Modelling Spatial Patterns of Overbank Sedimentation on Embanked Floodplains

This paper presents a GIS-based mathematical model for the simulation of floodplain sedimentation. The model comprises two components: (1) the existing hydrodynamic WAQUA model that calculates two-dimensional water flow patterns; and (2) the SEDIFLUX model that calculates deposition of sediment based on a simple mass balance concept with a limited number of model parameters. The models were applied to simulate floodplain sediment deposition over river reaches of several kilometres in length. The SEDIFLUX model has been calibrated and validated using interpolated raster maps of sediment deposition observed after the large magnitude December 1993 flood on the embanked floodplain of the lower river Rhine in the Netherlands. The model appeared to be an adequate tool to predict patterns of sediment deposition as the product of the complex interaction among river discharge and sediment concentration, floodplain topography, and the resulting water flow patterns during various discharge levels. In the investigated areas, the resulting annual average sedimentation rates varied between 0.5 mm/year and 4.0 mm/year. The role of the most important mechanisms governing the spatial patterns of overbank deposition, i.e. inundation frequency, sediment load, floodplain topography and its influence on the flow patterns over the floodplain, are discussed.     

The influence of oxic degradation on the sedimentary biomarker record I: evidence from Madeira Abyssal Plain turbidites

Free and ester-bound lipid biomarkers were analysed in oxidised and unoxidised parts of four distinct turbidites from the Madeira Abyssal Plain (MAP), which contained 1 to 2% organic carbon homogeneously distributed throughout the turbidites at the time they were deposited. These turbidites are well suited to study the effects of oxic degradation on lipid biomarkers without the complicating influence of varying organic matter sources, sedimentation rates, or bioturbation. One sample from the oxidised turbidite was compared with two samples from the unoxidised part of each turbidite. Postdepositional oxic degradation decreased concentrations of biomarkers by several orders of magnitude. The ester-bound lipids were degraded to a far lesser extent than their free counterparts were. The extent of degradation of different compounds differed substantially. Within a specific class of biomarkers, degradation also took place to a different extent, altering their distributions. This study shows that oxic degradation of the organic matter may have a profound effect on the biomarker fingerprint and may result in a severe bias in, for example, the interpretation of organic matter sources and the estimation of the palaeoproductivity of specific groups of phytoplankton.     

Total resonant absorption of acoustic oscillations in sunspots

The question of total resonant absorption of acoustic oscillations in sunspots is studied for cylindrical 1-D flux tubes that are stratified only in the radial direction and surrounded by a uniform, non-magnetic plasma. The numerical investigation of Goossens and Poedts (1992) in linear resistive MHD is taken further by increasing the strength of the azimuthal magnetic field in the equilibrium flux tubes. For relatively strong azimuthal magnetic fields, total absorption is found over a relatively wide range of spot radii.     

A possible link between gabbros bearing High Temperature Iddingsite alteration and huge pegmatoid intrusions: The Society Islands, French Polynesia

This paper reports new field observations and new petrological, textural and geochemical data on two gabbroic intrusions and one pegmatoid dyke from the French Polynesian islands Maupiti and Bora Bora, respectively. Olivine crystals from the Faataufi and Barque de Hiro gabbros (Maupiti) include High Temperature Iddingsite (HTI), exhibiting three distinct morphological facies. Chemical and crystallographical data performed by electron microprobe, scanning microscope, X-ray diffractometry and Near InfraRed spectroscopy show that HTI results from modifications of olivine structure through intense hydroxylation and Fe-oxidation. The HTI-free 120 m-wide Cloche de Hiro dyke (Bora Bora) exhibits a textural zonation from heterogranular/intergranular gabbro (peripheral part) to typical pegmatoid (inner area). We propose a textural tetrahedral classificatory diagram which can be used to clearly distinguish the textural characteristics of the pegmatoids from those of the other coarse-grained samples. Through comparison with a lava flow containing vesicle-rich segregation sheets, we suggest that the Cloche de Hiro dyke may correspond to a huge segregation structure derived from a Maupiti-type HTI-bearing gabbro through a vapor-differentiation process. Both intrusions might be considered as representative of two superposed levels in a vertically arranged magmatic complex. In this view, the Maupiti gabbroic bodies would represent the lower part of the postulated system. Under high oxygen fugacity, olivine crystals would have undergone important modifications of their structure, leading to HTI. The huge Bora Bora pegmatoid dyke would be the upper part of the complex. After expulsion from the HTI-bearing gabbroic solidification zone by build-up of gas pressure, vesicle-rich residual melt would have gathered into a shallow level and crystallized there as a pegmatoid body.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part I: Isotopic (C,O) study of the Khushaym Matruk natural analogue (central Jordan)

