Pyrolysis of modern wetland sediment: extracting climate records from fens in the Uinta Mountains and Fish Lake Plateau,Utah, USA

Rock‐Eval pyrolysis provides a quick, relatively inexpensive means of characterizing organic‐rich strata, and has been used for decades to understand global petroleum systems. Although designed to characterize ancient kerogens, pyrolysis is increasingly being used to understand Holocene systems as well. The ability of this technique to distinguish between types of preserved organic matter is useful in characterizing climatic evolution, particularly in systems sensitive to climatic fluctuation such as isolated fens and bogs. Cores collected from the Tokewanna and Garden Basin Cattail fens in central/eastern Utah exhibit variability of organic source, with the mixture of terrestrial and algal sources varying through time, as shown through the hydrogen index (HI) and oxygen index pyrolysis parameters. A sediment core was collected at each fen, and 176 samples were taken from the cores at 6‐cm intervals. Total organic carbon (TOC) for all samples ranges from 1.3 to 44.2%, with an average of 18.2% TOC. Samples range from 84 to 687 HI, equivalent to Type I (lacustrine algal) to Type III (terrestrial) organic material (OM). Variability in HI response represents mixing of the two OM sources, and the relative amount of aqueous organic input can be estimated through time based on age‐calibrated HI curves at the two sites. The balance of organic input serves as an accurate, high‐resolution proxy for climate, and calibration with palynological data near both sites confirms patterns shown by pyrolysis, showing the utility of this method in quickly, affordably and accurately characterizing Holocene sediments for use in understanding palaeoclimate.     

An overview of the Tennessee-Tombigbee Waterway

When the Tennessee-Tombigbee Waterway of Mississippi and Alabama opened to commercial and recreational traffic on January 16, 1985—some 21 months ahead of schedule—it signaled the completion of the largest Army Corps of Engineers Civil Works project ever undertaken, and perhaps the last of its kind After more than a century of studies and re-studies and major funding battles in Congress, the Tennessee-Tombigbee construction faced, predictably, great opposition on environmental grounds The first major project to be completed under the National Environmental Policy Act, it brought environmental design to the same level of prominence as engineering design.     

Stability considerations for one-dimensional inverse problems

Summary. We investigate the issues of stability and conditioning for the one-dimensional seismic inverse problem. We show that these issues are distinct; i.e. that numerically stable implementations of solutions to the inverse problem will not give accurate results if the problem is ill-conditioned. In addition, we identify the factors which determine the condition of the inverse problem. These are the total variation of the acoustic impedance profile being sought and the accuracy of the low-frequency content of the reflection data. We illustrate these results on implementations of two numerically stable algorithms for the inverse problem, one of which has a reputation for being unstable. A comparison shows nearly identical results for the two methods on noise-contaminated and frequency band limited reflection data. In fact, we conjecture that all of the well-known 'layer-stripping' inverse scattering methods share the same mathematical stability characteristics. On the other hand, we also show that ill-conditioning can lead to failure of such algorithms, through amplification of error due either to inaccurate data or to discretization or roundoff. Finally, we observe that appropriate smoothing of the seismic data for an ill-conditioned inverse problem (high-variation impedance profile) can cause the problem to become well-conditioned (lower-variation profile). As is typical with regularizations, the price paid for the newly-acquired ability to solve the problem is a loss of accuracy in the solution.     

Inertial Effects on the Vertical Transport of Suspended Particles in a Turbulent Boundary Layer

