Regional climate change experiments over southern South America. I: present climate

We present an analysis of a regional simulation of present-day climate (1981–1990) over southern South America. The regional model MM5 was nested within time-slice global atmospheric model experiments conducted by the HadAM3H model. We evaluate the capability of the model in simulating the observed climate with emphasis on low-level circulation patterns and surface variables, such as precipitation and surface air mean, maximum and minimum temperatures. The regional model performance was evaluated in terms of seasonal means, seasonal cycles, interannual variability and extreme events. Overall, the regional model is able to capture the main features of the observed mean surface climate over South America, its seasonal evolution and the regional detail due to topographic forcing. The observed regional patterns of surface air temperatures (mean, maxima and minima) are well reproduced. Biases are mostly within 3°C, temperature being overestimated over central Argentina and underestimated in mountainous regions during all seasons. Biases in northeastern Argentina and southeastern Brazil are positive during austral spring season and negative in other seasons. In general, maximum temperatures are better represented than minimum temperatures. Warm bias is larger during austral summer for maximum temperature and during austral winter for minimum temperature, mainly over central Argentina. The broad spatial pattern of precipitation and its seasonal evolution are well captured; however, the regional model overestimates the precipitation over the Andes region in all seasons and in southern Brazil during summer. Precipitation amounts are underestimated over the La Plata basin from fall to spring. Extremes of precipitation are better reproduced by the regional model compared with the driving model. Interannual variability is well reproduced too, but strongly regulated by boundary conditions, particularly during summer months. Overall, taking into account the quality of the simulation, we can conclude that the regional model is capable in reproducing the main regional patterns and seasonal cycle of surface variables. The present reference simulation constitutes the basis to examine the climate change simulations resulting from the A2 and B2 forcing scenarios which are being reported in a separate study.     

The last deglaciation in the Picos de Europa National Park (Cantabrian Mountains,northern Spain)

A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.     

Gravitation astrometric measurement experiment

The Gravitation Astrometric Measurement Experiment (GAME) is a mission concept based on astronomical techniques (astrometry and coronagraphy) for Fundamental Physics measurements, namely the ?? and ?? parameters of the Parametrized Post-Newtonian formulation of gravitation theories extending the General Relativity. The science case also addresses cosmology, extra-solar planets, Solar System objects and fundamental stellar parameters. The mission concept is described, including the measurement approach and the instrument design.     

Concentrations of PCBs,BHCs and DDTs residues in seaweeds of the east coast of Sicily

The levels of PCBs, DDT and BHC residues have been determined in thalli of 12 species of marine algae harvested along the east coast of Sicily. The results are discussed in comparison with those obtained earlier with animal species sampled in the same area.     

Equivalent-linear site response analysis on the site of the historical Trakošćan Castle,Croatia, using HVSR method

This paper presents a major extension of seismic vulnerability research project on the site of Trako??an Castle based on the initial horizontal-to-vertical-spectral-ratio (HVSR) results from Stanko et al. (2016). The estimated HVSR site frequencies and HV amplification at Trako??an Castle can only be used as an indication of the initial soil site frequency and amplification, so-called natural soil model, corresponding to the subsoil profile without the influence of an earthquake. The equivalent-linear (EQL) site response analysis has been carried out for different earthquake scenarios for a maximum input rock peak ground acceleration (PGA_ROCK) that corresponds to return periods of 95 (0.08 g), 475 (0.18 g) and 1000 years (0.31 g). The aim of the research is to evaluate structural seismic design responses and to determine type and degree of damage caused by local site effect, which is the result of an alluvial basin and topographic influences. The main objective of this research is the formation of local microseismic zones based on an EQL analysis: surface spectral acceleration and amplification maps at the predominant frequency. Based on the HVSR frequency response of the core structure of Trako??an Castle and the Tower itself (fundamental and higher frequency modes), maps of surface spectral acceleration and soil amplification at different frequencies (3, 5 and 10 Hz) are developed for different input PGA_ROCK levels (0.08, 0.18 and 0.31 g) to evaluate seismic response of the Castle. Observed amplifications are correlated with ground motion polarization and directionality of the ground motion from the alluvial basin to the hilltop. Shortening of predominant frequencies (lengthening of the period), particularly in the alluvial basin, has been observed with higher input PGA_ROCK in the EQL analysis. This effect is not manifested in the Trako??an hill, and predominant frequencies match HVSR frequencies. The use of certain geophysical survey methods at historical sites is a big problem, because terrain features (e.g. steep hills, mountains, ridges, slopes, cliffs) create lack of space and make it impossible to carry out geophysical investigation. Microtremor measurements at historical sites can overcome this limitation and provide local seismic response and vulnerability behaviour of historical monuments without destroying their authenticity. Also, computational modelling can greatly improve the results. The EQL site response analysis on the site of Trako??an Castle has confirmed and improved the results of seismic response and vulnerability based on HVSR method.     