The Khushaym Matruk site in central Jordan may represent a natural analogue depicting the interaction of alkaline solutions with a clayey sedimentary formation or with clay-rich confining barriers at the interface with concrete structures in waste disposal sites. In this locality, past spontaneous combustion of organic matter in a clayey biomicritic formation produced a ca. 60 m-thick layer of cement-marble containing some of the high-temperature phases usually found in industrial cements (e.g., spurrite, brucite, and Ca-aluminate). A vertical cross-section of the underlying sediments was used in order to study the interaction between cement-marbles and neighbouring clayey limestones under weathering conditions. A thermodynamic approach of the alteration parageneses (calcite–jennite–afwillite–brucite and CSH phases) in the cement-marbles constrains the interacting solutions to have had pH-values between 10.5 and 12. Over 3 m, the sediments located beneath the metamorphic unit were compacted and underwent carbonation. They display large C and O isotopic variations with respect to “pristine” sediments from the bottom of the section. Low δ¹³C-values down to −31.4‰/PDB show the contribution of CO₂ derived from the oxidization of organic matter and from the atmosphere to the intense carbonation process affecting that particular sedimentary level. The size of the C isotopic anomalies, their geometrical extent and their coincidence with the variations of other markers like the Zn content, the structure of organic matter, the mineralogical composition, all argue that the carbonation process was induced by the percolation of high pH solutions which derived from the alteration of cement-marbles. The temperature of the carbonation process remains conjectural and some post-formation O isotopic reequilibration likely affected the newly-formed carbonate. Carbonation induced a considerable porosity reduction, both in fractures and matrixes. The Khushaym Matruk site may have some bearing to the early life of a repository site, when water saturation of the geological formations hosting the concrete structures is incomplete, enabling simultaneous diffusion of alkaline waters and gaseous CO₂ in the near field.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.     

A new assessment of climate change impacts on food production shortfalls and water availability in Russia

While previous studies have focused on impacts of average climate change on Russian agriculture and water resources, this study takes into account the impact of changing frequency and spatial heterogeneity of extreme climate events, and the reliance of most of Russia on a few food producing regions. We analyze impacts of the IPCC A2 and B2 climate scenarios with the use of the Global Assessment of Security (GLASS) model (containing the Global Agro-Ecological Zones (GAEZ) crop production model and the Water-Global Assessment and Prognosis (WaterGAP 2) water resources model). As in previous studies we find that decreased crop production in some Russian regions can be compensated by increased production in others resulting in relatively small average changes. However, a different perspective on future risk to agriculture is gained by taking into account a change in frequency of extreme climate events. Under climate normal conditions it is estimated that “food production shortfalls” (a year in which potential production of the most important crops in a region is below 50% of its average climate normal production, taking into account production in food-exporting regions) occur roughly 1–3 years in each decade. This frequency will double in many of the main crop growing areas in the 2020s, and triple in the 2070s. The effects of these shortfalls are likely to propagate throughout Russia because of the higher likelihood of shortfalls occurring in many crop export regions in the same year, and because of the dependence of most Russian regions on food imports from a relatively few main crop growing regions. We estimate that approximately 50 million people currently live in regions that experience one or more shortfalls each decade. This number may grow to 82–139 million in the 2070s. The assessment of climate impacts on water resources indicates an increase in average water availability in Russia, but also a significantly increased frequency of high runoff events in much of central Russia, and more frequent low runoff events in the already dry crop growing regions in the South. These results suggest that the increasing frequency of extreme climate events will pose an increasing threat to the security of Russia's food system and water resources.     

Identifying the potential loss of monitoring wells using an uncertainty analysis

From the mid-1940s through the 1980s, large volumes of waste water were discharged at the Hanford Site in southeastern Washington State, causing a large-scale rise (>20 m) in the water table. When waste water discharges ceased in 1988, ground water mounds began to dissipate. This caused a large number of wells to go dry and has made it difficult to monitor contaminant plume migration. To identify monitoring wells that will need replacement, a methodology has been developed using a first-order uncertainty analysis with UCODE, a nonlinear parameter estimation code. Using a three-dimensional, finite-element ground water flow code, key parameters were identified by calibrating to historical hydraulic head data. Results from the calibration period were then used to check model predictions by comparing monitoring wells' wet/dry status with field data. This status was analyzed using a methodology that incorporated the 0.3 cumulative probability derived from the confidence and prediction intervals. For comparison, a nonphysically based trend model was also used as a predictor of wells' wet/dry status. Although the numerical model outperformed the trend model, for both models, the central value of the intervals was a better predictor of a wet well status. The prediction interval, however, was more successful at identifying dry wells. Predictions made through the year 2048 indicated that 46% of the wells in the monitoring well network are likely to go dry in areas near the river and where the ground water mound is dissipating.     

Radiation field in the troposphere and stratosphere—II. Numerical analysis

The results of calculations of the multiply-scattered solar-induced radiation field in the troposphere and stratosphere are presented for direct application to photochemical models. The enhancement factors due to multiple scattering are given for the heights, solar zenith angles and wavelengths (between 800 and 300 nm) which play a role in the photodissociation of various atmospheric constituents.