, remobilizing this Hg to streams as the soils erode.     

Weathering of the New Albany Shale, Kentucky: II. Redistribution of minor and trace elements

During weathering, elements enriched in black shale are dispersed in the environment by aqueous and mechanical transport. Here a unique evaluation of the differential release, transport, and fate of Fe and 15 trace elements during progressive weathering of the Devonian New Albany Shale in Kentucky is presented. Results of chemical analyses along a weathering profile (unweathered through progressively weathered shale to soil) describe the chemically distinct pathways of the trace elements and the rate that elements are transferred into the broader, local environment. Trace elements enriched in the unweathered shale are in massive or framboidal pyrite, minor sphalerite, CuS and NiS phases, organic matter and clay minerals. These phases are subject to varying degrees and rates of alteration along the profile. Cadmium, Co, Mn, Ni, and Zn are removed from weathered shale during sulfide-mineral oxidation and transported primarily in aqueous solution. The aqueous fluxes for these trace elements range from 0.1 g/ha/a (Cd) to 44 g/ha/a (Mn). When hydrologic and climatic conditions are favorable, solutions seep to surface exposures, evaporate, and form Fe-sulfate efflorescent salts rich in these elements. Elements that remain dissolved in the low pH (<4) streams and groundwater draining New Albany Shale watersheds become fixed by reactions that increase pH. Neutralization of the weathering solution in local streams results in elements being adsorbed and precipitated onto sediment surfaces, resulting in trace element anomalies.Other elements are strongly adsorbed or structurally bound to solid phases during weathering. Copper and U initially are concentrated in weathering solutions, but become fixed to modern plant litter in soil formed on New Albany Shale. Molybdenum, Pb, Sb, and Se are released from sulfide minerals and organic matter by oxidation and accumulate in Fe-oxyhydroxide clay coatings that concentrate in surface soil during illuviation. Chromium, Ti, and V are strongly correlated with clay abundance and considered to be in the structure of illitic clay. Illite undergoes minimal alteration during weathering and is concentrated during illuvial processes. Arsenic concentration increases across the weathering profile and is associated with the succession of secondary Fe(III) minerals that form with progressive weathering. Detrital fluxes of particle-bound trace elements range from 0.1 g/ha/a (Sb) to 8 g/ha/a (Mo). Although many of the elements are concentrated in the stream sediments, changes in pH and redox conditions along the sediment transport path could facilitate their release for aqueous transport.     

Cretaceous metamorphism in the Austroalpine Matsch Unit (Eastern Alps): The interrelation between deformation and chemical equilibration processes

In the polymetamorphic Austroalpine Matsch Unit (European Eastern Alps) Cretaceous upper greenschist facies metamorphism overprinted Variscan and Permian magmatic and metamorphic assemblages. Mineral compositional and (micro-)structural data of metapelites and metapegmatites document different mechanisms of interrelated deformation and (re-)equilibration during Cretaceous overprinting: i) Microfractures in relic garnet represented pathways for material transport, and thus established material exchange between intragranular domains and the matrix. Major element equilibration by fast diffusion along microfractures contrasts with limited volume diffusion in adjacent host garnet. ii) Syn-tectonic breakdown of staurolite initially to paragonite, then chloritoid allows correlating reaction progress with the formation of different fracture sets. iii) Syn-tectonic mineral growth with shape-preferred orientation in foliation domains contrasts with radial growth in microlithons and strain shadows of the mylonitic foliation. iv) Syn-tectonic unmixing of pre-existing oligoclase (an_14–16) produced fine-grained aggregates of two supposedly coexisting plagioclase-phases (an_3–6 and an_20–25) in strain shadows of the oligoclase-clasts. v) Pre-existing deformation-induced heterogeneities in the spatial distribution of phases and their preferred orientation influence the kinetics of phase equilibration. Understanding the mechanisms of the mutual interrelation between deformation and phase equilibration is a prerequisite for deducing PT-constraints from strained metamorphic rocks. New garnet—whole rock Sm-Nd data from metapegmatites indicate their emplacement at 263–280 Ma and provide an important age constraint on the interrelated deformation and re-equilibration processes.     

Rock displacement and thermal expansion study at historic heritage sites in Slovakia

The paper discusses the results of the research devoted to the preservation of cultural heritage carried out within last two decades in Slovakia. The aim of the study depended on monitoring of selected castle rocks showing instability problems due to extremely slow displacements of creep character. Apart from traditional methods of investigation at one test site (Spis Castle), authors implemented in their work the study of thermal expansion of the rocks as a result of seasonal periodic temperature changes having potential influence on displacements and numerical modeling in order to understand better the landslide failure mechanism. The results obtained from all study sites confirmed that even slow movements have to be implemented into preservation and stabilization works in order to safeguard the sites of great historic value.     