In many atmospheric flows, a dispersed phase is actively suspended by turbulence, whose competition with gravitational settling ultimately dictates its vertical distribution. Examples of dispersed phases include snow, sea-spray droplets, dust, or sand, where individual elements of much larger density than the surrounding air are carried by turbulent motions after emission from the surface. In cases where the particle is assumed to deviate from local fluid motions only by its gravitational settling (i.e., they are inertialess), traditional flux balances predict a power-law dependence of particle concentration with height. It is unclear, however, how particle inertia influences this relationship, and this question is the focus of this work. Direct numerical simulations are conducted of turbulent open-channel flow, laden with Lagrangian particles of specified inertia; in this way the study focuses on the turbulent transport which occurs in the lowest few meters of the planetary boundary layer, in regions critical for connecting emission fluxes to the fluxes felt by the full-scale boundary layer. Simulations over a wide range of particle Stokes number, while holding the dimensionless settling velocity constant, are performed to understand the role of particle inertia on vertical dispersion. It is found that particles deviate from their inertialess behaviour in ways that are not easily captured by traditional theory; concentrations are reduced with increasing Stokes number. Furthermore, a similarity-based eddy diffusivity for particle concentration fails as particles experience inertial acceleration, precluding a closed-form solution for particle concentration as in the case of inertialess particles. The primary consequence of this result is that typical flux parametrizations connecting surface emission models (e.g., saltation models or sea-spray generation functions) to elevated boundary conditions may overestimate particle concentrations due to the reduced vertical transport caused by inertia in between; likewise particle emission may be underestimated if inferred from concentration measurements aloft.     

Long-lasting floods buffer the thermal regime of the Pampas

The presence of large water masses influences the thermal regime of nearby land shaping the local climate of coastal areas by the ocean or large continental lakes. Large surface water bodies have an ephemeral nature in the vast sedimentary plains of the Pampas (Argentina) where non-flooded periods alternate with flooding cycles covering up to one third of the landscape for several months. Based on temperature records from 17 sites located 1 to 700 km away from the Atlantic coast and MODIS land surface temperature data, we explore the effects of floods on diurnal and seasonal thermal ranges as well as temperature extremes. In non-flooded periods, there is a linear increase of mean diurnal thermal range (DTR) from the coast towards the interior of the region (DTR increasing from 10 to 16 K, 0.79 K/100 km, r ² = 0.81). This relationship weakens during flood episodes when the DTR of flood-prone inland locations shows a decline of 2 to 4 K, depending on surface water coverage in the surrounding area. DTR even approaches typical coastal values 500 km away from the ocean in the most flooded location that we studied during the three flooding cycles recorded in the study period. Frosts-free periods, a key driver of the phenology of both natural and cultivated ecosystems, are extended by up to 55 days during floods, most likely as a result of enhanced ground heat storage across the landscape (~2.7 fold change in day-night heat transfer) combined with other effects on the surface energy balance such as greater night evaporation rates. The reduced thermal range and longer frost-free periods affect plant growth development and may offer an opportunity for longer crop growing periods, which may not only contribute to partially compensating for regional production losses caused by floods, but also open avenues for flood mitigation through higher plant evapotranspirative water losses.     

U-Pb systematics of monazite and xenotime: case studies from the Paleoproterozoic of the Grand Canyon, Arizona