High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

Argon isotope fractionation induced by stepwise heating

Noble gas isotopes are widely used to elucidate the history of the rocks in which they have been trapped, either from distinct reservoirs or by accumulation following radioactive decay. To extract noble gases from their host rocks, stepwise heating is the most commonly used technique to deconvolve isotopically different components, e.g., atmospheric, in situ radiogenic, or excess radiogenic from mantle or crustal reservoirs. The accurate determination of the isotopic composition of these different components is of crucial importance, e.g., for ages obtained by ⁴⁰Ar-³⁹Ar stepheating plateaus. However, diffusion theory-based model calculations predict that the stepwise thermal extraction process from mineral phases induces isotope fractionation and, hence, adulterates the original composition. Such effects are largely unconsidered, as they are small and a compelling experimental observation is lacking. We report the first unequivocal evidence for significant mass fractionation of argon isotopes during thermal extraction, observed on shungite, a carbon-rich Precambrian sedimentary rock. The degree of fractionation, as monitored by ³⁸Ar/³⁶Ar and ⁴⁰Ar/³⁶Ar ratios, very well agrees with theoretical predictions assuming an inverse square root dependence of diffusion coefficient and atomic mass, resulting in easier extraction of lighter isotopes. Hence, subatmospheric ⁴⁰Ar/³⁶Ar ratios obtained for argon extracted at low temperatures may not represent paleoatmospheric argon. Shungite argon resembles modern atmospheric composition, but constraints on the timing of trapping appear difficult to obtain, as shungites are multicomponent systems.In ⁴⁰Ar-³⁹Ar stepwise heating, the isotope fractionation effect could cause systematic underestimations of plateau ages, between 0.15 and 0.4% depending on age, or considerably higher if samples contain appreciable atmospheric Ar. The magnitude of this effect is similar to the presently achieved uncertainties of this increasingly precise dating technique. Our results also indicate the importance of thermally activated diffusion as a possible fractionation mechanism, e.g., for hydrothermal gas exhalations, or for carbonaceous carrier phases such as “Q” in meteorites that have been suggested as carriers of highly fractionated noble gas residues from the early solar nebula.     

Fluidization of buried mass-wasting deposits in lake sediments and its relevance for paleoseismology: Results from a reflection seismic study of lakes Villarrica and Calafquén (South-Central Chile)

A dense grid of very-high resolution seismic profiles on Lake Villarrica provides a quasi-3D view on intercalated lenses of low-amplitude reflections, which are connected by acoustic wipe-out patches and fractures to an underlying voluminous mass-wasting deposit. The lenses are interpreted as being created by earthquake-triggered liquefaction in this buried mass-wasting deposit and subsequent sediment fluidization and extrusion at the paleo-lake bottom. These sediment volcanoes are mapped in detail. They have a rather uniform circular geometry and show a linear relationship between apparent width and maximum thickness on a seismic section. The largest sediment volcanoes are up to 80 m wide and 1.9 m thick. Their slope angles designate a syn- to post-depositional sagging of most sediment volcanoes. Sediment volcano detection and mapping from nearby Lake Calafquén further strengthen the revealed geometrical relationships. Locally, some of the sediment/fluid escape structures extend to a higher position in the stratigraphy, which points to a polyphase escape process associated with multiple multi-century spaced strong earthquakes. Thickness and morphology of the source layer seem to exert a dominant control in the production of sediment/fluid extrusions. This study shows that reflection seismic profiling allowed recognizing 4 different seismic events in the studied stratigraphic interval, which are evidenced by mass-wasting deposits and/or fluidization features.