Crystal field stabilization energies of almandine-pyrope and almandine-spessartine garnets determined by FTIR near infrared measurements

The band positions of three partially overlapping Fe²⁺ spin-allowed transitions located between 4000 and 9000 cm^–1 in almandine-pyrope and almandinespessartine garnets solid solutions were measured using near-infrared (NIR) spectroscopy. The crystal field stabilization energies (CFSE) along both binaries were calculated assuming a splitting of 1100 cm^–1 for the lower orbitals. The CFSE show a slight increase along the almandine-spessartine binary from 3730 to 3810 cm^–1 and a larger increase from 3730 to 3970 cm^–1 for the almandine-pyrope binary. Dodecahedral Fe²⁺-site distortion increases with an increase in spessartine component and decreases with increasing pyrope component, in agreement with average dodecahedral site distortions determined from diffraction experiments. The excess CFSE's along both joins are negative. For the almandinespessartine binary they are small, but are about 3.5 times larger in magnitude along the join almandine-pyrope, where an interaction parameter of W= -2.9 KJ/mole has been derived from a symmetric mixing model. The excess CFSE are relatively small compared to the magnitudes of the excess enthalpies of mixing that have been assigned to garnet solid solutions. Moreover, they give no indication which could support the positive and asymmetric excess enthalpies of mixing that have been proposed for almandine-pyrope solid solutions.     

Identifying volcanic regimes using Hidden Markov Models

We examine the application of Hidden Markov Models (HMMs) to volcanic occurrences. The parameters in HMMs can be estimated from data by means of the Expectation–Maximization (EM) algorithm. Various formulations permit modelling the activity level of a volcano through onset counts, the intensity of a Markov Modulated Poisson Process (MMPP), or through the intervals between onsets. More elaborate models allow investigation of the relationship between durations and reposes. After fitting the model, the Viterbi algorithm can be used to identify the underlying (hidden) activity level of the volcano most consistent with the observations. The HMM readily provides forecasts of the next event, and is easily simulated. Data of flank eruptions 1600–2006 from Mount Etna are used to illustrate the methodology. We find that the volcano has longish periods of Poissonian behaviour, interspersed with less random periods, and that changes in regime may be more frequent than have previously been identified statistically. The flank eruptions of Mount Etna appear to have a complex time-predictable character, which is compatible with transitions between an open and closed conduit system. The relationship between reposes and durations appears to characterize the cyclic nature of the volcanoes activity.     

The tectono‐stratigraphic evolution of the Austral Basin and adjacent areas against the background of Andean tectonics,southern Argentina,South America

The Austral Basin (or Magallanes Basin) in southern Argentina is situated in a highly active tectonic zone. The openings of the South Atlantic and the Drake Passage to the east and south, active subduction in the west, and the related rise of the Andes have massively influenced the evolution of this area. To better understand the impacts of these tectonic events on basin formation to its present‐day structure we analysed 2D seismic reflection data covering about 95 000 km² on‐ and 115 000 km² offshore (Austral ‘Marina’ and Malvinas Basin). A total of 10 seismic horizons, representing nine syn‐ and post‐ rift sequences, were mapped and tied to well data to analyse the evolution of sedimentary supply and depocenter migration through time. 1D well backstripping across the study area confirms three main tectonic stages, containing (i) the break‐up phase forming basement graben systems and the evolution of the Late Jurassic – Early Cretaceous ancient backarc Austral/Rocas Verdes Basin (RVB), (ii) the inversion of the backarc marginal basin and the development of the foreland Austral Basin and (iii) the recent foreland Austral Basin. Synrift sedimentation did not exceed the creation of accommodation space, leading to a deepening of the basin. During the Early Cretaceous a first impulse of compression due to Andes uplift caused rise also of parts of the basin. Controlling factors for the subsequent tectonic development are subduction, balanced phases of sedimentation, accumulation and erosion as well as enhanced sediment supply from the rising Andes. Further phases of rock uplift might be triggered by cancelling deflection of the plate and slab window subduction, coupled with volcanic activity. Calculations of sediment accumulation rates reflect the different regional tectonic stages, and also show that the Malvinas Basin acted as a sediment catchment after the filling of the Austral Basin since the Late Miocene. However, although the Austral and Malvinas Basin are neighbouring basin systems that are sedimentary coupled in younger times, their earlier sedimentary and tectonic development was decoupled by the Rio Chico basement high. Thereby, the Austral Basin was affected by tectonic impacts of the Andes orogenesis, while the Malvinas Basin was rather affected by the opening of the South Atlantic.     

1971-2009 年珠穆朗玛峰地区尼泊尔境内气候变化

利用珠穆朗玛峰南坡尼泊尔境内(科西河流域) 的10 个气象站1971-2009 年月平均气温、月平均最高、最低气温和逐月降水资料, 采用线性趋势、Sen 斜率估计、Mann-Kendall 等方法分析区域气候变化状况及其时空特征, 并与珠穆朗玛峰北坡地区气候进行比较, 分析了珠穆朗玛峰地区气候变化的特征与趋势。结果表明:(1) 1971-2009 年间, 珠穆朗玛峰南坡年平均气温为20.0℃, 线性升温率为0.25℃/10a, 与北坡主要受年平均最低气温影响相反, 增幅主要受年平均最高气温升高的影响, 并且在1974 年及1992 年间出现两次显著增温, 增温特别明显的月份为2 月和9 月;(2) 该地区降水变化的局地性较强, 近40 年间年平均降水量为1729.01 mm, 年平均降水量以每年约4.27 mm的线性增幅有所增加, 但并不显著, 且降水月变化和季变化特征均不明显;(3) 由于珠穆朗玛峰南坡受到季风带来暖湿气流和喜马拉雅山阻挡的双重影响, 珠峰南坡的年平均降水量远高于北坡;(4) 珠穆朗玛峰南坡气温变暖的海拔依赖性并不明显, 且南坡地区的变暖趋势并没有北坡变暖趋势明显。     

