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251.
252.
Jean-Jacques Peucat Johildo Salomão Figueiredo Barbosa Ivana Conceição de Araújo Pinho Jean-Louis Paquette Hervé Martin C. Mark Fanning Angela Beatriz de Menezes Leal Simone Cruz 《Journal of South American Earth Sciences》2011,31(4):397-413
This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event. 相似文献
253.
The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2 总被引:1,自引:1,他引:1
Josep M. Soler Marco Boi Jos Luis Mogolln Jordi Cama Carlos Ayora Peter S. Nico Nobumichi Tamura Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588
Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H2SO4, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L−1, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO4–H+ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H+ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO4–H+ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H+ solutions. 相似文献
254.
Djouher Saadoud Mohamed Saïd Guettouche Mohamed Hassani Francisco José Martin Peinado 《Arabian Journal of Geosciences》2017,10(16):363
Wind-erosion risk is a challenge that threatens land development in dry-land regions. Soil analysis, remote sensing, climatic, vegetal cover and topographic data were used in a geographic information system (GIS), using multi-criteria analysis (MCA) to map wind-erosion risk (Rwe) in Laghouat, Algeria. The approach was based on modelling the risk and incorporating topographic and climatic effects. The maps were coded according to their sensitivity to wind erosion and to their socio-economic potential, from low to very high. By overlapping the effects of these layers, qualitative maps were drawn to reflect the potential sensitivity to wind erosion per unit area. The results indicated that severe wind erosion affects mainly all the southern parts and some parts in the north of Laghouat, where wind-erosion hazard (Hwe) is very high in 43% of the total area, and which was affected mainly by natural parameters such as soil, topography and wind. The results also identified features vulnerable to Rwe. The product of the hazard and the stake maps indicated the potential risk areas that need preventive measures; this was more than half of the study area, making it essential to undertake environmental management and land-use planning. 相似文献
255.
Reiser Martin Kaspar Schuster Ralf Spikings Richard Tropper Peter Fügenschuh Bernhard 《International Journal of Earth Sciences》2017,106(2):659-685
International Journal of Earth Sciences - New Ar–Ar muscovite and Rb–Sr biotite age data in combination with structural analyses from the Apuseni Mountains provide new constraints on... 相似文献
256.
The largest karst cave discovered in a tunnel during motorway construction in Slovenia’s Classical Karst (Kras) 总被引:1,自引:0,他引:1
Karst researchers of the Karst Research Institute ZRC SAZU are regularly consulted during the planning of Slovenia’s motorways
and invited to observe and monitor construction in the karst areas. More than 350 caves have been discovered in the course
of building 60 km of new motorways over the past decade. Access to the most important caves is preserved by concrete tubes
closed with metal covers at the roadside. The largest cave system in a tunnel, named LC-S647, is almost entirely preserved.
The protection of this cave will serve as a good example for the preservation of natural heritage in the future. Construction
work for the motorway uncovered a high degree of karstification. In particular, the discovery of this cave in the Kastelec
tunnel LC-S647 showed the existence of a major cave system in the geological and speleological past. A number of unconnected
passages have also been found. Caves discovered during highway construction have brought new knowledge about the cavernosity
and the geological history of this part of the karst. 相似文献
257.
Karst aquifers represent important water resources in many parts of the world. Unfortunately, karst aquifers are characterised
by high contamination risks. This paper presents a travel time based method for the estimation of karst groundwater vulnerability.
It considers (1) physics-based lateral flow within the uppermost weathered zone (epikarst) in a limestone-dominated region
and (2) high velocities of vertical infiltration at discrete infiltration points (e.g. sinkholes) or lines (e.g. dry valleys,
faults). Consequently, the Transit Time Method honours the actual flow path within the unsaturated zone of a karst aquifer
system. A test site in Northern Jordan was chosen for the demonstration of the assessment technique, i.e. the catchment area
of the Qunayyah Spring north of the capital Amman. The results demonstrate that zones of highest vulnerability lie within
valleys and nearby main fault zones. It also reveals that regions, categorised as protected areas by other methods due to
thick unsaturated zones, contribute to a major degree to the total risk. 相似文献
258.
Studies of basement‐bounded canyons in West Greenland show that these were long‐lasting features that extended inland for several hundreds of kilometres, acting as prominent sediment conduits sourcing the Albian–Palaeocene Nuussuaq Basin during several phases of basin evolution. The Ilulissat Icefjord canyon was the major conduit for sediment into the basin and provenance data indicate that it had a huge catchment area that extended to East Greenland. The Uparuaqqusuitsut canyon was also an important conduit for sediment in the northern part of the basin. It is suggested that the initial canyon formation occurred during uplift events in the Late Triassic and Late Jurassic when the deeply weathered basement surface formed during Early–Middle Triassic time was eroded. The recognition of these canyons as long‐lasting sediment conduits have huge implications for understanding the sediment distribution, source‐to‐sink studies and the palaeogeography of the North Atlantic basins. 相似文献
259.