Monazite is accepted widely as an important U-Pb geochronometer in metamorphic terranes because it potentially preserves prograde crystallization ages. However, recent studies have shown that the U-Pb isotopic system in monazite can be influenced by a variety of processes that partially obscure the early growth history. In this paper, we attempt to interpret complex monazite and xenotime U-Pb data from three Paleoproterozoic granite dikes exposed in the Grand Canyon. Single-crystal monazite analyses from an unfoliated granite dike spread out along concordia from the crystallization age of the dike (defined by U-Pb zircon data to be 1685 ± 1 Ma) to 1659 ± 2 Ma, a span of 26 million years. Back-scattered electron (BSE) imaging reveals that magmatic domains within most crystals from this sample are truncated by secondary domains associated with prominent embayments at the grain margin. Fragments of a single crystal yield contrasting, concordant dates and fragments from the edges and tips of crystals yield the youngest dates. Based on these observations we suggest that the secondary domains formed at least 26 million years after the crystal formed. Monazite and xenotime dates from the second sample, a sheared dike that cross-cuts the previous dike, spread out along concordia over 16 million years and range up to 2.4% normally discordant. Again, BSE imaging reveals secondary domains that truncate both magmatic zoning and xenocrystic cores. Fragments sliced from specific domains of a previously imaged monazite crystal demonstrate that the secondary domain is 13 million years younger than the core domain. Textures revealed in BSE images suggest that the secondary domains formed by fluid-mineral interaction. Normal discordance appears to result from both radiation damage accumulated at temperatures below 300 °C and water-mineral interaction. Monazite data from the third sample exhibit dispersion in both the ²⁰⁷Pb/²⁰⁶Pb dates (1677–1690 Ma) and discordance (+ 1.6% to − 3.1%). Reverse discordance in these monazites cannot be explained by incomplete dissolution or excess (thorogenic) ²⁰⁶Pb. Sliced fragments from several crystals reveal dramatic intragrain U-Pb disequilibrium that does not correlate with either Th or U concentration or position within the crystal. We suggest that reverse discordance resulted from mechanisms that involve exchange or fractionation of elemental U or elemental Pb, and that neither the U-Pb dates nor the ²⁰⁷Pb/²⁰⁶Pb dates are reliable indicators of the rock's crystallization age. Given the large number of processes proposed in the recent literature to explain monazite U-Pb systematics from rocks of all ages, our results can be viewed as another cautionary note for single-crystal and multi-crystal monazite geochronometry. However, we suggest that because individual crystals can preserve a temporal record of primary and secondary monazite growth, micro-sampling of individual monazite crystals may provide precise absolute ages on a variety of processes that operate during the prograde, peak and/or retrograde history of metamorphic terranes. Received: 9 June 1996 / Accepted: 18 October 1996     

Reliability-based design of R/C water tank structures under seismic action

Based on a reliability level 2 method, a procedure is proposed to design reinforced concrete structures for elevated tanks subjected to seismic action, with a specified probability of failure in a 50-year design life. To evaluate the probability of failure the ultimate limit state is obtained when the top column displacement demanded by the earthquake, a random variable, reaches the allowable displacement, which is here treated as deterministic. The seismic action is characterized probabilistically by the power spectral density function of the ground acceleration, which is obtained from a design spectrum. The strength and ductility of an annular column section of confined reinforced concrete for cyclic loads are evaluated with design aids. Design charts are made for a given tank capacity and specified seismic zone that allow one to choose different combinations of strength, stiffness and ductility for the same tolerable probability of failure. A step by step method is suggested for the design of the annular column section, choosing finally the most convenient design. The advantage of this methodology is shown through a numerical example.     

Climatic trends from isotopic records of tree rings: The past 100–200 years

There has been a great deal of discussion about global warming from accumulation of anthropogenic greenhouse gases in the atmosphere (Houghton et al., 1990). Relatively less attention has been paid to spatial and/or temporal climatic variations that may be associated with a warmer climate (Rind et al., 1989) or with anthropogenic activities (Schneider, 1994). In this article, we show that an increase in climatic variability may have started. Fourteen isotopic time series of tree rings are presented. These trees were randomly collected from world-wide locations and cover time periods of 120 to over 200 years. The isotopic records show increasing D values that suggest a consistent and progressive warming occurred in the 19th century in all locations where the trees were sampled. The rate of warming is greater at relatively cold locations than at warm locations with two exceptions. The records also suggest greater climatic variations both temporally and spatially in the 20th century than in the 19th century.     

The Uneven Landscape of California's Historical Landmarks

Historical markers help preserve and display history and communicate what a group deems important about a place's past. This paper analyzes the changing themes and landscape relevance of California's official historical landmarks. California's thousand‐plus markers are classified and mapped by themes, analyzed for changing topical emphasis over time, and evaluated for landscape presence. The thematic distribution and relative density of these landmarks is uneven. Gold Rush and Spanish themes have become less prevalent over time as culturally related landmarks have grown in importance. This paper illustrates how historical landmark programs help sustain and define the public's collective memory through designating dispersed geographical locations as particularly important points of reference to the past.