Multi‐Criteria Analysis for Optimization of Sodium Chromate Production from Chromic Waste

The proposal of application of multi‐criteria analysis and technological quality method for optimization of technological processes on the case study of sodium chromate production variants from waste was presented. The research on the use of chromic waste for the production of sodium chromate made it possible to determine the optimal process parameters. Technological quality method was used to define the value of criterions for multi‐criteria analysis while multi‐criteria analysis allowed determining the impact of criterions weights for ranking variants of technological process. Both methods in a complex way evaluate the degree of modernization of technologies, describing them qualitatively within the area of environmental, technical, and the economic effects of the proposed technological variants. Based on the proposed evaluating criteria both methods yield comparable results. The most advantageous alternatives provided realization of the sodium chromate production process with the use of in‐process recycling of chromic mud, off‐site recycling of chromic tannery waste and on‐site recycling of waste from the old chromic heaps.     

Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

The distribution of meteoric <Superscript>36</Superscript>Cl/Cl in the United States: a comparison of models

The natural distribution of ³⁶Cl/Cl in groundwater across the continental United States has recently been reported by Davis et al. (2003). In this paper, the large-scale processes and atmospheric sources of ³⁶Cl and chloride responsible for controlling the observed ³⁶Cl/Cl distribution are discussed.The dominant process that affects ³⁶Cl/Cl in meteoric groundwater at the continental scale is the fallout of stable chloride from the atmosphere, which is mainly derived from oceanic sources. Atmospheric circulation transports marine chloride to the continental interior, where distance from the coast, topography, and wind patterns define the chloride distribution. The only major deviation from this pattern is observed in northern Utah and southern Idaho where it is inferred that a continental source of chloride exists in the Bonneville Salt Flats, Utah.In contrast to previous studies, the atmospheric flux of ³⁶Cl to the land surface was found to be approximately constant over the United States, without a strong correlation between local ³⁶Cl fallout and annual precipitation. However, the correlation between these variables was significantly improved (R ²=0.15 to R ²=0.55) when data from the southeastern USA, which presumably have lower than average atmospheric ³⁶Cl concentrations, were excluded. The total mean flux of ³⁶Cl over the continental United States and total global mean flux of ³⁶Cl are calculated to be 30.5±7.0 and 19.6±4.5 atoms m^–2 s^–1, respectively.The ³⁶Cl/Cl distribution calculated by Bentley et al. (1986) underestimates the magnitude and variability observed for the measured ³⁶Cl/Cl distribution across the continental United States. The model proposed by Hainsworth (1994) provides the best overall fit to the observed ³⁶Cl/Cl distribution in this study. A process-oriented model by Phillips (2000) generally overestimates ³⁶Cl/Cl in most parts of the country and has several significant local departures from the empirical data.

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Resumen Davis et al. (2003) han informado de la distribución natural de la proporción ³⁶Cl/Cl en las aguas subterráneas de la parte continental de los Estados Unidos de América [EUA]. En este artículo, se discute cuáles son los procesos a gran escala y las fuentes atmosféricas del ³⁶Cl y del cloruro que dan lugar a la distribución observada de ³⁶Cl/Cl.El proceso dominante que afecta a la relación ³⁶Cl/Cl en las aguas subterráneas de origen meteórico a escala continental es el aporte de cloruro estable desde la atmósfera, que procede principalmente de los océanos. La circulación atmosférica transporta el cloruro marino hacia el interior, donde la distancia a la costa, topografía y corrientes del viento definen la distribución del cloruro. La única desviación principal de este esquema tiene lugar al norte de Utah y en el sur de Idaho, donde se deduce que existe una fuente continental de cloruro en los Rellanos Salados de Bonneville (Salt Flats).En contraste con estudios previos (Knies et al. 1994; Phillips 2000), se ha descubierto que el flujo atmosférico de ³⁶Cl hacia la superficie terrestre es aproximadamente constante en todos los estados, sin deducirse una correlación fuerte entre el aporte de ³⁶Cl y la precipitación anual. Sin embargo, la correlación entre estas variables se ve mejorada de forma significativa, con coeficientes de regresión comprendidos entre 0,15 y 0,55, cuando se excluyen los datos recogidos en el sudeste de los EUA, que tienen concentraciones de ³⁶Cl atmosférico presuntamente inferiores a la media. El flujo medio total de ³⁶Cl calculado en la zona continental de los Estados Unidos vale 30,5±7,0 átomos por metro cuadrado y segundo, mientras que el flujo total global de ³⁶Cl es de 19,6±4,5 átomos por metro cuadrado y segundo.La distribución de ³⁶Cl/Cl calculada por Bentley et al. (1986) infravalora la magnitud y variabilidad observada en los valores medidos a lo largo de los Estados Unidos. El modelo propuesto por Hainsworth (1994) proporciona el mejor ajuste conjunto a la distribución observada de ³⁶Cl/Cl en este estudio. El modelo orientado a procesos de Phillips (2000) sobreestima por lo general la distribución de ³⁶Cl/Cl en la mayoría del país y difiere significativamente de algunos valores locales empíricos.