Liquefaction mitigation in silty soils using composite stone columns and dynamic compaction

The objective of this study is to develop an analytical methodology to evaluate the effectiveness ofvibro stone column (S. C.) and dynamic compaction (D.C.) techniques supplemented with wick drains to densify and mitigate liquethctionin saturated sands and non-plastic silty soils. It includes the following: (i) develop numerical models to simulate and analyze soil densification during S.C. installation and D.C. process, and (ii) identify parameters controlling post-improvement soil density in both cases, and (iii) develop design guidelines for densification of silty soils using the above techniques. An analytical procedure was developed and used to simulate soil response during S.C. and D.C. installations, and the results were compared with available case history data. Important construction design parameters and soil properties that affect the effectiveness of these techniques, and construction design choices suitable for sands and non-plastic silty soils were identified. The methodology is expected to advance the use of S.C. and DC. in silty soils reducing the reliance on expensive field trials as a design tool. The ultimate outcome of this research will be design charts and design guidelines for using composite stone columns and composite dynamic compaction techniques in liquefaction mitigation of saturated silty soils.     

Planetary core size: A seismological approach

A key parameter for understanding the geodynamics of a terrestrial planet is the size of its core. Numerical evaluation of 28 different interior structure models of Mercury, Venus, Earth, the Moon, and Mars suggests that there is an almost linear relationship between the core radius and the extent of the seismic P-wave core shadow. A scaling law is derived from a simple mantle density and velocity model that permits the interpretation of respective seismic measurements on terrestrial planetary bodies.     

Accurate GPS measurement of the location and orientation of a floating platform

Abstract

This article describes the design and initial tests of the GPS portion of a system for making seafloor geodesy measurements. In the planned system, GPS antennas on a floating platform will be used to measure the location of an acoustic transducer, attached below the platform, which interrogates an array of transponders on the seafloor. Since the GPS antennas are necessarily some distance above the transducer, a short‐baseline GPS interferometer consisting of three antennas is used to measure the platform's orientation.

A preliminary test of several crucial elements of the system was performed at the Scripps Institution of Oceanography (SIO) in December 1989. The test involved a fixed antenna on the pier and a second antenna floating on a buoy about 80 m away. GPS measurements of the vertical component of this baseline, analyzed independently by two groups using different software, agree with each other and with an independent measurement within a centimeter.

The first test of an integrated GPS/acoustic system took place in the Santa Cruz Basin off the coast of southern California in May 1990. In this test a much larger buoy, designed and built at SIO, was equipped with three GPS antennas and an acoustic transducer that interrogated a transponder on the ocean floor. Preliminary analysis indicates that the horizontal position of the transponder can be determined with a precision of about a centimeter. Further analysis will be required to investigate the magnitude of systematic errors.     

Deep-sea Fe-Mn Crusts from the Northeast Atlantic Ocean: Composition and Resource Considerations

Eighteen deep-sea ferromanganese crusts (Fe-Mn crusts) from 10 seamounts in the northeast Atlantic were studied. Samples were recovered from water depths of ～1,200 to ～4,600 m from seamounts near Madeira, the Canary and Azores islands, and one sample from the western Mediterranean Sea.

The mineralogical and chemical compositions of the samples indicate that the crusts are typical continental margin, hydrogenetic Fe-Mn crusts. The Fe-Mn crusts exhibit a Co + Cu + Ni maximum of 0.96 wt%. Platinum-group element contents analyzed for five samples showed Pt contents from 153 to 512 ppb.

The resource potential of Fe-Mn crusts within and adjacent to the Portuguese Exclusive Economic Zone (EEZ) is evaluated to be comparable to that of crusts in the central Pacific, indicating that these Atlantic deposits may be an important future resource.     

Relationship between turbidity and fish diets in Lakes Waahi and Whangape,New Zealand

Abstract

Stomach contents of Gobiomorphus cotidianus,Retropinna retropinna, Gambusia affinis, and Anguilla australis were compared between two shallow lakes in the lower Waikato River basin, to examine the relationship between turbidity and diet. Lake Waahi and the south arm of Lake Whangape had been turbid (20–40 g suspended solids (SS) m^?3) and devoid of submerged macrophytes since the late 1970s and early 1980s, respectively. The main basin of Lake Whangape had been generally clearer (5 g SS m^?3) with dense beds of submerged macrophytes, but at the time of sampling (1987) water clarity had deteriorated (> c. 10 g SS m³) and submerged macrophytes had declined. The mysid Tenagomysis chiltoni was an important prey for all species of fish from turbid water bodies but was less important in stomachs of fish in the main basin of Lake Whangape. Apparently, mysids were not an important prey in Lake Waahi before it became turbid. Chironomid larvae and pupae dominated the diets of small fish in the main basin of Lake Whangape. Fish and mysids were the most important prey of shortfinned eels in both lakes, with mysids most important in Lake Waahi. High mysid densities in the turbid water bodies provide an alternative food resource apparently compensating for those lost by fish when water clarity declined and submerged macrophytes collapsed.