500-yr. precipitation variability in Southern Taihang Mountains,China, and its linkages to ENSO and PDO

An annually resolved and absolutely dated ring-width chronology spanning 657 yrs. is constructed with Whitebark pine (Pinus bungeana Zucc.) samples from the southern Taihang Mountains, Eastern China. On the basis of a significant correlation between the tree-ring width index and observed instrumental data, precipitation in current May is reconstructed for the region since AD 1510, with predictor variables accounting for 37.9 % of the variance in precipitation data. In agreement with other drought reconstructions, notable dry spells occur in the 1630s–1650s, 1680s–1700s, and 1770s–1800s, whereas wet periods prevail in the 1530s–1570s, 1840s–1870s, and 1950s-present. Wavelet analysis reveals clear 2–8, 20–40, and 80–130 yrs cycles at the 95 % confidence level for the reconstructed series over the past 500 yrs, suggesting possible linkages with the El Niño-Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). Correlation analysis between the tree-ring series, ENSO, and PDO index further demonstrates that precipitation is negatively correlated with PDO and ENSO in the long term.     

Degradation of chlorinated ethylenes by Fe0: inhibition processes and mineral precipitation

. Granular zero-valent iron was used for the treatment of groundwater pollution caused by chlorinated ethylenes, mainly TCE, cis-DCE and VC at an industrial site. The rapidly decreasing rates of de-chlorination in the initial phase were attributed to the precipitation of carbonates and the development of hydrogen by anaerobic corrosion. After 70 pore volumes, sulphate was reduced by bacteria. From this point in time, the degradation of TCE was slightly accelerated whereas the de-chlorination rates of the other chlorinated ethylenes decreased only slowly. This relative improvement was assumed to be caused by the uptake of electron-transfer-blocking hydrogen by bacteria. Because the overall trend of the degradation rates is negative we conclude that the inhibitive effect of carbonate precipitation and hydrogen formation cannot be compensated for by the positive influence of the activity of sulphate-reducing bacteria.