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Résumé La distribution naturelle du rapport ³⁶Cl/Cl dans les eaux souterraines des États-Unis a été récemment présentée par Davis et al. (2003). Dans ce travail, les processus à grande échelle et les sources atmosphériques de ³⁶Cl et de chlorure responsables du contrôle de la distribution observée du rapport ³⁶Cl/Cl sont discutés. Le processus dominant qui affecte le rapport ³⁶Cl/Cl dans les eaux souterraines dorigine météorique à léchelle continentale est lapport atmosphérique de chlorure stable, qui provient pour lessentiel de sources océaniques. La circulation atmosphérique transporte des chlorures marins vers lintérieur des continents, où la distribution de chlorure est définie par la distance à la côte, la topographie et les régimes des vents. La seule exception majeure à ce schéma est observée dans le nord de lUtah et le sud de lIdaho où lon suppose quil existe une source continentale de chlorure dans les bas-fonds salés de Bonneville. Au contraire de précédentes études (Knies et al. 1994; Phillips 2000), on trouve que le flux atmosphérique de ³⁶Cl vers le sol est approximativement constant sur lensemble des États-Unis, sans forte corrélation entre la retombée locale de ³⁶Cl et les précipitations annuelles. Cependant, la corrélation entre ces variables devient significative (R ²=0.15 à 0.55) lorsquon supprime les données du sud-est des États-Unis, dont on pense quelles présentent des concentrations en ³⁶Cl atmosphérique inférieures à la moyenne. Le flux total moyen de ³⁶Cl sur les États-Unis continentaux et le flux moyen global de ³⁶Cl sont respectivement évalués à 30.5 ± 7.0 et 19.6 ± 4.5 atomes.m^–2.s^–1. La distribution du rapport ³⁶Cl/Cl calculée par Bentley et al. (1986) sous-estime lordre de grandeur et la variabilité observés pour la distribution mesurée du rapport ³⁶Cl/Cl sur les États-Unis continentaux. Le modèle proposé par Hainsworth (1994) fournit le meilleur ajustement densemble à la distribution du rapport ³⁶Cl/Cl observée dans cette étude. Un modèle orienté vers les processus proposé par Phillips (2000) surestime dans lensemble le rapport ³⁶Cl/Cl dans la plupart des régions du pays et présente plusieurs désaccords locaux avec les données empiriques.

     

Numerical solution to the oblique derivative boundary value problem on non-uniform grids above the Earth topography

The paper presents a numerical solution of the oblique derivative boundary value problem on and above the Earth’s topography using the finite volume method (FVM). It introduces a novel method for constructing non-uniform hexahedron 3D grids above the Earth’s surface. It is based on an evolution of a surface, which approximates the Earth’s topography, by mean curvature. To obtain optimal shapes of non-uniform 3D grid, the proposed evolution is accompanied by a tangential redistribution of grid nodes. Afterwards, the Laplace equation is discretized using FVM developed for such a non-uniform grid. The oblique derivative boundary condition is treated as a stationary advection equation, and we derive a new upwind type discretization suitable for non-uniform 3D grids. The discretization of the Laplace equation together with the discretization of the oblique derivative boundary condition leads to a linear system of equations. The solution of this system gives the disturbing potential in the whole computational domain including the Earth’s surface. Numerical experiments aim to show properties and demonstrate efficiency of the developed FVM approach. The first experiments study an experimental order of convergence of the method. Then, a reconstruction of the harmonic function on the Earth’s topography, which is generated from the EGM2008 or EIGEN-6C4 global geopotential model, is presented. The obtained FVM solutions show that refining of the computational grid leads to more precise results. The last experiment deals with local gravity field modelling in Slovakia using terrestrial gravity data. The GNSS-levelling test shows accuracy of the obtained local quasigeoid model.     