High-resolution ion-microprobe measurement of lead isotopes: Variations within single zircons from Lac Seul,northwestern Ontario

Selected-area measurements of lead-isotope ratios in zircons have been made at high mass resolution using a modified A.E.I. IM20 ion-microprobe. At a working resolution of 3200 it is shown that the important interfering molecular peaks generated from the zircon matrix may be separated from atomic lead peaks. Corrections for overlapping peaks, which are necessary in measurements of lead isotopes at low mass resolution, are then only required for ²⁰⁸Pb.Measurements on N.B.S. standards show no isotope discrimination within counting statistics. Determination of ²⁰⁷Pb/²⁰⁶Pb on 29 single zircon grains from a tonalite gneiss and a granite from Lac Seul, northwestern Ontario, give very variable ratios with mean values close to those of bulk separates. Peaks in the distribution of 207/206 ratios obtained from the tonalite gneiss may be interpreted as evidence for two stages of lead loss. High 207/206 ratios are shown to be significant for at least two zircons and probably record a minimum age of formation of 3.3 ± 0.1 b.y. for the gneiss.     

Finding Common Ground: A Critique of Subsumption Theory and Its Application to Small-Scale Forest Carbon Offsetting in Uganda

Carbon markets as a policy tool to mitigate emissions of greenhouse gases continue to be controversial, especially in developing countries. It is thus refreshing that Carton and Andersson (2017 Carton, W., and E. Andersson. 2017. Where forest carbon meets its maker: Forestry-based offsetting as the subsumption of nature. Society &; Natural Resources 30 (7):829–43.[Taylor &; Francis Online], [Web of Science ®] , [Google Scholar]) undertook a field investigation of a transnational forest carbon offset project in Uganda. However, I am concerned that assumptions of structural Marxism that underwrite subsumption theory may have led the authors to see the project as inherently conflict ridden and exploitative and to neglect actual benefits. Their presentation of the project’s local impact jarred with my own empirical research into this project, undertaken in 2009, as well as more recent news accounts. While my field effort preceded the authors’ by 6 years, I attribute our different interpretations largely to theoretical and methodological differences. Evidence I present below suggests considerable alignment between the interests of transnational carbon markets and Ugandan smallholder farmers. Additional fieldwork might be able to resolve these differences in interpretation.     

The contribution of sulphur dioxide from ablating micrometeorites to the atmospheres of Earth and Mars

Atmospheric composition is a key control on climate and the habitability of planetary surfaces. Ablation of infalling micrometeorites has been recognised as one way in which atmospheric chemistry can be changed, especially at times in solar system history when the infall rates of exogenous material were high. Despite its potential to influence climate and habitability, extraterrestrial sulphur dioxide is currently an unquantified contribution to the atmospheres of the terrestrial planets. We have used flash pyrolysis to simulate the atmospheric entry of micrometeorites and Fourier-transform infrared spectroscopy to identify and quantify the sulphur dioxide produced from the carbonaceous meteorites Orgueil (CI1), ALH 88045 (CM1), Cold Bokkeveld (CM2), Murchison (CM2) and Mokoia (CV3). We have used this approach to understand the introduction of sulphur dioxide to the atmospheres of Earth and Mars from infalling micrometeorites. Sulphates, present in carbonaceous chondrites at a few wt.%, are resistant to thermal decomposition, limiting the yields of sulphur dioxide from unmelted micrometeorites. Infalling micrometeorites are a minor source of present-day sulphur dioxide on Earth and Mars, calculated to be up to around 2400 tonnes and about 350 tonnes, respectively. During the Late Heavy Bombardment (LHB), the much greater infall rates of micrometeoritic dust are calculated to be associated with average production rates of sulphur dioxide of around 20 Mt yr⁻¹ for the early Earth and 0.5 Mt yr⁻¹ for early Mars, for a LHB of 100 Myr. These rates of delivery of sulphur dioxide at high altitudes would have reduced the solar energy reaching the surfaces of these planets, via scattering of sunlight by stratospheric sulphate aerosols, and may have had detrimental effects on developing biospheres by promoting cooler climates and reducing the probability of liquid water on planetary surfaces.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

Spatiotemporal variability in channel deformations on rivers of Russia

We assess the spatiotemporal changes in channel processes on rivers of Russia, determine the causes for vertical (incision or directional sediment accumulation) and horizontal (displacement of channel forms) deformations and show the distribution of stream channel of different morphodynamical types and with a different reconfiguration rate. The conditions are revealed, under which the channel types change over time. Particular emphasis is placed on the analysis of spatiotemporal changes in channels caused by anthropogenic disturbances and by direct technogenic interferences in the life of rivers (hydroelectric schemes, quarries in the river channels, and waterway dredging).