Compositionally zoned crystals and real-time degassing data reveal changes in magma transfer dynamics during the 2006 summit eruptive episodes of Mt. Etna

One of the major objectives of volcanology remains relating variations in surface monitoring signals to the magmatic processes at depth that cause these variations. We present a method that enables compositional and temporal information stored in zoning of minerals (olivine in this case) to be linked to observations of real-time degassing data. The integrated record may reveal details of the dynamics of gradual evolution of a plumbing system during eruption. We illustrate our approach using the 2006 summit eruptive episodes of Mt. Etna. We find that the history tracked by olivine crystals, and hence, most likely the magma pathways within the shallow plumbing system of Mt. Etna, differed considerably between the July and October eruptions. The compositional and temporal record preserved in the olivine zoning patterns reveal two mafic recharge events within months of each other (June and September 2006), and each of these magma supplies may have triggered the initiation of different eruptive cycles (July 14–24 and August 31–December 14). Correlation of these observations with gas monitoring data shows that the systematic rise of the CO₂/SO₂ gas values is associated with the gradual (pre- and syn-eruptive) supply of batches of gas-rich mafic magma into segments of Etna’s shallow plumbing system, where mixing with pre-existing and more evolved magma occurred.     

Flux and dispersion of gases from the “Drachenschlund” hydrothermal vent at 8°18' S, 13°30' W on the Mid-Atlantic Ridge

Hydrothermal emission of mantle helium appears to be directly related to magma production rate, but other processes can generate methane and hydrogen on mid-ocean ridges. In an on-going effort to characterize these processes in the South Atlantic, the flux and distribution of these gases were investigated in the vicinity of a powerful black smoker recently discovered at 8°17.9' S, 13°30.4' W. The vent lies on the shoulder of an oblique offset in the Mid-Atlantic Ridge and discharges high concentrations of methane and hydrogen. Measurements during expeditions in 2004 and 2006 show that the ratio of CH₄ to ³He in the neutrally buoyant plume is quite high, 4 × 10⁸. The CTD stations were accompanied by velocity measurements with lowered acoustic Doppler current profilers (LADCP), and from these data we estimate the methane transport to have been 0.5 mol s^− 1 in a WSW-trending plume that seems to develop during the ebb tidal phase. This transport is an order of magnitude greater than the source of CH₄ calculated from its concentration in the vent fluid and the rise height of the plume. From this range of methane fluxes, the source of ³He is estimated to be between 0.14 and 1.2 nmol s^− 1. In either case, the ³He source is significantly lower than expected from the spreading rate of the Mid-Atlantic Ridge. From the inventory of methane in the rift valley adjacent to the vent, it appears that the average specific rate of oxidation is 2.6 to 23 yr^− 1, corresponding to a turnover time between 140 and 16 days. Vertical profiles of methane in the surrounding region often exhibited Gaussian-like distributions, and the variances appear to increase with distance from the vent. Using a Gaussian plume model, we obtained a range of vertical eddy diffusivities between 0.009 and 0.08 m²m² s^− 1. These high values may be due to tidally driven internal waves across the promontory on which the vent is located.     

Hydrochemical characterisation of ground and surface water at Dörtyol/Hatay/Turkey

The degradation of ground water quality due to human activities is a widespread environmental problem. Furthermore, coastal aquifers are threatened by sea water intrusion as a result of increasing water exploitation. The investigation area near Dörtyol is located at the Mediterranean coast, southern Turkey, and dominated by agricultural land use. Drinking, domestic and agricultural purposes require different amounts of uncontaminated water. In this study the hydrogeological characteristics of the coastal plain were investigated. Discharge and ground water level measurements as well as geological investigations were undertaken in field in addition to anion and cation analyses of ground and surface water. The results show geological and anthropogenic influence on ground and surface water composition. In spite of a large number of wells in the coastal area sea water intrusion was not detected. With the goal of devising sustainable water use regulations, more emphasis and research needs to be directed to the long-term observation of ground and surface water quality as well as the detailed investigation of hydraulic characteristics of the local aquifer.     

