Morphostructure and evolution of the central and Eastern Bransfield Basins (NW Antarctic Peninsula)

The Bransfield Basin is a narrow and elongated active rift basin located between the Antarctic Peninsula and the South Shetland Islands. The Bransfield Basin is composed of three small basins, and two of them, the Central and Eastern Bransfield Basins, were surveyed during a recent cruise (GEBRA 93). The full swath bathymetry coverage as well as the single-channel seismic reflection and magnetic profiles that have been acquired, help us to better understand the morphostructure and recent evolution of the Bransfield Basin. Six large volcanic edifices aligned with the basin axis stick out of the sedimented seafloor of the Central Bransfield Basin. In contrast, the Eastern Bransfield Basin is characterised by four deep troughs displaying a rhombic-shape, and small, scattered volcanic cones located in the southwestern half basin. Seamount volcanism plays an important role in the formation of new crust in the Bransfield Basin. The larger seamounts of the Central Bransfield Basin are located at the intersection of the two main orthogonal sets of faults (longitudinal ENE-WSW and transversal NNW-SSE). Morphological analysis of the seamounts indicates a multi-staged volcano-tectonic construction. The distribution and shape of these edifices suggests that both volcanism and extension are concentrated at the same preferential areas through time. This might be related to the fracturation style of the continental crust. The Central and Eastern Bransfield Basins are very different in morphostructure, volcanism, and sedimentary cover. The Central Bransfield Basin shows evidence of NW-SE extensional faulting and focused active MORB-volcanism interpreted as result of incipient seafloor spreading. The Eastern Bransfield Basin is still in a rifting stage, mainly dominated by a NW-SE extension and some left-lateral strike-slip component probably related to the South Scotia Ridge.J. Acosta, J. Baraza, P. Bart, A.M. Calafat, J.L. Casamor, M. De Batist, G. Ercilla, G. Francés, E. Ramos, J.L. Sanz, and A. Tassone.     

Amplification and deformation of tidal wave in the Upper Scheldt Estuary

Ocean Dynamics - The records of HW and LW in the most upper part of the Scheldt Estuary since 1971 have been analysed together with the daily river discharge. The tidal range, the hydraulic head...     

U‐Th Zircon Dating by Laser Ablation Single Collector Inductively Coupled Plasma‐Mass Spectrometry (LA‐ICP‐MS)

Zircon crystals in the age range of ca. 10–300 ka can be dated by ²³⁰Th/²³⁸U (U‐Th) disequilibrium methods because of the strong fractionation between Th and U during crystallisation of zircon from melts. Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) analysis of nine commonly used reference zircons (at secular equilibrium) and a synthetic zircon indicates that corrections for abundance sensitivity and dizirconium trioxide molecular ions (Zr₂O₃⁺) are critical for reliable determination of ²³⁰Th abundances in zircon. When corrected for abundance sensitivity and interferences, mean activity ratios of (²³⁰Th)/(²³⁸U) for nine reference zircons analysed on five different days averaged 0.995 ± 0.023 (95% confidence weighted by data‐point uncertainty only, MSWD = 1.6; n = 9), consistent with their U‐Pb ages > 4 Ma that imply equilibrium for all intermediate daughter isotopes (including ²³⁰Th) within the ²³⁸U decay chain. U‐Th zircon ages generated by LA‐ICP‐MS without mitigating (e.g., by high mass resolution) or correcting for abundance sensitivity and molecular interferences on ²³⁰Th are potentially unreliable. To validate the applicability of LA‐ICP‐MS to this dating method, we acquired data from three late Quaternary volcanic units: the 41 ka Campanian Ignimbrite (plutonic clasts), the 161 ka Kos Plateau Tuff (juvenile clasts) and the 12 ka Puy de Dôme trachyte lava (all eruption ages by Ar/Ar, with zircon U‐Th ages being of equal or slightly older). A comparison of the corrected LA‐ICP‐MS results with previously published secondary ion mass spectrometry (SIMS) data for these rocks shows comparable ages with equivalent precision for LA‐ICP‐MS and SIMS, but much shorter analysis durations (~ 2 min vs. ~ 15 min) per spot with LA‐ICP‐MS and much simpler sample preparation. Previously undated zircons from the Yali eruption (Kos‐Nisyros volcanic centre, Greece) were analysed using this method. This yielded a large age spread (~ 45 to > 300 ka), suggesting significant antecryst recycling. The youngest zircon age (~ 45 ± 10 ka) provides a reasonable maximum estimate for the eruption age, in agreement with the previously published age using oxygen isotope stratigraphy (~ 31 ka).     