Diagnostic analyses of convective events — The effect of propagating gust fronts

This paper is devoted to the testing experiment of a postprocessing tool aimed at the objective analysis of propagating gust fronts in a given convective environment. The tool is being developed to be applicable in the operational mode by utilizing NWP model outputs. The experiment was carried out on two summer convective cases which occurred in the Czech Republic. The cases were numerically simulated by the limited area NWP model LM COSMO with the horizontal resolution of 2.8 km. They represent different types of convective systems, both accompanied by objectively identifiable gust fronts and causing heavy precipitation. The event from July 2000 was characterised by the development of isolated thunderstorms. The other event from July 1998 was a long-lasting and organised convective system — a squall line. The hypothesis was that the developed postprocessing tool is capable to evaluate the role which downdraft outflows played in the decay and initiation of convective cells by interaction with convective environment and thus in prolongation of convection lifetime.The procedures of the Objective Analysis of Gust Fronts (OAGF) were applied to the thermodynamic outputs of the LM COSMO. The aim was to determine the position of gust fronts within the domain and to assess their speed of movement and the potential to initiate convection according to the properties of ambient vertical shear and stability as well as humidity conditions ahead of the respective downdraft outflows. In addition, the Radar Simulation Model (RSM) was employed to monitor the simulated convective systems in arbitrary PPI and RHI scans and to verify qualitatively the LM COSMO precipitation forecasts.The case studies has confirmed the applicability of the LM COSMO–OAGF chain and RSM, which may represent the potential for improving the operational nowcasting of hazardous convection phenomena. In both simulations, the objective gust fronts moved on into the vertical shear-favourable environment for triggering new convection. In addition to the dynamical organisation, there were also favourable stability and humidity conditions in the area of forced upward motions in the simulation of the event from July 2000.     

3D structure of the Earth's crust beneath the northern part of the Bohemian Massif

The SUDETES 2003 wide-angle refraction/reflection experiment covered the area of the south-western Poland and the northern Bohemian Massif. The good quality data that were gathered combined with the data from previous experiments (POLONAISE'97, CELEBRATION 2000) allowed us to prepare a 3D seismic model of the crust and uppermost mantle for this area. We inverted travel times of both refracted and reflected P waves using the JIVE3D package. This allowed us to obtain a model of P-wave velocity distribution as well as the shape of major boundaries in the crust. We also present a detailed uncertainty analysis for both the boundary depths and the velocity field. In doing the uncertainty analysis we found an interesting, strong dependence between uncertainty and inversion scheme (order of used phases). We also compared the model with surface geology and found good correlation between velocity inhomogeneities in the uppermost crust (down to 2 km) and major geological units. The higher velocity lower crust (6.9–7.2 km/s) could result from remelting of the lower crust or magmatic underplating.     

ECHOBASE—A portable geographic fishery research database system

A geographic fishery research database system (GFRDBS), called ECHOBASE, for storing and management of data on pelagic fish resources from acoustic surveys and catch samples, combined with environmental data in a geographic context, has been developed. The system constitutes a portable and inexpensive yet powerful tool for fishery research and environmental monitoring and provides on‐board data processing and mapping capabilities.

Data are acquired from an echosounder, echo signal processor, environmental profiler (CTD probe), and Global Positioning System (GPS) receiver. The electronic digitized maps (based on C‐MAP public format files) provide active on‐screen nautical charts.

The basic GFRDBS platform is a portable PC 486 machine, which is used as an on‐board data acquisition and processing tool running under MS Windows 3.1 operating environment. The system is designed around the Borland's PARADOX package, which provides a relational database for managing acoustic, catch, and environmental data. The ECHOBASE programs were written in Borland C ++ language as a Windows application.