Fluid-assisted zircon and monazite growth within a shear zone: a case study from Finnmark,Arctic Norway 总被引:1,自引:0,他引:1
Christopher L. Kirkland Martin J. Whitehouse Trond Slagstad 《Contributions to Mineralogy and Petrology》2009,158(5):637-657
The U–Pb ages, REE content, and oxygen isotopic composition of zircon rims developed within a major shear zone in the Kalak
Nappe Complex (KNC), Arctic Norway have been determined along with the age of monazite crystals. Different generations of
granitic veins have been distinguished based on both field criteria and monazite ages of 446 ± 3 and 424 ± 3 Ma. Within each
of these veins, inherited zircon cores are mantled by homogeneous low CL-response zircon rims which yield a range of concordant
U–Pb dates of ca. 470–360 Ma. Significant numbers of zircon rims coincide with the timing of monazite crystallization. The
zircon rims have moderate light REE enrichment compared to cores, distinctive (Sm/La)
n
values of less than 12, and La between 0.3 and 10 ppm. This indicates free elemental exchange between newly formed zircon
rims and the surrounding matrix. The rims have calculated accumulated alpha-radiation dosages corresponding with a crystalline
structure and δ18O values of 1‰. This implies rim crystallization directly from a zirconium-saturated hydrothermal fluid which was modified
by some silicate melt. Growth of the zircon rims was prolonged and locally variable due to preferential fluid flow. A third
type of zircon can be recognized, forming both rims and cores, with high alpha-radiation doses, and significant enrichment
in La, Pr, and Eu. These are interpreted as low-temperature hydrothermally altered metamict zircons. The high volatile input
and partial melting in the shear zone favoured prolonged zircon rim growth due to its ability to easily nucleate on inherited
seeds. On the other hand, monazite, susceptible to dissolution and re-growth, crystallized in brief episodes, as has been
predicted from theoretical phase diagrams. From a regional perspective, these results elucidate cryptic Ar–Ar cooling ages,
providing the first record of a Late Ordovician heating and cooling phase within the KNC prior to the climactic Scandian collision. 相似文献
260.
The ultramafic-hosted Logatchev Hydrothermal Field (LHF) at 15°N on the Mid-Atlantic Ridge and the Arctic Gakkel Ridge (GR) feature carbonate precipitates (aragonite, calcite, and dolomite) in voids and fractures within different types of host rocks. We present chemical and Sr isotopic compositions of these different carbonates to examine the conditions that led to their formation. Our data reveal that different processes have led to the precipitation of carbonates in the various settings. Seawater-like 87Sr/86Sr ratios for aragonite in serpentinites (0.70909 to 0.70917) from the LHF are similar to those of aragonite from the GR (0.70912 to 0.70917) and indicate aragonite precipitation from seawater at ambient conditions at both sites. Aragonite veins in sulfide breccias from LHF also have seawater-like Sr isotope compositions (0.70909 to 0.70915), however, their rare earth element (REE) patterns show a clear positive europium (Eu) anomaly indicative of a small (< 1%) hydrothermal contribution. In contrast to aragonite, dolomite from the LHF has precipitated at much higher temperatures (~ 100 °C), and yet its 87Sr/86Sr ratios (0.70896 to 0.70907) are only slightly lower than those of aragonite. Even higher temperatures are calculated for the precipitation of deformed calcite veins in serpentine–talc fault schists form north of the LHF. These calcites show unradiogenic 87Sr/86Sr ratios (0.70460 to 0.70499) indicative of precipitation from evolved hydrothermal fluids. A simple mixing model based on Sr mass balance and enthalpy conservation indicates strongly variable conditions of fluid mixing and heat transfers involved in carbonate formation. Dolomite precipitated from a mixture of 97% seawater and 3% hydrothermal fluid that should have had a temperature of approximately 14 °C assuming that no heat was transferred. The much higher apparent precipitation temperatures based on oxygen isotopes (~ 100 °C) may be indicative of conductive heating, probably of seawater prior to mixing. The hydrothermal calcite in the fault schist has precipitated from a mixture of 67% hydrothermal fluid and 33% seawater, which should have had an isenthalpic mixing temperature of ~ 250 °C. The significantly lower temperatures calculated from oxygen isotopes are likely due to conductive cooling of hydrothermal fluid discharging along faults. Rare earth element patterns corroborate the results of the mixing model, since the hydrothermal calcite, which formed from waters with the greatest hydrothermal contribution, has REE patterns that closely resemble those of vent fluids from the LHF. Our results demonstrate, for the first time, that (1) precipitation from pure seawater, (2) conductive heating of seawater, and (3) conductive cooling of hydrothermal fluids in the sub-seafloor all can lead to carbonate precipitation within a single ultramafic-hosted hydrothermal system. 相似文献