Pyrite oxidation during sample storage determines phosphorus fractionation in carbonate-poor anoxic sediments

We investigated the phosphorus (P) and iron (Fe) fractionation in four cores with anoxic sediments, deposited during the mid-Cretaceous oceanic anoxic event 2 (∼94 Ma) and the Paleocene-Eocene thermal maximum (∼55 Ma), that were exposed to oxygen after core recovery. Surprisingly, P associated with iron oxyhydroxides (Fe-bound P) was a major P phase in these laminated sediments deposited under euxinic conditions. A significant fraction of total Fe was present as (poorly) crystalline ferric Fe. This fraction increased with increasing storage time of the investigated cores. In carbonate-poor samples, Fe-bound P accounted for up to 99% of total P and its abundance correlated with pyrite contents. In samples with higher CaCO₃ contents (>5 wt% in the investigated samples), P was mostly present in authigenic Ca-P minerals, irrespective of pyrite contents. We conclude that the P fractionation in anoxic, carbonate-poor, sediments is strongly affected by pyrite oxidation that occurs when these sediments are exposed to oxygen. Pyrite oxidation produces sulfuric acid and iron oxyhydroxides. The abundance of poorly crystalline Fe oxyhydroxides provides further evidence that these were indeed formed through recent (post-recovery) oxidation rather than in situ tens of millions of years ago. The acid dissolves apatite and the released phosphate is subsequently bound in the freshly formed iron oxyhydroxides. Pyrite oxidation thus leads to a conversion of authigenic Ca-P to Fe-bound P. In more calcareous samples, CaCO₃ can act as an effective buffer against acidic dissolution of Ca-P minerals. The results indicate that shielding of sediments from atmospheric oxygen is vital to preserve the in situ P fractionation and to enable a valid reconstruction of marine phosphorus cycling based on sediment records.     

Comparison of climate field reconstruction techniques: application to Europe

This paper presents a comparison of principal component (PC) regression and regularized expectation maximization (RegEM) to reconstruct European summer and winter surface air temperature over the past millennium. Reconstruction is performed within a surrogate climate using the National Center for Atmospheric Research (NCAR) Climate System Model (CSM) 1.4 and the climate model ECHO-G 4, assuming different white and red noise scenarios to define the distortion of pseudoproxy series. We show how sensitivity tests lead to valuable “a priori” information that provides a basis for improving real world proxy reconstructions. Our results emphasize the need to carefully test and evaluate reconstruction techniques with respect to the temporal resolution and the spatial scale they are applied to. Furthermore, we demonstrate that uncertainties inherent to the predictand and predictor data have to be more rigorously taken into account. The comparison of the two statistical techniques, in the specific experimental setting presented here, indicates that more skilful results are achieved with RegEM as low frequency variability is better preserved. We further detect seasonal differences in reconstruction skill for the continental scale, as e.g. the target temperature average is more adequately reconstructed for summer than for winter. For the specific predictor network given in this paper, both techniques underestimate the target temperature variations to an increasing extent as more noise is added to the signal, albeit RegEM less than with PC regression. We conclude that climate field reconstruction techniques can be improved and need to be further optimized in future applications.     

The graininess of dark matter haloes

We use the recently completed one billion particle Via Lactea II Λ cold dark matter simulation to investigate local properties like density, mean velocity, velocity dispersion, anisotropy, orientation and shape of the velocity dispersion ellipsoid, as well as the structure in velocity space of dark matter haloes. We show that at the same radial distance from the halo centre, these properties can deviate by orders of magnitude from the canonical, spherically averaged values, a variation that can only be partly explained by triaxiality and the presence of subhaloes. The mass density appears smooth in the central relaxed regions but spans four orders of magnitude in the outskirts, both because of the presence of subhaloes as well as of underdense regions and holes in the matter distribution. In the inner regions, the local velocity dispersion ellipsoid is aligned with the shape ellipsoid of the halo. This is not true in the outer parts where the orientation becomes more isotropic. The clumpy structure in local velocity space of the outer halo cannot be well described by a smooth multivariate normal distribution. Via Lactea II also shows the presence of cold streams made visible by their high 6D phase space density. Generally, the structure of dark matter haloes shows a high degree of graininess in phase space that cannot be described by a smooth distribution function.     