Modelling ecohydrological feedbacks in forest and grassland plots under a prolonged drought anomaly in Central Europe 2018–2020

Recent studies have highlighted the importance of understanding ecohydrological drought feedbacks to secure water resources under a changing climate and increasing anthropogenic impacts. In this study, we monitored and modelled feedbacks in the soil–plant-atmosphere continuum to the European drought summer 2018 and the following 2 years. The physically based, isotope-aided model EcH₂O-iso was applied to generic vegetation plots (forest and grassland) in the lowland, groundwater-dominated research catchment Demnitzer Millcreek (NE Germany; 66 km²). We included, inter alia, soil water isotope data in the model calibration and quantified changing “blue” (groundwater recharge) and “green” (evapotranspiration) water fluxes and ages under each land use as the drought progressed. Novel plant xylem isotope data were excluded from calibration but were compared with simulated root uptake signatures in model validation. Results indicated inter-site differences in the dynamics of soil water storage and fluxes with contrasting water age both during the drought and the subsequent 2 years. Forest vegetation consistently showed a greater moisture stress, more rapid recovery and higher variability in root water uptake depths from a generally younger soil water storage. In contrast, the grassland site, which had more water-retentive soils, showed higher and older soil water storage and groundwater recharge fluxes. The damped storage and flux dynamics under grassland led to a slower return to younger water ages at depth. Such evidence-based and quantitative differences in ecohydrological feedbacks to drought stress in contrasting soil-vegetation units provide important insights into Critical Zone water cycling. This can help inform future progress in the monitoring, modelling and development of climate mitigation strategies in drought-sensitive lowlands.     

Development and Testing of a Field Screening Method Based on Bubbling Extraction and Photoionization Detection for Measurement of Benzene and Total VOCs

A field screening method was developed for rapid measurement of benzene and gasoline range total petroleum hydrocarbons (TPHg) concentrations in groundwater. The method is based on collecting photoionization detector (PID) measurements from vapor samples. The vapor samples are collected by bubbling air through groundwater samples (air sparging) with a constant volume, temperature and sparging rate. The level of accuracy, sensitivity, precision, and statistical significance of the estimated concentrations, derived from the screening method, are comparable to conventional laboratory analytical results at concentrations equal to or greater than 150 µg/L for benzene and greater than 50 µg/L for TPHg. The method's concentration estimations can assist in making real‐time decisions regarding location of dissolved plumes and light nonaqueous phase liquid (LNAPL) source zones at many fuel release sites. The screening method was tested in the laboratory and in the field with 208 and 107 samples, respectively. The study concludes that the screening method can be used as a tool to aid in completing a site conceptual model as well as analyzing groundwater from monitoring wells.     

The dynamics of phytoplankton, bacteria and heterotrophic flagellates at two Banks near Magdeburg in the River Elbe (Germany)

The main objectives of this study were to describe the seasonal standing stock dynamics of phytoplankton, bacterioplankton and heterotrophic flagellates in the highly eutrophic River Elbe (Germany), and to compare the seasonal patterns observed with other streams. Emphasis was placed on examining and assessing abiotic and biotic controlling factors influencing the structure and dynamics of the riverine plankton. All the physico-chemical and biological parameters determined were within the range or somewhat higher (in the case of phytoplankton abundance and biomass) than reported for other large streams. The underwater light conditions resulting from atypically short phytoplankton growth periods of about 6 months per year and the low phytoplankton carbon to chl a ratio of 23 were identified as a major limiting factor for phytoplankton development in the River Elbe. The seasonal distribution pattern of bacterioplankton indicated probable tight trophodynamical coupling both with phytoplankton and with heterotrophic flagellates, whereas heterotrophic flagellates showed a more trophic link with bacterial densities. Although approximately constant DOC and DON levels throughout the year sustained bacterial growth rates, during the phytoplankton growing season an increase of bacterial standing stocks was observed. Although the left-bank sampling site of the Elbe is strongly influenced by the tributaries Mulde and Saale containing higher concentrations of chloride, nitrogen nutrients, heavy metals and organic pollutants, no clear differences were observed between the two sides of the river concerning the biological parameters measured. Possible reasons and the slightly higher phytoplankton abundance and diversity at the right bank are discussed.     