Seasonal climate information preserved in West Antarctic ice core water isotopes: relationships to temperature, large-scale circulation, and sea ice

As part of the United States’ contribution to the International Trans-Antarctic Scientific Expedition (ITASE), a network of precisely dated and highly resolved ice cores was retrieved from West Antarctica. The ITASE dataset provides a unique record of spatial and temporal variations of stable water isotopes (δ¹⁸O and δD) across West Antarctica. We demonstrate that, after accounting for water vapor diffusion, seasonal information can be successfully extracted from the ITASE cores. We use meteorological reanalysis, weather station, and sea ice data to assess the role of temperature, sea ice, and the state of the large-scale atmospheric circulation in controlling seasonal average water isotope variations in West Antarctica. The strongest relationships for all variables are found in the cores on and west of the West Antarctic Ice Sheet Divide and during austral fall. During this season positive isotope anomalies in the westernmost ITASE cores are strongly related to a positive pressure anomaly over West Antarctica, low sea ice concentrations in the Ross and Amundsen Seas, and above normal temperatures. Analyses suggest that this seasonally distinct climate signal is due to the pronounced meridional oriented circulation and its linkage to enhanced sea ice variations in the adjacent Southern Ocean during fall, both of which also influence local to regional temperatures.     

Distribution of branched tetraether lipids in geothermally heated soils: Implications for the MBT/CBT temperature proxy

Branched glycerol dialkyl glycerol tetraether (GDGT) membrane lipids occur in soils and peat bogs and are assumed to be produced by anaerobic bacteria. Two indices based on the distribution of these lipids in soils, the Cyclisation of Branched Tetraethers (CBT) and the Methylation of Branched Tetraethers (MBT) index have been shown to linearly relate to pH, and to mean annual air temperature (MAT) and pH, respectively. To directly evaluate the impact of changes in soil temperature on the MBT/CBT proxy, we determined these indices in soils sampled from a transect away from two hot springs in California, which provided a set of soils similar in composition but with different temperatures (12–41 °C). The CBT values of these geothermally heated soils show a good relation with pH (R² 0.76), similar to that of a global MBT/CBT calibration set. Also, the relationship between MBT, soil pH and temperature for the geothermally heated soils is similar to that of a global soil calibration set, although the intercept for the geothermally heated soils is significantly lower, likely because our data set is based on in situ soil temperatures rather than MAT. The results confirm the dependence of the MBT index on soil temperature and pH and support the applicability of the MBT/CBT indices as a proxy for continental palaeotemperatures and past soil pH.     

Distribution of Crenarchaeota tetraether membrane lipids in surface sediments from the Red Sea

The Red Sea represents an extreme marine environment, with high salinity, high temperature and low level of nutrients, complicating the application of standard geochemical palaeotemperature proxies. In order to investigate the applicability of the TEX₈₆ (TetraEther indeX of GDGTs with 86 carbons) proxy for sea surface temperature (SST) in the Red Sea, the distribution of glycerol dialkyl glycerol tetraether membrane lipids (GDGTs) in sediments from the Red Sea and the Gulf of Aden were examined. Against expectations, TEX₈₆ values for the Red Sea do not show a simple linear relationship with SST and deviate from the global core top calibration. In the northern Red Sea, at temperatures between 25 and 28 °C, the values increase linearly with SST, whereas in the southern Red Sea, at temperatures above 28 °C, TEX₈₆ decreases with increasing temperature. Factors like seasonality and depth of production, salinity and nutrient availability, as well as diagenetic overprint or influence of allochtonous terrestrial lipids, cannot explain this pattern. However, the observed TEX₈₆ relationship with SST could be explained by the presence of a hypothetical endemic Crenarchaeota population in the Red Sea with a specific TEX₈₆ vs. SST relationship. In the Southern Red Sea, a two-component mixing model implies an exponential decrease in the endemic population towards the Gulf of Aden. Thus, the application of the TEX₈₆ as a palaeotemperature proxy in the Red Sea is likely only possible for the northern Red Sea area with the specific SST vs. TEX₈₆ relationship determined in this study and potentially for the whole Red Sea basin during glacials, when water exchange with the Indian Ocean was more restricted than today and the endemic archaeal lipid distribution was not affected by transport from the Indian Ocean. Our results suggest that distinct populations of Crenarchaeota in extreme environments such as evaporitic basins may have different membrane composition, necessitating application of another calibration than the global core top calibration for TEX₈₆ palaeothermometry.     

Multimass spherical structure models for N-body simulations

We present a simple and efficient method to set up spherical structure models for N -body simulations with a multimass technique. This technique reduces by a substantial factor the computer run time needed in order to resolve a given scale as compared to single-mass models. It therefore allows to resolve smaller scales in N -body simulations for a given computer run time. Here, we present several models with an effective resolution of up to  1.68 × 10⁹  particles within their virial radius which are stable over cosmologically relevant time-scales. As an application, we confirm the theoretical prediction by Dehnen that in mergers of collisionless structures like dark matter haloes always the cusp of the steepest progenitor is preserved. We model each merger progenitor with an effective number of particles of approximately 10⁸ particles. We also find that in a core–core merger the central density approximately doubles whereas in the cusp–cusp case the central density only increases by approximately 50 per cent. This may suggest that the central regions of flat structures are better protected and get less energy input through the merger process.