Modulation of the inflow into the Caribbean Sea by North Brazil Current rings

A two-year long record from a triangular mooring array between the Lesser Antilles islands Tobago, Barbados, and St. Lucia is used to investigate the inflow into the Caribbean Sea, the amount of South Atlantic Water (SAW) carried with the inflow, and the role of North Brazil Current (NBC) rings in the observed variability. The data set consists of time series from temperature/conductivity recorders and current meters in the moorings, bottom-mounted inverted echo sounders at the Tobago and St. Lucia mooring positions, and supplementary shipboard measurements. The acoustic travel time measurements of the inverted echo sounders and the conductivity/temperature time series are used for continuous estimation of dynamic height profiles and geostrophic currents between the surface and 1000 dbar as well as the amount of SAW found at the mooring positions.The observations show a domination of intraseasonal variability between 0 and 15 Sv, superimposed on the long-term fluctuations. With time scales of one to three months, these represent the signature of the NBC rings. The baroclinic transport time series shows nine periods of increased variability, indicative of the rings interacting with the Lesser Antilles island arc; with the exception of one, these periods were associated with corresponding sea surface height anomalies. No marked seasonality was observed in the transport variability or the ring frequency.The arrival of individual rings leads to a weakening of the inflow into the Caribbean. Nevertheless, the rings carry large amounts of SAW into the area, and the immediate increase of the transport towards the end of a ring event suggests a subsequent flow of this SAW-rich water into the Caribbean. At St. Lucia, rings sometimes cause a short-term decrease of SAW content, indicative of an influx of northern hemispheric water and a blocking situation. The average transport of SAW into the Caribbean south of St. Lucia during the observations amounted to 5.5 Sv, with no significant seasonal cycle, but a small positive trend in SAW fraction as well as in transport of about 15% and 1 Sv, respectively; a corresponding trend in the baroclinic volume transport was not observed.     

Tidal flow asymmetry in the diurnal regime: bed-load transport and morphologic changes around the Red River Delta

The relation between tidal flow asymmetry and net transport of sediment in the semidiurnal regime has been extensively described. This study reveals that in the diurnal regime, the direction of long-term net bed-load transport and resulting morphologic changes is partly determined by the phase-angle relationship of O₁, K₁, and M₂. Simple analytical formulations of time-averaged bed-load transport were derived which separate the relative contributions of tidal asymmetry from that of residual flow with tidal stirring. In this particular case, the Red River Delta in Vietnam, transports related to tidal asymmetry are larger than those induced by the monsoon currents, and are an order of magnitude larger than those associated with topographic residual flow around the delta. Tide-induced morphologic changes dominate at water depths between 10 and 25 m, of which the patterns of erosion and deposition overlap with observed bathymetric changes. Additional observed changes that occur in more shallow water cannot be explained by tidal asymmetry and are probably related to wave action and to deposition from the buoyant river plume.Responsible Editor: Jens Kappenberg     

A SOLAR-RADIATION-DRIVEN WATER BUDGET METHODOLOGY FOR SLOPING ARID AND SEMIARID LANDS

A solar-radiation-based water balance model has been developed for use in sloping arid and semiarid lands. This model consists of equations for the calculation of direct beam, diffuse, and global radiation values from local values of extraterrestrial radiation, percent possible sunshine, latitude, declination of the sun, atmospheric pressure, and slope; an adaptation of the Makkink formula for calculation of evapotranspiration; and a modification of the Thornthwaite and Mather method for determining the soil moisture. Calculated global radiation values are within 4% of the measured values provided in the Climatic Atlas of the United States. Water balances determined for several mountainous sites show significant variation with slope and aspect.